Print: | ISSN 0256-1115 |
Online: | ISSN 1975-7220 |
Korean Journal of Chemical Engineering,
Vol.11, No.3, 211-215, 1994 TRANSPORT PHENOMENA IN GAS PERMEATION THROUGH GLASSY POLYMER MEMBRANES WITH CONCENTRATION-DEPENDENT SORPTION AND DIFFUSION PARAMETERS
The modified dual-mode mobility model for permeation of a gas in glassy polymer membranes was combined with the extended dual-mode sorption model to take account of the plasticization effect of sorbed gas molecules on both sorption and diffusion processes. The combined model was further simplified by the introduction of a concentration of the mobile gas species. However, the observed pressure dependence of mean permeability coefficients of carbon dioxide in methylme-thacrylate-n-butyl acrylate copolymer and polymethylmethacrylate films at 30℃ and also that of oxy-gen in a polycarbonate film at 50℃ and 60℃ showed that a plasticization action of sorbed gas species has an influence on the diffusion process rather than on the sorption process, that is, were simulated by the modified dual-mode mobility model combined with the conventional dual-mode sorption model.
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