The copolymerization of phenyl glycidyl ether (PGE) and carbon dioxide was performed in the presence of ionic liquid catalyst. 1-Butyl-3-methyl imidazolium chloride, tetrabutylamouim chloride and 1-n-butylpyridinium chloride were used as catalyst for this reaction carried out in a batch reactor. All the ionic liquid catalysts showed good catalytic activity for the synthesis of polycarbonates with very low polydispersity, close to 1. The carbonate content, turnover number (TON), and average molecular weight of the copolymer were affected by the structure of the ionic liquid. High carbon dioxide pressure enhanced TON and carbonate content because of the increase of carbon dioxide absorption in PGE solution. ZnBr2 and a Zn-Co cyanide complex were also tested as a catalyst and/or cocatalyst for this reaction to compare their catalytic performance with the imidazolium salt ionic liquids.