| Issue |
Korean Journal of Chemical Engineering,
Vol.8, No.1, 53-55, 1991
Vol.8, No.1, 53-55, 1991
RODIUM-CATALYZED CARBONYLATION OF METHYL GLYCOLATE AND GLYCOLIC ACID
Catalytic carbonylation of methyl glycolate in the presence of a homogeneous Rh com-plex and an iodide promoter yields actoxy methyl acetate and acetic acid. Carbonylation of glycolic acid under the same conditions gives acetic acid and CO2, probably from decomposition of the maloinc acid intermediate.
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