Issue
Korean Journal of Chemical Engineering,
Vol.29, No.11, 1585-1590, 2012
Evaluation of electro-coagulation method for decolorization and degradation of organic dyes in aqueous solutions
This research has two parts: at first part electro coagulation (EC) method was used to remove the dye Direct Black 22 (DB22 (in aqueous media. All experiments were done in a 2 liter reactor with two electrodes made of steel (SS-304) as cathodes and one aluminum electrode as anode. Parameters affecting the process, such as anode material, electrolyte concentration, current density, initial pH of solution and the initial dye concentration, were investigated. Total amount of consumed energy was used for determination of optimal conditions. According to the results obtained for DB22 at optimized conditions, color and COD removal percentage were 92% and 85%, respectively. In addition, the current efficiency for aluminum anode in removal of DB22 was 90%. At the second part of the research work, color removal by EC for six different dyes was evaluated. The results showed that dye structure and anode type are very important factors on performance of the process.
[References]
  1. Khataee AR, Zarei M, Desalination, 273(2-3), 453, 2011
  2. Daneshvar N, Khataee AR, Ghadim ARA, Rasoulifard MH, J. Hazard. Mater., 148(3), 566, 2007
  3. Parsa JB, Rezaei M, Soleymani AR, J. Hazard. Mater., 168(2-3), 997, 2009
  4. Khataee AR, Kasiri MB, J. Mol. Catal. A-Chem., 328(1-2), 8, 2010
  5. Daneshvar N, Ashassi-Sorkhabi H, Tizpar A, Sep. Purif. Technol., 31(2), 153, 2003
  6. Merzouk B, Gourich B, Sekki A, Madani K, Chibane M, J. Hazard. Mater., 164(1), 215, 2009
  7. Fathinia M, Khataee AR, Zarei M, Aber S, J. Mol. Catal. A-Chem., 333(1-2), 73, 2010
  8. Can OT, Kobya M, Demirbas E, Bayramoglu M, Chemosphere., 62, 181, 2006
  9. Bennajah M, Gourich B, Essadki AH, Vial C, Delmas H, Chem. Eng. J., 148(1), 122, 2009
  10. Sengil IA, Ozacar M, J. Hazard. Mater., 16, 1369, 2009
  11. Daneshvar N, Oladegaragoze A, Djafarzadeh N, J. Hazard. Mater., 129(1-3), 116, 2006
  12. Irdemez S, Yildiz YS, Tosunoglu V, Sep. Purif. Technol., 52(2), 394, 2006
  13. Trompette JL, Vergnes H, J. Hazard. Mater., 163(2-3), 1282, 2009
  14. Phalakornkule C, Polgumhang S, Tongdaung W, Karakat B, Nuyut T, J. Environ. Manage., 9, 918, 2010
  15. Kobya M, Demirbas E, Can OT, Bayramoglu M, J. Hazard. Mater., 132(2-3), 183, 2006
  16. El-Ashtoukhy ESZ, Amin NK, J. Hazard. Mater., 179(1-3), 113, 2010
  17. Merzouk B, Gourich B, Sekki A, Madani K, Vial C, Barkaoui M, Chem. Eng. J., 149(1-3), 207, 2009
  18. Kim TH, Park C, Shin EB, Kim S, Desalination, 150(2), 165, 2002
  19. Kobya M, Hiz H, Senturk E, Aydiner C, Demirbas E, Desalination, 190(1-3), 201, 2006
  20. Khatibikamal V, Torabian A, Janpoor F, Hoshyaripour G, J. Hazard. Mater., 179(1-3), 276, 2010
  21. Emamjomeh MM, Sivakumar M, J. Environ. Manage., 90, 1204, 2009
  22. Kabdasli I, Arslan T, Olmez-Hanci T, Arslan-Alaton I, Tunay O, J. Hazard. Mater., 165(1-3), 838, 2009
  23. Nanseu-Njiki CP, Tchamango SR, Ngom PC, Darchen A, Ngameni E, J. Hazard. Mater., 168(2-3), 1430, 2009
  24. Tezcan Un U, Koparal AS, Bakir Ogutveren U, J. Environ.Manage., 90, 428, 2009
  25. Feng JW, Sun YB, Zheng Z, Zhang JB, Li S, Tian YC, J.Environ. Sci., 19, 1409, 2007
  26. Adhoum N, Monser L, Bellakhal N, Belgaied JE, J. Hazard. Mater., 112(3), 207, 2004
  27. Bektas N, Akbulut H, Inan H, Dimoglo A, J. Hazard. Mater., 106(2-3), 101, 2004
  28. Dimoglo HYAA, Cihan F, Karpuzcu M, Clean Technol.Environ. Policy., 6, 288, 2004
  29. Mohana S, Shrivastava S, Divecha J, Madamwar D, Bioresour. Technol., 99(3), 562, 2008
  30. Vasudevan S, Sozhan G, Ravichandran S, Jayaraj J, Lakshmi J, Sheela SM, Ind. Eng. Chem. Res., 47(6), 2018, 2008
  31. Chen GH, Sep. Purif. Technol., 38(1), 11, 2004
  32. Daneshvar N, Sorkhabi HA, Kasiri MB, J. Hazard. Mater., 112(1-2), 55, 2004
  33. APHA, 14th Ed., Standard Method for the Examination of Water and Wastewater, American Public Health Association (APHA), Washington, DC, 1997