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- In relation to this article, we declare that there is no conflict of interest.
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Received January 19, 2021
Accepted August 5, 2021
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Copyright © KIChE. All rights reserved.
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Refractive Index and Excess Volume for Diisopropylamine + Isomeric Butanol Mixtures in terms of Nakata and Sakurai model
Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology, Murthal-131 039, India
sanjeevmakin@gmail.com
Korean Chemical Engineering Research, November 2021, 59(4), 644-651(8), 10.9713/kcer.2021.59.4.644 Epub 2 November 2021
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Abstract
Alkyl amines are widely used in various industries. Nowadays these are also used in CO2 capture technology because amines react with CO2 and remove it from the flue gas. To make the amines more compatible towards this technology, physico chemical properties may be altered by mixing with other solvents. In the present report, we measured the refractive properties of pure diisopropylamine (DIPA) (1) + isomeric butanol (2) at 298.15 K to 308.15 K. The Δn values were positive for DIPA + n-butanol or sec-butanol or isobutanol or tert-butanol mixtures. The measured data was correlated with Redlich-Kister equation. The excess molar volume data were predicted from refractive index data using Nakata and Sakurai model. The experimental data were also predicted by various correlations, and the prediction capability of these correlations was reported through standard deviation. Further, the deviation in refractive index (Δn) data was interpreted by the consideration of specific molecular interactions between DIPA and isomeric butanol.
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References
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Noh HJ, Park SJ, In SJ, J. Ind. Eng. Chem., 16(2), 200 (2010)
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Hwang IC, Park SJ, Han KJ, Fluid Phase Equilib., 309(2), 145 (2011)
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Sadeghi R, Azizpour S, J. Chem. Eng. Data, 56(2), 240 (2011)
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Hwang IC, Park SJ, Han KJ, In SJ, J. Ind. Eng. Chem., 18(1), 499 (2012)
Llovell F, Vilaseca O, Jung N, Vega LF, Fluid Phase Equilib., 360, 367 (2013)
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Bhagat P, Maken S, Asian J. Chem., 32, 2443 (2020)
Bhagat P, Maken S, Journal of Molecular Liquids, In press 114640(2020).
Brocos P, Pineiro A, Bravo R, Phys. Chem. Chem. Phys., 5, 550 (2003)
Devi R, Gahlyan S, Rani M, Maken S, Asian J. Chem., 30, 2054 (2018)
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Vuksanovic JM, Bajic DM, Ivanis GR, et al., J. Serb. Chem. Soc., 79, 707 (2014)
Nakata M, Sakurai M, Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 83, 2449 (1987).
Oswal SL, Oswal P, Gardas RL, Patel SG, Shinde RG, Fluid Phase Equilib., 216(1), 33 (2004)
Dubey GP, Sharma M, Dubey N, J. Chem. Thermodyn., 40(2), 309 (2008)
Vaid ZS, More UU, Oswal SB, Malek NI, Thermochim. Acta, 634, 38 (2016)
Alavianmehr MM, Hemmati N, Ghodrati H, Physics and Chemistry of Liquids, 55, 85 (2017).
Rahul D, Sankar MG, Chand GP, Ramachandran D, J. Mol. Liq., 211, 386 (2015)
Nain AK, Srivastava T, Pandey JD, Gopal S, J. Mol. Liq., 149S, 9 (2009)
Outcalt SL, Laesecke A, Fortin TJ, J. Mol. Liq., 151, 50 (2010)
Bravo-Sanchez MG, Iglesias-Silva GA, Estrada-Baltazar A, Hall KR, J. Chem. Eng. Data, 55(6), 2310 (2010)
Spasojevic VD, Djordjevic BD, Serbanovic SP, Radovic IR, Kijevcanin ML, J. Chem. Eng. Data, 59(6), 1817 (2014)
Tanaka R, Toyama S, J. Chem. Thermodyn., 28(12), 1403 (1996)
Loras S, Monton JB, Espana F, J. Chem. Eng. Data, 42(5), 914 (1997)
Kumar H, J. Mol. Liq., 276, 562 (2019)
Dubey GP, Sharma M, J. Chem. Eng. Data, 52(2), 449 (2007)
Khanlarzadeh K, Iloukhani H, J. Chem. Thermodyn., 43(11), 1583 (2011)
Riddick JA, "Organic Solvents. Physical Properties and Methods of Purification, fourth ed., Wiley New York, 1986.
Giner B, Artigas H, Carrion A, Lafuente C, Royo FM, J. Mol. Liq., 108, 303 (2003)
Kijevcanin ML, Radovic IR, Djordjevic BD, Tasic AZ, Serbanovic SP, Thermochim. Acta, 525(1-2), 114 (2011)
Ortega J, Espiau F, Postigo M, J. Chem. Eng. Data, 50(2), 444 (2005)
Gahlyan S, Rani M, Maken S, J. Mol. Liq., 219, 1107 (2016)
