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- In relation to this article, we declare that there is no conflict of interest.
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Received October 12, 2015
Accepted December 22, 2015
Available online June 14, 2016
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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친수성 실리카와 하이드로겔 전해질이 적용된 활성탄 수퍼커패시터의 전기화학적 특성
Electrochemical Properties of Activated Carbon Supercapacitors Adopting Hydrophilic Silica and Hydrogel Electrolytes
한밭대학교 화학생명공학과, 34158 대전광역시 유성구 동서대로 125 1한국전자통신연구원 정보통신부품소재연구소 전력제어소자연구실, 34129 대전광역시 유성구 가정로 218
Department of Chemical and Biological Engineering, Hanbat National University, 125, Dongseo-daero, Yuseong-gu, Daejeon, 34158, Korea 1Research Section of Power Control Devices, Electronics & Telecommunications Research Institute (ETRI), 218, Gajeong-ro, Yuseong-gu, Daejeon, 34129, Korea
jmko@hanbat.ac.kr
Korean Chemical Engineering Research, June 2016, 54(3), 293-298(6)
https://doi.org/10.9713/kcer.2016.54.3.293
https://doi.org/10.9713/kcer.2016.54.3.293
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Abstract
6M의 KOH 수계 전해액에 potassium polyacrylate (PAAK)가 3 wt.% 포함된 하이드로겔 전해질을 제조하고, 이에 친수성 실리카 OX50을 1 wt.% 포함시킨 하이드로겔 전해질을 함께 제조하고, 이를 Scimat 분리막에 코팅 및 건조하여 활성탄 수퍼커패시터의 자기지지체 전해질/분리막으로 사용하여 그 실리카 첨가효과를 조사하였다. 실리카 입자는 다공성 분리막 지지체의 표면기공에 균일하게 분포하여 하이드로겔의 이온전도도와 전기화학적 안정성을 향상시켰으며 이에 따라 고속스캔 조건에서도 활성탄 수퍼커패시터의 비축전용량이 비교적 높게 유지되었는데, 이는 실리카가 포함된 하이드로겔 전해질이 활성탄 전극과 분리막 사이에서의 계면저항이 감소하기 때문이다.
A hydrogel electrolyte consisting of 6 M KOH aqueous solution, potassium polyacrylate (PAAK, 3 wt.%), and a hydrophilic silica OX50 (1 wt.%) was prepared to use as an electrolyte medium coated on a Scimat separator of activated carbon supercapacitor. The silica particle distributed homogeneously on surface pores of the separator to increase ionic conductivity and electrochemical stability of the hydrogel electrolyte. The silica addition also involved superior specific capacitance even at higher scan rates due to decrease in interfacial resistance between hydrogel electrolyte and activated carbon electrode.
Keywords
References
Simon P, Gogotsi Y, Dunn B, Science, 343(6176), 1210 (2014)
Yan J, Wang Q, Wei T, Fan Z, Adv. Energy Mater, art. no. 1300816, 4(4) (2014)
Wang G, Zhang L, Zhang J, Chem. Soc. Rev., 41(2), 797 (2012)
Yu Z, Tetard L, Zhai L, Thomas J, Energy Environ. Sci., 8(3), 702 (2015)
Beguin F, Presser V, Balducci A, Frackowiak E, Adv. Mater., 26(14), 2219 (2014)
Nishiyama Y, Satoh M, J. Polym. Sci. B: Polym. Phys., 38(21), 2791 (2000)
Iwakura C, Wada H, Nohara S, Furukawa N, Inoue H, Morita M, Electrochem. Solid State Lett., 6(2), A37 (2003)
Nohara S, Wada H, Furukawa N, Inoue H, Morita M, Iwakura C, Electrochim. Acta, 48(6), 749 (2003)
Wada H, Nohara S, Furukawa N, Inoue H, Sugoh N, Iwasaki H, Morita M, Iwakura C, Electrochim. Acta, 49(27), 4871 (2004)
Nohara S, Toshihide AA, Wada H, Furukawa N, Inoue H, Sugoh N, Iwasaki H, Iwakura C, J. Power Sources, 157(1), 605 (2006)
Lee KT, Wu NL, J. Power Sources, 179(1), 430 (2008)
Lee KT, Lee JF, Wu NL, Electrochim. Acta, 54(26), 6148 (2009)
Nam HS, Wu NL, Lee KT, Kim KM, Yeom CG, Hepowit LR, Ko JM, Kim JD, J. Electrochem. Soc., 159(6), A899 (2012)
Kim KM, Nam JH, Lee YG, Cho WI, Ko JM, Curr. Appl. Phys., 13(8), 1702 (2013)
Ko JM, Nam JH, Won JH, Kim KM, Synth. Met., 189(1), 152 (2014)
Latifatu M, Ko JM, Lee YG, Kim KM, Jo J, Jang Y, Yoo JJ, Kim JH, Korean Chem. Eng. Res., 51(5), 550 (2013)
Yoon CS, Ko JM, Latifatu M, Lee HS, Lee YG, Kim KM, Won JH, Jo J, Jang Y, Kim JH, Korean Chem. Eng. Res., 52(5), 553 (2014)
Lee HS, Kim KM, Jang Y, Kim KY, Yu JJ, Kim JH, Ko JM, J. Korean Electrochem. Soc., 18(3), 115 (2015)
Kim KM, Latifatu M, Lee YG, Ko JM, Kim JH, Cho WI, J. Electroanal. Chem., 32(2-3), 146 (2014)
Kim KM, Hepowit LR, Kim JC, Lee YG, Ko JM, Korean J. Chem. Eng., 32(4), 717 (2015)
http://www.aerosil.com/.
