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- In relation to this article, we declare that there is no conflict of interest.
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Received September 27, 2012
Accepted November 5, 2012
Available online January 30, 2013
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제올라이트 촉매상에서의 알킬 방향족 화합물 전환 반응기구에 대한 최근 연구 동향
Recent Advances in the Mechanistic Studies of Alkylaromatic Conversions over Zeolite Catalysts
포항공과대학교 화학공학과/환경공학부, 경북 포항시 남구 효자동 산 31번지
Department of Chemical Engineering and School of Environmental Science and Engineering, POSTECH, San 31 Hyoja-dong, Nam-gu, Pohang, Gyeongbuk 790-784, Korea
sbhong@postech.ac.kr
Korean Chemical Engineering Research, February 2013, 51(1), 1-9(9)
https://doi.org/10.9713/kcer.2013.51.1.1
https://doi.org/10.9713/kcer.2013.51.1.1
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Abstract
제올라이트 촉매를 이용한 알킬 방향족 화합물의 전환은 현대 석유화학 산업에서 큰 비중을 차지한다. 본 총설에서는 제올라이트의 구조적 ·물리화학적 특성에 따른 알킬 방향족 화합물 전환 반응의 기구에 대해 고찰하였다. 제올라이트의 형상선택성은 알킬 방향족 화합물 전환에 있어서 반응중간체의 생성을 조절함으로써 반응 기구 및 생성물 분포에 직접적인 영향을 미친다. 다양한 알킬 방향족 화합물의 전환 반응에 대하여 반응 중간체의 구조 및 역할에 대한 고찰을 통해 지금까지 알려진 반응기구들을 정리하였다. 아울러 제올라이트 촉매를 기초로 하는 향후 석유화학 공정 개발에 대한 전망을 기술하였다.
The transformation of alkylaromatic hydrocarbons using zeolite catalysts play big part in the current petrochemical industry. Here we review recent advances in the understanding of the reaction mechanisms of various alkylaromatic conversions with respect to the structural and physicochemical properties of zeolite catalysts employed. Indeed, the shape-selective nature of zeolite catalysts determines the type of reaction intermediates and hence the prevailing reaction mechanism together with the product distribution. The prospect of zeolite catalysis in the developement of more efficient petrochemical processes is also described.
Keywords
References
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Arsenova N, Haag WO, Karge HG, Stud. Surf. Sci. Catal., 94, 441 (1995)
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Huang J, Jiang YJ, Marthala VRR, Bressel A, Frey J, Hunger M, J. Catal., 263(2), 277 (2009)
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Streitwieser A, Reif L, J. Am. Chem. Soc., 82, 5003 (1960)
Amelse JA, Stud. Surf. Sci. Catal., 38, 165 (1988)
Kim BH, Lee JG, Yim T, Kim HJ, Lee HY, Kim YG, Tetrahedron Lett., 47, 7727 (2006)
Millini R, Frigerio F, Bellussi G, Pazzuconi G, Perego C, Pollesel P, Romano U, J. Catal., 217(2), 298 (2003)
Das J, Halgeri AB, Catal. Surv. Asia., 7(1), 3 (2003)
Vermeiren W, Gilson JP, Top. Catal., 52, 1131 (2009)
Baerlocher C, McCusker LB, “Database of Zeolite Structure, http://www.iza-structure.org/data-bases/”.
Al-Khattaf S, Akhtar MN, Odedairo T, Aitani A, Tukur NM, Kubu M, Musilova-Pavlackova Z, Cejka J, Appl. Catal. A: Gen., 394(1-2), 176 (2011)
Min HK, Cha SH, Hong SB, ACS Catal., 2, 971 (2012)
Huang J, Jiang Y, Marthala VRR, Hunger M, J. Am. Chem. Soc., 130(38), 12642 (2008)
Min HK, Chidambaram V, Hong SB, J. Phys. Chem. C., 114, 1190 (2010)
Min HK, Hong SB, J. Phys. Chem. C., 115, 16124 (2011)
Xiong YS, Rodewald PG, Chang CD, J. Am. Chem. Soc., 117(37), 9427 (1995)
Corma A, Sastre E, J. Catal., 129, 177 (1991)
Palomares AE, Edermirth G, Lercher JA, J. Catal., 168(2), 442 (1997)
