Issue
Korean Journal of Chemical Engineering,
Vol.26, No.6, 1813-1820, 2009
Preparation of molecularly imprinted polymer membrane with blending trimethoprim-MIP and polysulfone and its transport properties
An imprinted polymer membrane (IPM) with blending trimethoprim-MIP and polysulfone (PSF) was prepared by bulk polymerization and membrane preparation. In the process of the preparation, the influencing factors on membrane structure and properties, such as the concentration of PSF, the content of additive polyethelene glycol (PEG) and TMP imprinted polymer, were thoroughly investigated by scanning electron microscopy (SEM) and the membrane performance tester. The adsorption properties and selectivity properties of IPM to different substrates were estimated by using the method of equilibrium binding experiments. Finally, the transport properties of the membranes were investigated by using the diffusion chambers. The results showed that the imprinted polymer membrane exhibited a high selectivity for TMP.
[References]
  1. Ye L, Ramstrom O, Mosbach K, Anal. Chem., 70, 2789, 1998
  2. Jin Y, Choi DK, Row KH, Korean J. Chem. Eng., 25(4), 816, 2008
  3. Percival CJ, Stanley S, Galle M, Braithwaite A, Newton MI, McHale G, Hayes W, Anal. Chem., 73, 4225, 2001
  4. Liu Q, Zhou Y, Liu Y, Chin. J. Anal. Chem., 27, 1341, 1999
  5. Wulff G, Sarhan A, Zabrocki K, Tetrahedron Lett., 44, 4329, 1973
  6. Yoshikawa M, Izumi J, Kitao T, React. Funct. Polym., 42(1), 93, 1999
  7. Yoshikawa M, Izumi J, Guiver MD, Robertson GP, Macromol. Mater. Eng., 286, 52, 2001
  8. Wang HY, Kobayashi T, Fukaya T, Fujii N, Langmuir, 13(20), 5396, 1997
  9. Ramamoorthy M, Ulbricht M, J. Membr. Sci., 217(1-2), 207, 2003
  10. Malaisamy R, Ulbricht M, Sep. Purif. Technol., 39(3), 211, 2004
  11. Kondo Y, Yoshikawa M, Analyst, 126, 871, 2001
  12. Marx-Tibbon S, Willner I, J. Chem. Soc., Chem. Commun., 10, 1261, 1994
  13. Mathewkrotz J, Shea KJ, J. Am. Chem. Soc., 118(34), 8154, 1996
  14. Yang Z, Xu Z, Bing N, Chem. Ind. Eng. Prog., 25, 131, 2006
  15. He X, He G, Zeng B, Sun H, Yang H, Chen S, Zhou H, Journal of Xiamen University (Natural Science), 40, 495, 2001
  16. Zhang Y, Technology of Water Treatment, 27, 99, 2001
  17. Zhou J, He X, Yang W, Shi H, Chemical Journal of Chinese Universities, 19, 1388, 1998
  18. Hawkins DM, Trache A, Ellis EA, Stevenson D, Holzenburg A, Meininger GA, Reddy SM, Biomacromolecules, 7(9), 2560, 2006
  19. Jin Y, Row KH, Korean J. Chem. Eng., 22(2), 264, 2005
  20. Ferrer I, Lanza F, Tolokan A, Horvath V, Sellergren B, Horvai G, Barcelo D, Anal. Chem., 72, 3934, 2000
  21. Stevenson D, Trends in Ana1ytical Chemistry, 18, 154, 1999