Issue
Korean Journal of Chemical Engineering,
Vol.14, No.1, 23-29, 1997
THE NONLINEAR BEHAVIOR OF SURFACTANT-ACTIVATED ELECTRORHEOLOGICAL SUSPENSIONS
The nonlinear electrorheological (ER) behavior of nonionic surfactant-activated ER suspensions is in vestigated. The influence of three nonionic surfactants (Brij 30, GMO, and GTO) on the electrorheological (ER) response of various alumina/silicone oil suspensions shows similar behavior. The prevalent feature common to all formulations is that the yield stress, Ք0, initially increases with surfactant concentration, passes through a miximum, then decreases with surfactant concentration. The nonlinear behavior observed at large surfactant concentrations (i.e., τ0 = En, where n<2) arises from field-induced phase separation of a surfactant-rich phase as opposed to field-dependent conductivity of a homogeneous continuous phase.
[References]
  1. Anderson RA, "Electrorheological Fluids," (Tao, R., Ed.), World Scientific, Singapore, 81, 1992
  2. Anderson RA, Langmuir, 10(9), 2917, 1994
  3. Block H, Kelly JP, J. Phys. D: Appl. Phys., 21, 1661, 1988
  4. Brosseau C, J. Appl. Phys., 70, 5544, 1991
  5. Davis LC, Appl. Phys. Lett., 60, 319, 1992
  6. Deinega YF, Vinogradov GV, Rheol. Acta, 23, 636, 1984
  7. Felici N, Foulc JN, Atten P, "Electrorheological Fluids: Mechanisms, Properties, Technology, and Applications," (Tao, R. and Roy, G.D. Eds.), World Scientific, Singapore, 139, 1994
  8. Felici N, IEEE Trans. Electr. Insul., 1, 233, 1985
  9. Gast AP, Zukoski CF, Adv. Colloid Interface Sci., 30, 153, 1989
  10. Jordan TC, Shaw MT, IEEE Trans. Electr. Insul., 24, 849, 1989
  11. Kim YD, "Non-ionic Surfactant-Activated Electrorheological Suspensions," Ph.D. Thesis, U. of Wisconsin, 1996
  12. Klingenberg DJ, Zukoski CF, Langmuir, 6, 15, 1990
  13. Rosen MJ, "Surfactants and Interfacial Phenomena," 2nd ed., Wiley, New York, 1989
  14. Shulman ZP, Gorodkin RG, Korobko EV, Gleb VK, J. Non-Newton. Fluid Mech., 8, 29, 1981
  15. Weiss KD, Carlson JD, J. Intell. Sys. Struct., 4, 13, 1993
  16. Winslow WM, J. Appl. Phys., 20, 1137, 1949
  17. Zhu BY, Gu T, Adv. Colloid Interface Sci., 37, 1, 1991