Issue
Korean Journal of Chemical Engineering,
Vol.26, No.4, 1009-1015, 2009
CO2 gasification of Thai coal chars: Kinetics and reactivity studies
Abstract.Two sized fractions (<75 μm and 150-250 μm) of Ban Pu lignite A and Lampang subbituminous B coals were pyrolyzed in a drop tube fixed bed reactor under nitrogen atmosphere at 500-900 ℃. Gasification of coal chars with excess carbon dioxide was then performed at 900-1,100 ℃. The result was analyzed in terms of reactivity index, reaction rate and activation energy. It was found that chars at lower pyrolysis temperature had highest carbon conversion, and for chars of the same sized fraction and at the same pyrolysis temperature, reactivity indices increased with gasification temperature. The lower rank Ban Pu lignite A had higher Rs values than higher rank Lampang subbituminous B coals. Smaller chars from both coals had higher Rs values, due to the higher ash content. At present, it can be concluded that, within the gasification temperature range studied, gasification rates of chars obtained at various pyrolysis temperatures showed a linear correlation with temperature. However, additional experiment is needed to verify the correlation.
[References]
  1. Ye DP, Agnew JB, Zhang DK, Fuel, 77(11), 1209, 1998
  2. van Heek K, Mulen HJ, Fuel, 64, 1405, 1985
  3. Samaras P, Diamadopoulos E, Sakellaropoulos GP, Fuel, 75, 1108, 1996
  4. Liu H, Kaneko M, Luo C, Kato S, Kojima T, Fuel, 82, 523, 2003
  5. Cai HY, Guell AJ, Chatzakis IN, Lim JY, Dugwell DR, Kandiyoti R, In: Pajares JA, Tascon JMD, editors, Coal Science: Elsevier, 515, 1995
  6. Sinag A, Sinek K, Teke AT, Misirlioglu Z, Canel M, Wang L, Chem. Eng. Process., 42(12), 1027, 2003
  7. Matsuoka K, Akiho H, Xu W, Gupta R, Wall TF, Tomita A, Fuel, 84, 63, 2005
  8. Ng SH, Fung DP, Kim S, Fuel, 67, 700, 1988
  9. Sekine Y, Ishikawa K, Kikuchi E, Matsukata M, Akimoto A, Fuel, 85, 122, 2006
  10. Johnson JL, Kinetics of coal gasification, John Wiley & Sons, New York, 1979
  11. Ahn DH, Gibbs BM, Ko KH, Kim JJ, Fuel, 80, 1651, 2001
  12. Kajitani S, Hara S, Matsuda H, Fuel, 81, 539, 2002
  13. Kajitani S, Suzuki N, Ashizawa M, Hara S, Fuel, 85, 163, 2006
  14. Levenspiel O, Chemical reactions engineering, John Wiley & Sons, New York, 1999
  15. Park HY, Ahn DH, Korean J. Chem. Eng., 24(1), 24, 2007
  16. ASTM Standard, D2013 - 86, Preparing coal samples for analysis, American Society for Testing and Materials, U.S.A., 2000
  17. Luo C, Watanabe T, Nakamura M, Uemiya S, Kojima T, Fuel, 80(2), 233, 2001
  18. Sun Q, Li W, Chen H, Li B, Fuel, 83, 1787, 2004
  19. Ochoa J, Cassanello MC, Bonelli PR, Cukierman AL, Fuel Process. Technol., 74(3), 161, 2001
  20. Arenillas A, Pevida CF, Rubiera, Pis JJ, Fuel, 82, 2001, 2003