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Issue
Korean Journal of Chemical Engineering,
Vol.28, No.11, 2178-2183, 2011
Visible light-irradiated degradation of alachlor on Fe-TiO2 with assistance of H2O2
Wantala K, Khemthong P, Wittayakun J, Grisdanurak N
0.1 Fe/Ti mole ratio of Fe-TiO2 catalysts were synthesized via solvothermal method and calcined at various temperatures: 300, 400, and 500 ℃. The calcined catalysts were characterized by XRD, N2-adsorption-desorption, UVDRS, XRF, and Zeta potential and tested for photocatalytic degradation of alachlor under visible light. The calcined catalysts consisted only of anatase phase. The BET specific surface area decreased with the calcination temperatures. The doping Fe ion induced a red shift of absorption capacity from UV to the visible region. The Fe-TiO2 calcined at 400 ℃ showed the highest photocatalytic activity on degradation of alachlor with assistance of 30 mM H2O2 at pH 3 under visible light irradiation. The degradation fitted well with Langmuir-Hinshelwood model that gave adsorption coefficient and the reaction rate constant of 0.683 L mg^(-1) and 0.136 mg/L·min, respectively.
Keywords: Solvothermal; Fe-TiO2; Visible Light; Alachlor; H2O2; Photocatalysis
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