Issue
Korean Journal of Chemical Engineering,
Vol.12, No.5, 535-539, 1995
CORRELATION OF THE VAPOR-LIQUID EQUILIBRIA OF CFC, HCFC AND FC MIXTURES : CRITICAL EVALUATION OF MIXING RULES
The vapor-liquid equilibrium data of the binary CFC, HCFC, and FC mixtures were correlated with the Soave-Redlich-Kwong equation of state incorporated with some types of mixing rules; the conventional one fluid, Panagiotopoulos-Reid and modified Huron-Vidal second order mixing rules. The Panagiotopoulos-Reid mixing rule showed the superiority to the other models in predicting the VLE of freon mixtures with low errors. The modified Huron-Vidal second order model showed good convergence ability, which was due to its robustness to parameter variation.
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