| Issue |
Korean Journal of Chemical Engineering,
Vol.28, No.1, 252-255, 2011
Vol.28, No.1, 252-255, 2011
Calculation of thermodynamic quantities for carbon tetrachloride (CCl4) close to the III-IV phase transition
We calculate the thermal expansion α(p), isothermal compressibility κ(T) and the specific heat, C(p)-C(v), as a function of pressure using the observed V-P data at room temperature close to the III-IV phase transition in CCl(4). Calculated κ(T), α(p) and C(p)-C(v) decrease as the pressure increases from phase III to phase IV in this molecular crystal system, as expected. On the basis of our calculations of the κ(T), α(p) and C(p)-C(v), the Pippard relations are established close to the III-IV phase transition in CCl(4), which can be verified experimentally.
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