Issue
Korean Journal of Chemical Engineering,
Vol.25, No.4, 738-743, 2008
Partial oxidation reforming of biomass fuel gas over nickel-based monolithic catalyst with naphthalene as model compound
With naphthalene as biomass tar model compound, partial oxidation reforming (with addition of O2) and dry reforming of biomass fuel gas were investigated over nickel-based monoliths at the same conditions. The results showed that both processes had excellent performance in upgrading biomass raw fuel gas. Above 99% of naphthalene was converted into synthesis gases (H2+CO). About 2.8 wt% of coke deposition was detected on the catalyst surface for dry reforming process at 750 oC during 108 h lifetime test. However, no coke deposition was detected for partial oxidation reforming process, which indicated that addition of O2 can effectively prohibit the coke formation. O2 can also increase the CH4 conversion and H2/CO ratio of the producer gas. The average conversion of CH4 in dry and partial oxidation reforming process was 92% and 95%, respectively. The average H2/CO ratio increased from 0.95 to 1.1 with the addition of O2, which was suitable to be used as synthesis gas for dimethyl ether (DME) synthesis.
[References]
  1. Corella J, Sanz A, Fuel Process. Technol., 86(9), 1021, 2005
  2. Wang T, Chang J, Fu Y, Zhang Q, Li Y, Korean J. Chem. Eng., 24(1), 181, 2007
  3. Cimino S, Di Benedetto A, Pirone R, Russo G, Catal. Today, 69(1-4), 95, 2001
  4. Cimino S, Pirone R, Lisi L, Appl. Catal. B: Environ., 35(4), 243, 2002
  5. BHARADWAJ SS, SCHMIDT LD, Fuel Process. Technol., 42(2-3), 109, 1995
  6. Dissenayake D, Rosynek MP, Kharas KCC, J. Catal., 132, 117, 1991
  7. Chyang CS, Lo KC, Wang KL, Korean J. Chem. Eng., 22(5), 774, 2005
  8. Lee SW, Nam SS, Kim SB, Lee KW, Choi CS, Korean J. Chem. Eng., 17(2), 174, 2000
  9. Hickman DA, Schmidt LD, Science, 259, 343, 1993
  10. Choudhary VR, Rajput AM, Prabhakar B, J. Catal., 139, 326, 1993
  11. Vernon PDF, Green MLH, Cheetham AK, Catal. Lett., 6, 181, 1990
  12. Corella J, Toledo M, Padilla R, Ind. Eng. Chem. Res., 43(10), 2433, 2004
  13. Corella J, Toledo JM, Padilla R, Ind. Eng. Chem. Res., 43(26), 8207, 2004
  14. Corella J, Toledo JM, Padilla R, Ind. Eng. Chem. Res., 44(7), 2036, 2005
  15. Nijhuis TA, Beers AEW, Vergunst T, Catal. Res., 43, 345, 2001
  16. Promaros E, Assabumrungrat S, Laosiripojana N, Praserthdam P, Tagawa T, Goto S, Korean J. Chem. Eng., 24(1), 44, 2007
  17. FUNG DPC, KIM SD, Korean J. Chem. Eng., 7(2), 109, 1990
  18. Isupova LA, Sadykov VA, Tikhov SF, Kimkhai ON, Kovalenko ON, Kustova GN, Ovsyannikova IA, Dovbii ZA, Kryukova GN, Rozovskii AY, Tretyakov VF, Lunin VV, Catal. Today, 27(1-2), 249, 1996
  19. Toledo JM, Corella J, Molina G, Ind. Eng. Chem. Res., 45(4), 1389, 2006
  20. Vaillant SR, Gastec AS, Catal. Today, 47(1-4), 415, 1999
  21. Wang TJ, Chang J, Cui XQ, Fuel Process. Technol., 87, 21, 2006
  22. Wang TJ, Chang J, Lv P, Energy Fuels, 19(2), 637, 2005
  23. Wang CG, Wang TJ, Lv PM, Journal of Fuel Chemistry and Technology, 35, 285, 2007