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Issue
Korean Journal of Chemical Engineering,
Vol.29, No.3, 396-403, 2012
Separation of sinigrin from Indian mustard (Brassica juncea L.) seed using macroporous ion-exchange resin
Wang T, Liang H, Yuan Q
Sinigrin is a major glucosinolate present in Indian mustard (Brassica juncea L.) seeds as the precursor of the anticancer compound allyl isothiocyanate. In the present study, the adsorption and desorption characteristics of six macroporous ion-exchange resins for the separation of sinigrin from crude aqueous extracts have been compared. The results indicated that D261 resin showed the best adsorption and desorption capacity to sinigrin, and its adsorption data fit best to the Freundlich isotherm. The dynamic adsorption/desorption experiments were carried out to optimize the separation process. After treatment with D261 resin in one run, the purity of sinigrin in the product was increased 15.57-fold from 3.75% to 58.37% with the recovery of 79.82%. Meanwhile, the separation effect of D261 resin was also supported by UV and IR. The separation process using macroporous ion-exchange resin in our paper provides a novel, rapid and economical method for separation of sinigrin.
Keywords: Sinigrin; Indian Mustard; Brassica juncea L.; Macroporous Ion-exchange resin; Separation
[References]
  1. Michael JG, Nutr., 24, 393, 2008
  2. Rangkadilok N, Nicolas ME, Bennett RN, Premier RR, Eagling DR, Taylor PWJ, Sci. Hortic., 96, 11, 2002
  3. Fahey JW, Zalcmann AT, Talalay P, Phytochemistry., 56, 5, 2001
  4. Isshiki K, Tokuoka K, Mori R, Chiba S, Biosci., Biotechnol., Biochem., 56, 1476, 1992
  5. Lin CM, Preston JF, Wei CI, J. Food Prot., 63, 727, 2000
  6. Hou DX, Fukuda M, Fujii M, Fuke Y, Cancer Lett., 161, 195, 2000
  7. Nomura T, Shinoda S, Yamori T, Sawaki S, Nagata I, Ryoyama K, Fuke Y, Cancer Detect. Prev., 29, 155, 2005
  8. Krul C, Humblot C, Philippe C, Vermeulen M, Vannuenen M, Havenaar R, Rabot S, Carcinogenesis., 23, 1009, 2002
  9. Du QZ, Fang J, Gao SJ, Zeng QY, Mo CH, Sep. Purif. Technol., 59(3), 294, 2008
  10. Charpentier N, Bostyn S, Coic JP, Ind. Crops. Prod., 8, 151, 1998
  11. Fahey JW, Wade KL, Stephenson KK, Chou FE, J. Chromatogr.A., 996, 85, 2003
  12. Rochfort S, Caridi D, Stintion M, Craige TV, Jones R, J.Chromatogr. A., 1120, 205, 2006
  13. Toribio A, Nuzillard JM, Renault JH, J. Chromatogr. A., 1170, 44, 2007
  14. Nobre C, Santos MJ, Dominguez A, Torres D, Rocha O, Peres AM, Rocha I, Ferreira EC, Teixeira JA, Rodrigues LR, Anal. Chim. Acta., 654, 71, 2009
  15. Ou S, Luo Y, Xue F, Huang C, Zhang N, Liu Z, J. Food Eng., 78, 1298, 2007
  16. Kiefer R, Holl WH, Ind. Eng. Chem. Res., 40(21), 4570, 2001
  17. Rengaraj S, Kim Y, Joo CK, Choi K, Yi J, Korean J. Chem. Eng., 21(1), 187, 2004
  18. Kim TY, Park SK, Cho SY, Kim HB, Kang Y, Kim SD, Kim SJ, Korean J. Chem. Eng., 22(1), 91, 2005
  19. Lee JW, Jung HJ, Moon H, Korean J. Chem. Eng., 14(4), 277, 1997
  20. Sherrington DC, Chem. Commun., 21, 2275, 1998
  21. Abrams IM, Millar JR, React. Funct. Polym., 35(1), 7, 1997
  22. Fu BQ, Liu J, Li H, Li L, Lee FSC, Wang XR, J. Chromatogr. A., 1089, 18, 2005
  23. Rangkadilok N, Nicolas ME, Bennett RN, Premier RR, Eagling DR, Taylor PWJ, Sci. Hortic., 96, 27, 2002
  24. Zagorodni AA, Kotova DL, Selemenev VF, React. Funct. Polym., 53, 157, 2002
  25. Rodrigues LA, da Silva MLCP, Desalination, 263(1-3), 29, 2010
  26. Wang YF, Gao HZ, Yeredla R, Xu HF, Abrecht M, J. Colloid Interface Sci., 305(2), 209, 2007
  27. Silva EM, Pompeu DR, Larondelle Y, Rogez H, Sep. Purif. Technol., 53(3), 274, 2007
  28. Zhang B, Yang RY, Zhao Y, Liu CZ, J. Chromatogr. B., 867, 253, 2008
  29. Baskaralingam P, Pulikesi M, Elango D, Ramamurthi V, Sivanesan S, J. Hazard. Mater., 128(2-3), 138, 2006
  30. Jung MW, Ahn KH, Lee YH, Kim KP, Insook RP, Rhee JS, Park JT, Paeng KJ, J. Chromatogr. A., 917, 87, 2001
  31. Traybal RE, Mass Transfer Operation, Tata McGraw Hill, Singapore, 1981
  33. Kuang PQ, Liang H, Yuan QP, Sep. Sci. Technol., 46(1), 179, 2011
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