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Issue
Korean Journal of Chemical Engineering,
Vol.28, No.4, 1126-1132, 2011
Efficient degradation of methylene blue dye by catalytic oxidation using the Na8Nb6O19·13H2O/H2O2 system
Liu C, Xu H, Li H, Liu L, Xu L, Ye Z
Na8Nb6O19·13H2O particles were synthesized by a simple hydrothermal method. The catalysts were characterized by X-ray diffraction (XRD), scanning electronic microscopy (SEM) and thermogravimetric and differential scanning (TG-DSC). The XRD and TG-DSC analyses indicated that Na8Nb6O19·13H2O was an intermediate hexaniobate during the preparation of NaNbO3 powders. Methylene blue (MB) dye degradation using Na8Nb6O19·13H2O/H2O2, Nb2O5/H2O2 and NaNbO3/H2O2 systems were investigated, respectively. Among the catalytic oxidation systems, Na8Nb6O19·13H2O showed the highest activity for degradation of MB in the presence of H2O2. The results indicated that the dye degradation efficiency could be 93.5% at 30 ℃ after 60 min in the presence of the Na8Nb6O19·13H2O/H2O2 system. It was also found that the degradation of MB over the catalytic systems followed pseudo-first-order kinetics, and the degradation rate was 0.02376 min.1 in the Na8Nb6O19·13H2O/H2O2 system, which was higher than that in the Nb2O5/H2O2 and NaNbO3/H2O2 systems. A possible mechanism for MB catalytic oxidation degradation using the Na8Nb6O19·13H2O H2O2 system was proposed.
Keywords: Na8Nb6O19·13H2O/H2O2; Methylene Blue; Degradation
[References]
  1. Wong MS, Chu WC, Sun DS, Huang HS, Chen JH, Tsai PJ, Lin NT, Yu MS, Hsu SF, Wang SL, Chang HH, Appl. Environ. Microbiol., 72, 6111, 2006
  2. Konstantinou IK, Albanis TA, Appl. Catal. B: Environ., 49(1), 1, 2004
  3. Tang J, Zou Z, Ye J, Chem. Mater., 16, 1644, 2004
  4. Baldrian P, Merhautova V, Gabriel J, Nerud F, Stopka P, Hruby M, Benes MJ, Appl. Catal. B: Environ., 66(3-4), 258, 2006
  5. Karcher S, Kornmuller A, Jekel M, Water Res., 36, 4717, 2002
  6. Gemeay AH, Mansour IA, El-Sharkawy RG, Zaki AB, J. Mol. Catal. A-Chem., 193(1-2), 109, 2003
  7. Costa RCC, Moura FCC, Ardisson JD, Fabris JD, Lago RM, Appl. Catal. B: Environ., 83(1-2), 131, 2008
  8. Feng JY, Hu XJ, Yue PL, Zhu HY, Lu GQ, Water Res., 37, 3776, 2003
  9. Chou S, Huang C, Chemosphere., 38, 2719, 1999
  10. de Souza WF, Guimaraes IR, Oliveira LCA, Guerreiro MC, Guarieiro ALN, Carvalho KTG, J. Mol. Catal. A-Chem., 278(1-2), 145, 2007
  11. Nyman M, Anderson TM, Provencio PP, Cryst. Growth Des., 9, 1036, 2009
  12. Roof IP, Park S, Vogt T, Rassolov V, Smith MD, Omar S, Nino J, zur Loye HC, Chem. Mater., 20, 3327, 2008
  13. Ding QP, Yuan YP, Xiong X, Li RP, Huang HB, Li ZS, Yu T, Zou ZG, Yang SG, J. Phys. Chem. C., 112, 18846, 2008
  14. Muthurajan H, Kumar HH, Samuel V, Gupta UN, Ravi V, Ceram. Int., 34, 671, 2008
  15. Li GQ, Kako T, Wang DF, Zou ZG, Ye JH, J. Solid State Chem., 180, 2845, 2007
  16. Chang YF, Yang ZP, Chao XL, Liu ZH, Wang ZL, Mater. Chem. Phys., 111(2-3), 195, 2008
  17. Atamanik E, Thangadurai V, J. Phys. Chem. C., 113, 4648, 2009
  18. Han JT, Liu DQ, Song SH, Kim Y, Goodenough JB, Chem. Mater., 21, 4753, 2009
  19. Katsumata K, Cordonier CEJ, Shichi T, Fujishima A, J. Am. Chem. Soc., 131(11), 3856, 2009
  20. Ke TY, Chen HA, Sheu HS, Yeh JW, Lin HN, Lee CY, Chiu HT, J. Phys. Chem. C., 112, 8827, 2008
  21. Ling CD, Avdeev M, Kutteh R, Kharton VV, Yaremchenko AA, Fialkova S, Sharma N, Macquart RB, Hoelzel M, Gutmann M, Chem. Mater., 21, 3853, 2009
  22. Oliveira LCA, Goncalves M, Guerreiro MC, Ramalho TC, Fabris JD, Pereira MC, Sapag K, Appl. Catal. A: Gen., 316(1), 117, 2007
  23. Bayot D, Tinant B, Devillers M, Catal. Today, 78(1-4), 439, 2003
  24. Passoni LC, Siddiqui MRH, Steiner A, Kozhevnikov IV, J. Mol. Catal. A-Chem., 153(1-2), 103, 2000
  25. Compton OC, Osterloh FE, J. Phys. Chem. C., 113, 479, 2009
  26. Feliczak A, Walczak K, Wawrzynczak A, Nowak I, Catal. Today., 140, 23, 2009
  27. Silva AC, Oliveira DQL, Oliveira LCA, Anastacio AS, Ramalho TC, Lopes JH, Carvalho HWP, Torres CER, Appl. Catal. A: Gen., 357(1), 79, 2009
  28. Wu SY, Zhang W, Chen XM, J. Mater. Sci. Mater. Electron., 21, 450, 2010
  29. Lanfredi S, Dessemond L, Martins Rodrigues AC, J. Eur.Ceram. Soc., 20, 983, 2000
  30. Zhu HY, Zheng ZF, Gao XP, Huang YN, Yan ZM, Zou J, Yin HM, Zou QD, Kable SH, Zhao JC, Xi YF, Martens WN, Frost RL, J. Am. Chem. Soc., 128(7), 2373, 2006
  31. Yang SJ, He HP, Wu DQ, Chen D, Liang XL, Qin ZH, Fan MD, Zhu JX, Yuan P, Appl. Catal. B: Environ., 89(3-4), 527, 2009
  32. Lopez A, Bozzi A, Mascolo G, Kiwi J, J. Photochem. Photobio., A: Chem., 156, 121, 2003
  33. Deng JH, Jiang JY, Zhang YY, Lin XP, Du CM, Xiong Y, Appl. Catal. B: Environ., 84(3-4), 468, 2008
  34. Kozlov YN, Nizova GV, Shul'pin GB, J. Mol. Catal. A-Chem., 227(1-2), 247, 2005
  35. Khaliullin RZ, Bell AT, Head-Gordon M, J. Phys. Chem. B, 109(38), 17984, 2005
  36. Shishido T, Miyatake T, Teramura K, Hitomi Y, Yamashita H, Tanaka T, J. Phys. Chem. C., 113, 18713, 2009
[Cited By]
  1. Ciobanu G, Harja M, Rusu L, Mocanu AM, Luca C, Korean Journal of Chemical Engineering, 31(6), 1021, 2014
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