ISSN: 0304-128X ISSN: 2233-9558
Copyright © 2024 KICHE. All rights reserved

Overall

Language
english
Conflict of Interest
In relation to this article, we declare that there is no conflict of interest.
Publication history
Received August 30, 2023
Revised October 4, 2023
Accepted October 5, 2023
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.

Most Cited

Photocatalytic Degradation and Adsorptive Removal of Tetracycline on Amine-Functionalized Graphene Oxide/ZnO Nanocomposites

University of Ulsan
jschung@ulsan.ac.kr
Korean Chemical Engineering Research, November 2023, 61(4), 635-644(10), 10.9713/kcer.2023.61.4.635 Epub 1 November 2023
downloadDownload PDF

Abstract

Due to the rapid development of the livestock industry, particularly due to residual pharmaceutical

antibiotics, environmental populations have been negatively affected. Herein, we report a ZnO/melamine-functionalized

carboxylic-rich graphene oxide (ZFG) photocatalyst for visible light-driven photocatalytic degradation of tetracycline

hydrochloride in aqueous solutions. The properties of the photocatalysts were evaluated by XRD, FTIR, XPS, Fe-SEM,

HR-TEM, TGA, Raman spectroscopy, UV-Vis spectroscopy, zeta potential, and electrochemical measurements. The

photocatalytic activity was measured using high-performance liquid chromatography. The photocatalytic properties of

the ZFG photocatalyst evaluated against the tetracycline hydrochloride (TCH) antibiotic under visible light irradiation

showed superior photodegradation of 96.27% within 60 min at an initial pH of 11. The enhancement of photocatalytic

degradation was due to the introduction of functionalized graphene, which increases the light-harvesting capability and

molecular adsorption capability in addition to minimizing the recombination rate of photogenerated charge carriers due

to its role as an electron acceptor and mediator.

