If an accident occurs at work places that handle 'the accident preparedness substances', it causes more property damage and casualties than accidents of normal chemical substances. Even though various systems and regulations have been operated in order to prevent accidents, techniques for reducing and removing human error, which is one of the main reasons of accidents, are still inadequate. In this paper, hazardous work digitization, potential hazard verification, and work evaluation based on domestic technical guidelines have been performed through a case study of the accident of hydrofluoric acid leakage in Gumi in September 2012, and development of a new risk mapping method has been studied to supplement existing systems.