Issue
Korean Journal of Chemical Engineering,
Vol.29, No.12, 1812-1816, 2012
Simultaneous removal of H2S and COS using Zn-based solid sorbents in the bench-scale continuous hot gas desulfurization system integrated with a coal gasifier
A bench-scale continuous hot gas desulfurization system using Zn-based solid sorbents was developed to remove H2S and COS simultaneously in a 110 Nm3/h of real coal-gasified syngas. The bench-scale unit, which consisted of a fast fluidized-bed type desulfurizer and a bubbling fluidized-bed type regenerator, was integrated with a 3 ton/day-scale coal gasifier installed at the Institute for Advanced Engineering. The solid sorbents, which consisted of 50 wt% of ZnO for sulfides sorption and 50 wt% of supporters for mechanical strength, were manufactured by a spray drying method and supplied by Korea Electric Power Corporation Research Institute. The bench-scale unit was designed to operate at the high temperature of above 500 ℃ and the high pressure of 19 kgf/cm2 gauge. Integration of the bench-scale unit with a coal gasifier was first performed to investigate the operation stability of the integrated system. And the long-term continuous operation above 30 h was performed to analyze the desulfurization performance of the bench-scale unit. The concentration of both H2S and COS in the syngas was measured by a continuous UV gas analyzer and an online gas chromatograph and that of both H2S and COS after desulfurization was measured by an online gas chromatograph. Through the above 30-h continuous operation, the sulfur removal reached up to 99.9%.
[References]
  1. Choi YC, Park TJ, Kim JH, Lee JG, Hong JC, Kim YG, Korean J. Chem. Eng., 18(4), 493, 2001
  2. Yi CK, Jo SH, Lee BH, Lee SY, Son JE, Jin GT, Korean J. Chem. Eng., 18(6), 1005, 2001
  3. Gupta R, Turk B, Lesemann M, 2009 Gasification Tecnlologies Conference, Colorado, USA, 2009
  4. Hornick M, Gardner B, 2011 Gasification Technologies Conference, San Francisco, USA, 2011
  5. Yi CK, Jo SH, Kwon HS, Kim KB, Chae HK, Jin GT, Son JE, Korean Chem. Eng. Res., 40, 246, 2002
  6. Jo SH, Park YC, Ryu HJ, Yi CK, 1st Asian Conference on Innovative Energy & Environmental Chemical Engineering, Sapporo, Japan, 2008
  7. Park YC, Jo SH, Lee SY, Yi CK, The 13th International Conference on Fluidization - New Paradigm in Fluidization Engineering, Kyeongju, Korea, 2010
  8. Jo SH, Park YC, Ryu HJ, Yi CK, Baek JI, 27th Pittsburgh Coal Conference, Pittsburgh, USA, 2010
  9. Yi CK, Son JE, Adv. Powder Technol., 21(2), 119, 2010