Korean Journal of Chemical Engineering, Vol.25, No.6, 1546-1552, 2008
Hydrothermal synthesis of zeolite L in a Na+/K+ mixed alkali system
Zeolite L was prepared from the substrate system of Na2O-K2O-Al2O3-SiO2-H2O at temperatures of 373-443 K by hydrothermal crystallization. The influence of various synthesis parameters such as the concentration ratios of the components, starting raw materials, synthesis temperature, gel aging, and stirring on the crystallization was investigated. Investigations revealed that the crystallinity of zeolite L crystals depends on molar ratios of the components such as SiO2/Al2O3, (K2O+Na2O)/SiO2, Na2O/(K2O+Na2O), and H2O/(K2O+Na2O). Pure and highly crystalline zeolite L could be obtained from a gel with the molar composition 5.4K2O-5.7Na2O-Al2O3-30SiO2-500H2O after 24 h at 443 K. It was found that the silica source affected the crystal size of zeolite L, and as the synthesis temperature increased, the average crystal size became larger. The crystal size could be decreased significantly by stirring the gel or subjecting the substrate mixture to an aging treatment at room temperature prior to the hydrothermal treatment. Thermal stability of the zeolite L crystals obtained was also briefly investigated.
[References]
Baerlocher C, Meier WM, Olson DH, Atlas of zeolite framework types, 5th ed., Elsevier, Amsterdam (2001)
Corma A, Garcia H, Eur. J. Inorg. Chem., 1143 (2004)
Bhat SD, Niphadkar PS, Gaydhankar TR, Awate SV, Belhekar AA, Joshi PN, Micropor. Mesopor. Mater. , 76 , 81, 2004
Bhat SD, Chaphekar GM, Niphadkar PS, Gaydhankar TR, Bokade VV, Joshi PN, Stud. Surf. Sci. Catal. , 154 , 233, 2004
Holzl M, Mintova S, Bein T, Stud. Surf. Sci. Catal. , 158 , 11, 2005
Lee YJ, Lee JS, Yoon KB, Micropor. Mesopor. Mater. , 80 , 237, 2005
Su BL, Norberg V, Hansenne C, de Mallmann A, Adsorption , 6 , 61, 2000
Su BL, Norberg V, Hansenne C, Langmuir , 16 (3), 1132, 2000
Joshi PN, Joshi UD, Kim TH, Kim KI, Shiralkar VP, Adsorption , 7 , 279, 2001
Larlus O, Tosheva L, Holzl M, Mintova S, Metzger T, Valtchev VP, Stud. Surf. Sci. Catal. , 158 , 367, 2005
Pechar TW, Kim S, Vaughan B, Marand E, Tsapatsis M, Jeong HK, Cornelius CJ, J. Membr. Sci. , 277 (1-2), 195, 2006
Pechar TW, Kim S, Vaughan B, Marand E, Baranauskas V, Riffle J, Jeong HK, Tsapatsis M, J. Membr. Sci. , 277 (1-2), 210, 2006
Bhat SD, Aminabhavi TM, J. Membr. Sci. , 306 , 173, 2007
Arcoya A, Seoane XL, Grau JM, Appl. Surf. Sci. , 205 (1-4), 206, 2003
Grau JM, Seoane XL, Arcoya A, Catal. Lett. , 83 (3-4), 247, 2002
Jongpatiwut S, Sackamduang P, Rirksomboon T, Osuwan S, Resasco DE, J. Catal. , 218 (1), 1, 2003
Jongpatiwuta S, Trakarnroek S, Rirksomboon T, Osuwan S, Resasco DE, Catal. Lett. , 100 (1-2), 7, 2005
Nagamatsu S, Inomata M, Kishida M, Wakabayashi K, J. Jpn. Petrol. Inst. , 44 , 351, 2001
Jacobs G, Alvarez WE, Resasco DE, Appl. Catal. A: Gen. , 206 (2), 267, 2001
Kale SM, Singh AP, J. Mol. Catal. A-Chem. , 184 (1-2), 399, 2002
Alvarez WE, Resasco DE, Catal. Lett. , 8 , 53, 1991
Pan H, Wei G, Yuan H, Huo Q, Li Q, Pan X, Wang W, Yu X, Stud. Surf. Sci. Catal. , 170 , 1392, 2007
Calzaferri G, Huber S, Maas H, Minkowski C, Angew. Chem. Int. Ed. , 42 , 3732, 2003
Bruhwiler D, Calzaferri G, C.R. Chimie , 8 , 391, 2005
Minkowski C, Calzaferri G, Angew. Chem. Int. Ed. , 44 , 5325, 2005
Li H, Devaux A, Popovic Z, Cola LD, Calzaferri G, Micropor. Mesopor. Mater. , 95 , 112, 2006
Ko YS, Ahn WS, Bull. Korean Chem. Soc. , 20 , 173, 1999
Ko YS, Ahn WS, Powder Technol. , 145 (1), 10, 2004
Joshi PN, Kotasthane AN, Shiralkar VP, Zeolites , 10 , 598, 1990
Garces LJ, Makwana VD, Hincapie B, Sacco A, Suib SL, J. Catal. , 217 (1), 107, 2003
Bajpai PK, Rao MS, Gokhale KVGK, Ind. Eng. Chem. Prod. Res. Develop. , 17 , 223, 1978
Ghamami L, Sand LB, Zeolites , 3 , 186, 1983
Ernst S, Jacobs PA, Martens JA, Weitkamp J, Zeolites , 7 , 458, 1987
Jacobs PA, Martens JA, Stud. Surf. Sci. Catal. , 33 , 58, 1987
Bhat RN, Kumar RJ, J. Chem. Tech. Biotech. , 48 , 453, 1990
Larlus O, Valtchev VP, Chem. Mater. , 16 , 3381, 2004
Mintova S, Valtchev V, Micropor. Mesopor. Mater. , 55 , 171, 2002
Ginter DM, Bell AT, Radke CJ, Zeolites , 12 , 742, 1992
Brock AA, Link GN, Poitras PS, Thompson RW, J. Mater. Chem. , 3 , 907, 1993
Hamilton KE, Coker EN, Sacco A, Dixon AG, Thompson RW, Zeolites , 13 , 645, 1993
Franklin KR, Lowe BM, Zeolites , 8 , 495, 1988
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