References

1. Zhou, C., Lai, C., Xu, P., Zeng, G., Huang, D., Li, Z., Zhang, C.,
Cheng, M., Hu, L., Wan, J., Chen, F., Xiong, W. and Deng, R.,
“Rational Design of Carbon-Doped Carbon Nitride/Bi12O17Cl2
Composites: A Promising Candidate Photocatalyst for Boosting
Visible-Light-Driven Photocatalytic Degradation of Tetracycline,”
ACS Sustainable Chemistry & Engineering, 6, 6941-6949
(2018).
2. Chen, X., Xu, X., Cui, J., Chen, C., Zhu, X., Sun, D. and Sun,
D., “Visible-light Driven Degradation of Tetracycline Hydrochloride
and 2,4-dichlorophenol Byfilm-like N-carbon@N-ZnO
Catalyst with Three-dimensional Interconnected Nanofibrous
Structure,” J. Hazardous Materials, 392, 122331(2020).
3. Tung, M. H. T., Cam, N. T. D., Thuan, D. V., Quan, P. V.,
Hoang, C. V., Phuong, T. T. T., Lam, N. T., Tam, T. T., Chi, N. T.
P. L., Lan, N. T., Thoai, D. N. and Pham, T.-D., “Novel Direct
Z-scheme AgI/N–TiO2 Photocatalyst for Removal of Polluted
Tetracycline Under Visible Irradiation,” Ceramics International,
46, 6012-6021(2020).
4. Chen, G., Yu, Y., Liang, L., Duan, X., Li, R., Lu, X., Yan, B., Li,
N. and Wang, S., “Remediation of Antibiotic Wastewater by
Coupled Photocatalytic and Persulfate Oxidation System: A
Critical Review,” J. Hazardous Materials, 408,124461(2020).
5. Saadati, F., Keramati, N. and Ghazi, M. M., “Influence of Parameters
on the Photocatalytic Degradation of Tetracycline in Wastewater:
A Review,” Critical Reviews in Environmental Science
and Technology, 46, 757-782(2016).
6. Das, P., Pan, A., Chakraborty, K., Pal, T. and Ghosh, S., “RGOZnSe
Photocatalyst towards Solar-Light-Assisted Degradation
of Tetracycline Antibiotic Water Pollutant,” ChemistrySelect, 3,
10214-10219(2018).
7. Thi, V. H. T. and Lee, B.-K., “Great Improvement on Tetracycline
Removal Using ZnO Rod-activated Carbon Fiber Composite
Prepared with a Facile Microwave Method,” J. Hazardous
Materials, 324, 329-339(2017).
8. Zhao, C., Hong, P., Li, Y., Song, X., Wang, Y. and Yang, Y., “Mechanism
of Adsorption of Tetracycline–Cu Multi-pollutants by
Graphene Oxide Mechanism of Adsorption of Tetracycline–Cu
Multi-pollutants by Graphene Oxide,” J. Chemical Technology
and Biotechnology, 94, 1176-1186(2019).
9. Du, Q., Wu, P., Sun, Y., Zhang, J. and He, H., “Selective Photodegradation
of Tetracycline by Molecularly Imprinted ZnO@Selective
Photodegradation of Tetracycline by Molecularly Imprinted
ZnO@,” Chemical Engineering J., 390, 129350(2020).
10. Yan, X., Yan, X., Ning, G., Li, J., Ai, T., Su, X. and Wang, Z.,
“A Novel Poly(triazine imide) Hollow Tube/ZnO Heterojunction
for Tetracycline Hydrochloride Degradation Under Visible
Light Irradiation,” Advanced Powder Technology, 30, 359-
365(2019).
11. Xu, F., Yuan, Y., Wu, D., Zhao, M., Gao, Z. and Jiang, K., “Synthesis
of ZnO/Ag/graphene Composite and its Enhanced Photocatalytic
Efficiency,” Materials Research Bulletin, 48, 2066-
2070(2013).
12. Thinh, D. B., Tien, N. T., Dat, N. M., Phong, H. H. T., Giang, N.
T. H., Tai, L. T., Oanh, D. T. Y., Nam, H. M., Phong, M. T. and
Hieu, N. H., “Improved Photodegradation of p-nitrophenol From
Water Media Using Ternary MgFe2O4-doped TiO2/reduced Graphene
Oxide,” Synthetic Metals, 270, 116583(2020).
13. Zhu, P., Chen, Y., Duan, M., Liu, M., Zou, P. and Zhou, M.,
“Enhanced Visible Photocatalytic Activity of Fe-Cu-ZnO/Graphene
Oxide Photocatalysts for the Degradation of Organic Dyes,”
Canadian J. Chemical Engineering, 96, 1479-1488(2018).
14. Sharma, P., Kumar, N., Chauhan, R., Singh, V., Srivastava, V.
C., Sharma, P., Kumar, N., Chauhan, R., Singh, V. and Srivastava,
V. C., “Growth of Hierarchical ZnO Nano Flower on Large
Functionalized rGO Sheet for Superior Photocatalytic Mineralization
of Antibiotic,” Chemical Engineering J., 392, 123746(2020).
15. Anirudhan, T. S. and Deepa, J. R., “Nano-zinc Oxide Incorporated
Graphene Oxide/nanocellulose Composite for the Adsorption
and Photo Catalytic Degradation of Ciprofloxacin Hydrochloride