Cho WJ, Yeom CG, Kim BC, Kim KM, Ko JM, Yu KH, Electrochim. Acta, 89, 807 (2013)
Jung HW, Hamenu L, Lee HS, Latifatu M, Kim KM, Ko JM, Curr. Appl. Phys., 15(4), 567 (2015)
Lee EJ, Lee YJ, Kim JK, Lee M, Yi J, Yoon JR, Song JC, Song IK, Mater. Res. Bull., 70, 209 (2015)
Calvo EG, Lufrano F, Staiti P, Brigandi A, Arenillas A, Menendez JA, J. Power Sources, 241, 776 (2015)
Obreja VVN, Physica E, 40(7), 2596 (2008)
Davies A, Yu AP, Can. J. Chem. Eng., 89(6), 1342 (2011)
Gu W, Yushin G, WIREs Energy Environ., 3(5), 424 (2014)
Sugimoto W, Iwata H, Yokoshima K, Murakami Y, Takasu Y, J. Phys. Chem. B, 109(15), 7330 (2005)
Yan J, Wang Q, Wei T, Fan Z, Adv. Energy Mater, art. no. 1300816, 4(4) (2014)
Wang G, Zhang L, Zhang J, Chem. Soc. Rev., 41(2), 797 (2012)
Yu Z, Tetard L, Zhai L, Thomas J, Energy Environ. Sci., 8(3), 702 (2015)
Beguin F, Presser V, Balducci A, Frackowiak E, Adv. Mater., 26(14), 2219 (2014)
Nishiyama Y, Satoh M, J. Polym. Sci. B: Polym. Phys., 38(21), 2791 (2000)
Iwakura C, Wada H, Nohara S, Furukawa N, Inoue H, Morita M, Electrochem. Solid State Lett., 6(2), A37 (2003)
Nohara S, Wada H, Furukawa N, Inoue H, Morita M, Iwakura C, Electrochim. Acta, 48(6), 749 (2003)
Wada H, Nohara S, Furukawa N, Inoue H, Sugoh N, Iwasaki H, Morita M, Iwakura C, Electrochim. Acta, 49(27), 4871 (2004)
Nohara S, Toshihide AA, Wada H, Furukawa N, Inoue H, Sugoh N, Iwasaki H, Iwakura C, J. Power Sources, 157(1), 605 (2006)
Lee KT, Wu NL, J. Power Sources, 179(1), 430 (2008)
Lee KT, Lee JF, Wu NL, Electrochim. Acta, 54(26), 6148 (2009)
Nam HS, Wu NL, Lee KT, Kim KM, Yeom CG, Hepowit LR, Ko JM, Kim JD, J. Electrochem. Soc., 159(6), A899 (2012)
Kim KM, Nam JH, Lee YG, Cho WI, Ko JM, Curr. Appl. Phys., 13(8), 1702 (2013)
Ko JM, Nam JH, Won JH, Kim KM, Synth. Met., 189(1), 152 (2014)
Latifatu M, Ko JM, Lee YG, Kim KM, Jo J, Jang Y, Yoo JJ, Kim JH, Korean Chem. Eng. Res., 51(5), 550 (2013)
Yoon CS, Ko JM, Latifatu M, Lee HS, Lee YG, Kim KM, Won JH, Jo J, Jang Y, Kim JH, Korean Chem. Eng. Res., 52(5), 553 (2014)
Lee HS, Kim KM, Jang Y, Kim KY, Yu JJ, Kim JH, Ko JM, J. Korean Electrochem. Soc., 18(3), 115 (2015)
Kim KM, Latifatu M, Lee YG, Ko JM, Kim JH, Cho WI, J. Electroanal. Chem., 32(2-3), 146 (2014)
Kim KM, Hepowit LR, Kim JC, Lee YG, Ko JM, Korean J. Chem. Eng., 32(4), 717 (2015)
http://www.aerosil.com/.
Cho WJ, Yeom CG, Kim BC, Kim KM, Ko JM, Yu KH, Electrochim. Acta, 89, 807 (2013)
Jung HW, Hamenu L, Lee HS, Latifatu M, Kim KM, Ko JM, Curr. Appl. Phys., 15(4), 567 (2015)
Lee EJ, Lee YJ, Kim JK, Lee M, Yi J, Yoon JR, Song JC, Song IK, Mater. Res. Bull., 70, 209 (2015)
Calvo EG, Lufrano F, Staiti P, Brigandi A, Arenillas A, Menendez JA, J. Power Sources, 241, 776 (2015)
Obreja VVN, Physica E, 40(7), 2596 (2008)
Davies A, Yu AP, Can. J. Chem. Eng., 89(6), 1342 (2011)
Gu W, Yushin G, WIREs Energy Environ., 3(5), 424 (2014)
Sugimoto W, Iwata H, Yokoshima K, Murakami Y, Takasu Y, J. Phys. Chem. B, 109(15), 7330 (2005)
