Print: | ISSN 0256-1115 |
Online: | ISSN 1975-7220 |
Korean Journal of Chemical Engineering,
Vol.26, No.6, 1754-1758, 2009 High-pressure vapor-liquid equilibrium measurement for the binary mixtures of carbon dioxide+n-butanol
High-pressure vapor-liquid equilibrium data for the binary mixtures of CO2+n-butanol were measured at various isotherms of (313.15, 323.15, 333.15 and 343.15) K, respectively. The equilibrium compositions of vapor and liquid phases and pressures at each temperature were measured in a circulation-type equilibrium apparatus. To facilitate easy equilibration, both vapor and liquid phases were circulated separately in the experimental apparatus and the equilibrium
composition was analyzed by an on-line gas chromatograph. The experimental data were compared with literature results and correlated with the Peng-Robinson (PR) equations of state using the Wong-Sandler mixing rules. Calculated results with the PR EOS showed good agreement with our experimental data.
Keywords:
High-pressure VLE; Carbon Dioxide; n-Butanol; Peng-Robinson Equation of State; Wong-Sandler Mixing Rule; SCORR
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