Issue
Korean Journal of Chemical Engineering,
Vol.6, No.2, 131-137, 1989
ONE-FLUID MIXING RULES FOR CUBIC EQUATIONS OF STATE : III. SOLUBILITY OF PURE SOLIDS IN SUPERCRITICAL MIXED SOLVENTS
Three cubic equations of state are carefully examined to evaluate their capability for correlating the solubility of pure solids in supercritical mixed solvents. After obtaining the pure solute-solvent interaction parameters, the solid solute-cosolvent interaction parameters were directly calculated from the experimental ternary solubility data. The Redlich-Kwong, Soave, and Peng-Robinson equations of state correlate well the solubility data of 32 ternary systems producing AAD(%) errors of 12.54, 12.50 and 12.67% respectively.