Svelle S, Olsbye U, Lillerud KP, Kolboe S, Bjorgen M, J. Am. Chem. Soc., 128(17), 5618 (2006)
Millini R, Perego C, Top. Catal., 52, 42 (2009)
Clark LA, Sierka M, Sauer J, J. Am. Chem. Soc., 126(3), 936 (2004)
Weitkamp J, Ernst S, Catal. Today., 19, 107 (1994)
Olson DH, Haag WO, ACS Symp. Ser., 248, 275 (1984)
Babu GP, Santra M, Shiralkar VP, Ratnasamy PJ, J.Catal., 100, 458 (1986)
Rane SJ, Chakrabarty DK, Appl. Catal., 75, 281 (1991)
Sastre E, Corma A, Jajula F, Figueras F, Perez-Pariente J, J.Catal., 126, 457 (1990)
Adair B, Chen CY, Wan KT, Davis ME, Micropor. Mater., 7, 261 (1996)
Jones CW, Zones SI, Davis ME, Micropor.Mesopor, Mater., 28, 471 (1999)
Jones CW, Zones SI, Davis ME, Appl. Catal. A: Gen., 181(2), 289 (1999)
Degnan TF, J. Catal., 216(1-2), 32 (2003)
Wei JJ, J. Catal., 76, 433 (1982)
Morin S, Gnep NS, Guisnet M, J. Catal., 159(2), 296 (1996)
Guisnet M, Gnep NS, Morin S, Micropor. Mesopor.Mater., 35-36, 47 (2000)
Chen NY, Kaeding WW, Dwyer FG, J. Am. Chem. Soc., 101, 6783 (1979)
Hong SB, Min HK, Shin CH, Cox PA, Warrender SJ, Wright PA, J. Am. Chem. Soc., 129(35), 10870 (2007)
Roger HP, Moller KP, O’Connor CT, Micropor. Mater., 8, 151 (1997)
Das J, Bhat YS, Halgeri AB, Catal. Lett., 23(1-2), 161 (1994)
Roger HP, Moller KP, O'Connor CT, J. Catal., 176(1), 68 (1998)
Park SH, Lee JH, Rhee HK, Korean J. Chem. Eng., 17(2), 198 (2000)
Cejka J, Kotrla J, Krejci A, Appl. Catal. A: Gen., 277(1-2), 191 (2004)
Chao KJ, Leu LJ, Zeolites., 9, 193 (1989)
Matsuda T, Asanuma M, Kikuchi E, Appl.Catal., 38, 289 (1988)
Wang I, Tsai TS, Huang ST, Ind. Eng. Chem. Res., 29, 2005 (1990)
Cartraoul P, Cointot A, Gnep NS, Guisnet M, Joly G, Tejada J, Appl. Catal., 21, 85 (1986)
Cejka J, Wichterlova B, Catal. Rev.-Sci. Eng., 44(3), 375 (2002)
Dumitriu E, Hulea V, Kaliaguine S, Huang MM, Appl. Catal. A: Gen., 135(1), 57 (1996)
Krejci A, Al-Khattaf S, Ali MA, Bejblova M, Cejka J, Appl. Catal. A: Gen., 377(1-2), 99 (2010)
Lee YK, Park SH, Rhee HK, Catal. Today, 44(1-4), 223 (1998)
Halgeri AB, Prasada Rao TSR, Stud. Surf. Sci. Catal., 24, 667 (1985)
Hulea V, Bilba B, Lupascu M, Dumitriu E, Nibou D, Lebaili S, Kessler H, Micropor. Mater., 8, 201 (1997)
Dumitriu E, Guimon C, Hulea V, Lutic D, Fechete I, Appl. Catal. A: Gen., 237(1-2), 211 (2002)
Fernandes LD, Monteiro JLF, Sousa-Aguiar EF, Martinez A, Corma A, J. Catal., 177(2), 363 (1998)
Moreau F, Bernard S, Gnep NS, Lacombe S, Merlen E, Guisnet M, J. Catal., 202(2), 402 (2001)
Moreau F, Moreau P, Gnep NS, Magnoux P, Lacombe S, Guisnet M, Micropor. Mesopor. Mater., 90, 327 (2006)
Robschlager KH, Christoffel EG, Ind. Eng. Chem. Prod. Res.Dev., 18(4), 347 (1979)
Arsenova N, Haag WO, Karge HG, Stud. Surf. Sci. Catal., 94, 441 (1995)
Weiβ U, Weihe M, Hunger M, Karge HG, Weitkamp J, Stud. Surf. Sci. Catal., 105, 973 (1997)
Arsenova-Hartel N, Bludau H, Haag WO, Karge HG, Micropor. Mesopor. Mater., 35-36, 113 (2000)
Huang J, Jiang YJ, Marthala VRR, Bressel A, Frey J, Hunger M, J. Catal., 263(2), 277 (2009)
De Vos DE, Ernst S, Perego C, O’Connor CT, Stocker M, Micropor. Mesopor. Mater., 56, 185 (2002)
Streitwieser A, Reif L, J. Am. Chem. Soc., 82, 5003 (1960)
Amelse JA, Stud. Surf. Sci. Catal., 38, 165 (1988)
Kim BH, Lee JG, Yim T, Kim HJ, Lee HY, Kim YG, Tetrahedron Lett., 47, 7727 (2006)
Millini R, Frigerio F, Bellussi G, Pazzuconi G, Perego C, Pollesel P, Romano U, J. Catal., 217(2), 298 (2003)
