| Issue |
Korean Journal of Chemical Engineering,
Vol.25, No.5, 1004-1007, 2008
Vol.25, No.5, 1004-1007, 2008
Synthesis of cyclic carbonate from allyl glycidyl ether and CO2 over silica-supported ionic liquid catalysts prepared by sol-gel method
A silica-supported ionic liquid (Im-IL) was proven to be an effective heterogeneous catalyst for solventless synthesis of cyclic carbonate from allyl glycidyl ether (AGE) and carbon dioxide. Im-IL catalysts were prepared by sol-gel method. The synthesis of cyclic carbonate from AGE and CO2 was carried out in a batch autoclave reactor. Im-IL with shorter alkyl chain length showed the highest conversion of AGE, probably due to the steric hindrance for the formation of intermediate from the catalyst prepared by using longer alkyl chains and AGE. High temperature and high pressure were favorable for the conversion of AGE. Im-IL can be reused for the reaction up to two consecutive runs without any considerable loss of its catalytic activity.
[References]
- Shaikh AA, Sivaram S, Chem. Rev., 96(3), 951, 1996
- Sheldon R, Chem. Commun., 2399, 2001
- Zhao DB, Wu M, Kou Y, Min E, Catal. Today, 74(1-2), 157, 2002
- Wasserscheid P, Keim W, Angew. Chem.-Int. Edit., 39, 3772, 2000
- Dupont J, de Souza RF, Suarez PAZ, Chem. Rev., 102(10), 3667, 2002
- Marsh KN, Deev A, Wu ACT, Tran E, Klamt A, Korean J. Chem. Eng., 19(3), 357, 2002
- Song CE, Shim WH, Roh EJ, Choi JH, Chem. Commun., 1695, 2000
- Kim HS, Kim JJ, Kwon HN, Chung MJ, Lee BG, Jang HG, J. Catal., 205(1), 226, 2002
- Yasuda H, He LN, Sakakura T, J. Catal., 209(2), 547, 2002
- Kruper WJ, Dellar DV, J. Org. Chem., 60, 725, 1995
- Lu XB, Feng XJ, He R, Appl. Catal. A: Gen., 234(1-2), 25, 2002
- Yoshida M, Ihara M, Chem. Eur. J., 10, 2886, 2004
- Shen YM, Duan WL, Shi M, Eur. J. Org. Chem., 3080, 2004
- Kihara N, Hara N, Endo T, J. Org. Chem., 58, 6198, 1993
- Yano T, Matsui H, Koike T, Ishiguro H, Rujihara H, Yoshihara M, Maeshima T, Chem. Commun., 1129, 1997
- Yamaguchi K, Ebitani K, Yoshida T, Yoshida H, Kaneda K, J. Am. Chem. Soc., 121(18), 4526, 1999
- Kim DS, Ahn WS, Korean J. Chem. Eng., 20(1), 39, 2003
- Lee EH, Cha SW, Dharma MM, Choe Y, Ahn JY, Park DW, Korean J. Chem. Eng., 24(3), 547, 2007
- Mun NY, Kim KH, Park DW, Choe Y, Kim I, Korean J. Chem. Eng., 22(4), 556, 2005
- Yang HZ, Deng Y, Shi F, Chem. Commun., 274, 2002
- Calo V, Nacci A, Monopoli A, Fanizzi A, Org. Lett., 4, 2561, 2002
- Li FW, Xiao LF, Xia CG, Hu B, Tetrahedron Lett., 45, 8307, 2004
- Sun J, Fujita S, Arai M, J. Organomet. Chem., 690, 3490, 2005
- Palgunadi J, Kwon OS, Lee H, Bae JY, Ahn BS, Min NY, Kim HS, Catal. Today, 98(4), 511, 2004
- Aida T, Inoue S, J. Am. Chem. Soc., 105, 1304, 1983
- Paddock RL, Nguyen ST, J. Am. Chem. Soc., 123(46), 11498, 2001
- Shen YM, Duan WL, Shi M, J. Org. Chem., 68, 1559, 2003
- Kim HS, Kim JJ, Lee BG, Jung OS, Jang HG, Kang SO, Angew. Chem. Int. Ed. Engl, 39, 4096, 2000
- Li FW, Xia CG, Xu LW, Sun W, Chen GX, Chem. Commun., 2042, 2003
- Yu BS, Jeong ES, Kim KH, Park DW, Park SW, Lee JW, React. Kinet. Catal. Lett., 84(1), 175, 2005
- Mao LF, Li FW, Peng HH, Xia CG, J. Mol. Catal. A-Chem., 253(1-2), 265, 2006
- Olivier-Bourbigou H, Magna L, J. Mol. Catal. A-Chem., 182(1), 419, 2002
- Zhao DB, Wu M, Kou Y, Min E, Catal. Today, 74(1-2), 157, 2002
- Liotta CL, Starks CM, Halpen ME, Phase Transfer Catalysis, Chapman and Hall, New York, 1994
- Wang JQ, Yue XD, Cai F, He LN, Catal. Commun., 8, 167, 2007
- Nomura R, Kimura M, Teshima S, Ninagawa A, Matsuda H, Bull. Chem. Soc. Jpn., 55, 3200, 1982
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