Print: | ISSN 0256-1115 |
Online: | ISSN 1975-7220 |
Korean Journal of Chemical Engineering,
Vol.12, No.5, 593-596, 1995 THE CRYSTALLINE QUALITY OF Si FILMS PREPARED BY THERMAL-AND PHOTO-CVD AT LOW TEMPERATURES
Various silicon films were prepared by thermal-and UV photo-CVD processes. The reactants were SiH4, SiH2F2, SiF4, and H2. Silicon films grown at temperatures below 500℃ were either amorphous or crystalline depending on the process conditions, and the growth rates ranged between 5 and 80Å/min. The film obtained by photo-CVD using fluoro-silanes as the reactants was crystalline even when the deposition temperature was as low as 250℃. Analyses of the film by RBS, SIMS, XRD, and ex-situ IR indicated that the film grown from silanes was contaminated by oxygen and other impurities while one from fluoro-silanes was relatively low in the impurities. The film crystallinity was higher in the latter case than the former.
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