Issue
Korean Journal of Chemical Engineering,
Vol.13, No.2, 115-122, 1996
MODIFIED RESPONSE SURFACE METHODOLOGY(MRSM) FOR PHASE EQUILIBRIUM-THEORETICAL BACKGROUND
The effect of molecular interaction energy among different molecules in the mixed solutions significantly depends upon the size of individual molecule size and molecular arrangement. In order to compensate these effects on the existing method, a new method of representing the relationship of temperature and compositions of each phase(vapor and liquid phases in equilibrium) and azeotropic mixture is proposed. The optimized models of the RSM(response surface methodology) and MRSM(modified response surface methodology) are briefly described. The applications of these models to the solution thermodynamics are also explained.
[References]
  1. Abram DS, Prausnitz JM, AIChE J., 21, 116, 1975
  2. Box GEP, Biometrics, 10, 16, 1954
  3. Chao KC, Hougen OA, Chem. Eng. Sci., 7, 246, 1958
  4. Fredenslund A, Gmehling J, Rasmussen P, "Vapor-Liquid Equilibrium Using UNIFAC," Elsevier, Amsterdam, 1979
  5. Gmehling J, Onken U, Arlt W, "Vapor-Liquid Equilibrium Data Collection," Chemistry Data Series, DECHEMA, Germany, 1981
  6. Ha DM, Park JC, HWAHAK KONGHAK, 29(3), 284, 1991
  7. Hill WJ, Hunter WG, Technometric, 8, 571, 1966
  8. Hilm AK, Ellis SRM, Barker PE, Br. Chem. Eng., 15, 1321, 1970
  9. Hu Y, Liu HL, Prausnitz JM, Fluid Phase Equilib., 95, 73, 1994
  10. Kim MG, Ha DM, Park JC, Korean J. Chem. Eng., 12(1), 39, 1995
  11. King MB, "Phase Equilibrium in Mixtures," Pergamon Press, London, 1969
  12. Kojima K, Tochigi K, "Prediction of Vapor-Liquid Equilibria by the ASOG Method," Elsevier, Amsterdam, 1979
  13. Lee LL, Starling KE, Fluid Phase Equilib., 21, 77, 1985
  14. Lee LL, "Molecular Thermodynamics of Nonideal Fluids," Butterworths, Boston, 1988
  15. Lu BCY, Li JCM, Ting TW, Ind. Eng. Chem., 51, 219, 1959
  16. Malesinski W, "Azetropy and Other Theoretical Problems of Vapor-Liquid Equilibrium," Polish Scientific Publishers, Warszawa, 1965
  17. Nagata I, J. Chem. Eng. Data, 7, 461, 1962
  18. Park JC, "Prediction of the Activity Coefficients for Non-Ideal Liquid Mixtures," The 183rd Meeting of European Federation of Chem. Engineers at Helsinki, Finland, June, 1977
  19. Park JC, "Estimation of the Activity Coefficients for Non-Ideal Liquid Mixtures," Theses Collection, Kyung Hee Univ., 9, 555, 1979
  20. Park JC, "Estimation of the Activity Coefficients for Non-Ideal Liquid Mixtures: Effect of Variables of TPTT Equations on Response Model of Molecular Interaction Energy Parameters of Two and Three Component Systems," Theses Collection, Kyung Hee Univ., 11, 139, 1982
  21. Park JC, "Estimation of Activity Coefficients for Non-Ideal Liquid Mixtures: Selection of Response Surface Model by Means of Response Surface Methodology for Multicomponent System," PACHEC Proceeding, 2, 340, 1983
  22. Park JC, "Estimation of Multicomponent Phase Surface by Means of Response Surface Methodology and Comparison of Fitting for 3 & 4 Component Systems," Kyung Hee Univ. Publication, Seoul, Korea, 1985
  23. Park JC, "The Partial Molar Interaction Energy of the TPTT Equation," Theses Collection, Kyung Hee Univ., 15, 239, 1986
  24. Park JC, "Representation of Multiple Phase Response Surface by Means of Computer Graphics," Kyung Hee Univ. Publication, Seoul, Korea, 1987
  25. Park JC, Kim MG, HWAHAK KONGHAK, 26(2), 194, 1988
  26. Park JC, "Mandang Park, Jong-Chul, Ph.D., Full Professor, 60th Birthday, Anniversary Theses Collection," Munyangsa, Seoul, Korea, 1988
  27. Park JC, Ha DM, Kim MG, "Estimation Methodology of Multicomponent Phase Equilibria by Group-Group and Interaction Parameters," Proc. 5th APCChE Congress, 4a-14, Kuala Lumpur. Malaysia, 1990
  28. Park JC, "Theory and Practice of Modified Response Surface Methodology in Phase Equilibrium," 68th Annual Meeting of the Korean Chemical Society, Changwon, Korea, 1991
  29. Park JC, "Mandang Park, Jong Chul, Ph.D. Honorable Retirement Commemoration Theses Collection," Munyangsa, Seoul, Korea, 1992
  30. Prausnitz JM, Lichtenthaler RN, deAzevedo EG, "Molecular Thermodynamics of Fluid Phase Equilibria," 2nd Ed., Prentice-Hall Inc., Englewood Cliffs, N.J., 1986
  31. Redlich O, Kister AT, J. Chem. Phys., 15, 849, 1947
  32. Reid RC, Praustniz JM, Poling PE, "The Properties of Gases and Liquids," 3rd Ed., McGraw-Hill, New York, 1986
  33. Renon H, Prausnitz JM, AIChE J., 14, 135, 1968
  34. Shin HS, Park JC, "Comparison of Methods of Estimating VLE by Means of the Wilson, NRTL, UNIQUAC Equations for Ternary Systems by Computer Graphics," Theses Collection, Kyung Hee Univ., 17, 497, 1988
  35. Wilson GM, J. Am. Chem. Soc., 86, 127, 1964
  36. Wisniak J, Tamir A, J. Chem. Eng. Data, 22, 253, 1977