From Aqueous Solutions,” J. Colloid and Interface Science,
490, 343-356(2017).
16. Munawar, T., Mukhtar, F., Nadeem, M. S., Mahmood, K., Hussain,
A., Ali, A., Arshad, M. I., un Nabi, M. A. and un Nabi, M.
A., “Structural, Optical, Electrical, and Morphological Studies of
rGO Anchored Direct Dual-Z-Scheme ZnO-Sm2O3–Y2O3 Heterostructured
Nanocomposite: Direct Dual-Z-scheme ZnOSm2O3–
Y2O0 Heterostructured Nanocomposite,” Solid State Sciences,
106, 106307(2020).
17. Jesús, J. L.-P., Manuel, S.-P., Carla, V. G.-P., José, R.-U., “Photodegradation
of Tetracyclines in Aqueous Solution by Using
UV and UV/H2O2 Oxidation Processes,” J. Chemical Technology
and Biotechnology, 85, 1325-1333(2010).
18. Alireza, N.-E. and Arezoo, S., “Enhancement of the Photocatalytic
Activity of Ferrous Oxide by Doping Onto the Nanoclinoptilolite
Particles Towards Photodegradation of Tetracycline,”
Chemosphere, 107, 136-144(2014).
19. Zyoud, A. H., Zubi, A., Zyoud, S. H., Hilal, M. H., Zyoud, S.,
Qamhieh, N., Hajamohideen, A. and Hajamohideen, A., “Kaolinsupported
ZnO Nanoparticle Catalysts in Self-sensitized Tetracycline
Photodegradation: Zero-point Charge and pH Effects,” Applied
Clay Science, 182, 105294(2019).
20. Demircivi, P. and Demircivi, P., “Visible-light-enhanced Photoactivity
of Perovskite-type W-doped BaTiO3 Photocatalyst for
Photodegradation of Tetracycline,” J. Alloys and Compounds,
774, 795-802(2019).
21. Ashok Kumar, K. V., Lakshminarayana, B, Suryakala, D. and Subrahmanyam, Ch., “Reduced Graphene Oxide Supported ZnO
Quantum Dots for Visible Light-induced Simultaneous Removal
of Tetracycline and Hexavalent Chromium,” RSC Advances, 10,
20494-20503(2020).
22. Wu, F., Zhou, F., Zhu, Z., Zhan, S. and He, Q., “Enhanced Photocatalytic
Activities of Ag3PO4/GO in Tetracycline Degradation,”
Chemical Physics Letters, 724, 90-95(2020).
23. Abdel-Mottaleb, M. M., Khalil, A., Karim, S. A., Osman, T. A.,
and Khattab, A., “High Performance of PAN/GO-ZnO Composite
Nanofibers for Photocatalytic Degradation Under Visible
Irradiation,” J. of the Mechanical Behavior of Biomedical Materials,
96, 118-124(2020).
24. Kumar, K. V. A., Lakshminarayana, B., Suryakala, D., Subrahmanyam,
C., “Reduced Graphene Oxide Supported ZnO Quantum
Dots for Visible Light-induced Simultaneous Removal of
Tetracycline and Hexavalent Chromium,” RSC Advances, 10,
20494-20503(2020).
25. Wu, F., Zhou, F., Zhu, Z., Zhan, S. and He, Q., “Enhanced Photocatalytic
Activities of Ag3PO4/GO in Tetracycline Degradation,”
Chemical Physics Letters, 724, 90-95(2020).
26. Abdel-Mottaleb, M. M., Khalil, A., Karim, S., Osman, T. A. and
Khattab, A., “High Performance of PAN/GO-ZnO Composite
Nanofibers for Photocatalytic Degradation Under Visible Irradiation,”
J. of the Mechanical Behavior of Biomedical Materials,
96, 118-124(2019).
27. Qiao, D., Li, Z., Duan, J. and He, X., “Adsorption and Photocatalytic
Degradation Mechanism of Magnetic Graphene Oxide/ZnO
Nanocomposites for Tetracycline Contaminants,” Chemical Engineering
J., 400, 125952(2020).
28. Jia, K., Liu, G., Lang, D.-N., Chen, S.-F., Yang, C., Wu, R.-L.,
Wang, W. and Wang, J.-D., “Degradation of Tetracycline by Visible
Light Over ZnO Nanophotocatalyst,” J. of the Taiwan Institute
of Chemical Engineers, 136, 104422(2022).
29. Gang, R., Xu, L., Xia, Y., Zhang, L., Wang, S., Li, R., “Facile
One-step Production of 2D/2D ZnO/rGO Nanocomposites under
Microwave Irradiation for Photocatalytic Removal of Tetracycline,”
ACS Omega, 6, 3831-3839(2021).
30. Kar, S., Chakraborty, K., Pal, T. and Ghosh, S., “Enhanced Photocatalytic
Degradation of Tetracycline by RGO-ZnO Composite,
AIP Conference Proceedings, 2265, 030134(2020).

The Korean Institute of Chemical Engineers. F5, 119, Anam-ro, Seongbuk-gu, 233 Spring Street Seoul 02856, South Korea.
Phone No. +82-2-458-3078FAX No. +82-507-804-0669E-mail : kiche@kiche.or.kr

Copyright (C) KICHE.all rights reserved.

- Korean Chemical Engineering Research 상단으로