Korean Journal of Chemical Engineering, Vol.25, No.5, 982-986, 2008
Alkylation of isobutane and butene using chloroaluminate imidazolium ionic liquid as catalyst: Effect of organosulfur compound additive
Abstract.Alkylation of isobutane and butene was carried out in a batch unit using 1-butyl-3-methylimidazolium chloride (BMIC)-aluminium (III) chloride (AlCl3) ionic liquid as catalyst. The effects of additives of butyl thioalcohol and ethyl thioether on the properties of ionic liquids for alkylation were investigated. Improvement of production distribution with high yields of isooctane and selectivity of TMP under a mild reaction condition was observed after addition of butyl thioalcohol. Moreover, the effects of operating variables were investigated and the mechanism was discussed.
[References]
Corma A, Martines A, Catal. Rev. , 35 , 483, 1993
Rao P, Vatcha SR, Oil Gas J. , 94 , 56, 1996
Albright LF, Oil Gas J. , 88 , 79, 1990
Marsh KN, Deev A, Wu ACT, Tran E, Klamt A, Korean J. Chem. Eng. , 19 (3), 357, 2002
Lee SH, Ha SH, You CY, Koo YM, Korean J. Chem. Eng. , 24 (3), 436, 2007
Huddleston JG, Willauer HD, Swatloski RP, Visser AE, Rogers RD, Chem. Commun. , 1765, 1998
Ju HY, Manju MD, Kim KH, Park SW, Park DW, Korean J. Chem. Eng. , 24 (5), 917, 2007
Lee EH, Cha SW, Dharma MM, Choe Y, Ahn JY, Park DW, Korean J. Chem. Eng. , 24 (3), 547, 2007
Mun NY, Kim KH, Park DW, Choe Y, Kim I, Korean J. Chem. Eng. , 22 (4), 556, 2005
Kim DS, Ahn WS, Korean J. Chem. Eng. , 20 (1), 39, 2003
Yeon SH, Kim KS, Choi S, Cha JH, Lee H, Oh J, Lee BB, Korean J. Chem. Eng. , 23 (6), 940, 2006
Choi S, Kim KS, Cha JH, Lee H, Oh JS, Lee BB, Korean J. Chem. Eng. , 23 (5), 795, 2006
Moon YH, Lee SM, Ha SH, Koo YM, Korean J. Chem. Eng. , 23 (2), 247, 2006
Lee SM, Chang WJ, Choi AR, Koo YM, Korean J. Chem. Eng. , 22 (5), 687, 2005
Kim KS, Demberelnyamba ND, Yeon SW, Choi S, Cha JH, Lee H, Korean J. Chem. Eng. , 22 (5), 717, 2005
Carmichael AJ, Haddleton DH, Bon SAF, Seddon KR, Chem. Commun. , 1237, 2000
Welton T, Chem. Rev. , 99 (3), 2071, 1999
Blanco CG, Banciella DC, Azpiroz MDG, J. Mol. Catal. A-Chem. , 253 (1-2), 203, 2006
Kumar P, Vermeiren W, Dath JP, Hoelderich WF, Appl. Catal. A: Gen. , 304 (1), 131, 2006
Xin H, Wu Q, Han M, Wang D, Jin Y, Appl. Catal. A: Gen. , 292 , 354, 2005
Xiao Y, Malhotra SV, J. Mol. Catal. A-Chem. , 230 (1-2), 129, 2005
Zhao ZK, Yuan B, Qiao WH, Li ZS, Wang GR, Cheng L, J. Mol. Catal. A-Chem. , 235 (1-2), 74, 2005
Chauvin Y, Hirschauer A, Olivier H, J. Mol. Catal. , 92 , 155, 1994
Ya KS, Namboodiri VV, Varma RS, Smirniotis PG, J. Catal. , 222 (2), 511, 2004
Schmerling L, J. Am. Chem. Soc. , 68 , 275, 1946
Zhao DB, Wu M, Kou Y, Min E, Catal. Today , 74 (1-2), 157, 2002
Berenblyum AS, Katsman EA, Karasev YZ, Appl. Catal. A: Gen. , 315 , 128, 2006
Brown HC, Pearsall H, Eddy LP, J. Am. Chem. Soc. , 72 , 5347, 1950
Evering BL, d’Ouville EL, Lien AP, Waugh RC, Ind. Eng. Chem. , 45 , 582, 1953
Roebuck AK, Evering BL, Ind. Eng. Chem. Res. Develop. , 9 , 76, 1970
Albright LF, Spalding MA, Kopser CG, Eckert RE, Ind. Eng. Chem. Res. , 27 , 386, 1988
Albright LF, Spalding MA, Faunce J, Eckert RE, Ind. Eng. Chem. Res. , 27 , 391, 1988
이전 논문 다음 논문
Result Search