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Issue
Korean Journal of Chemical Engineering,
Vol.25, No.4, 675-680, 2008
One-step synthesis of methylmethacrylate from methacrolein over Keggin-type heteropoly compounds
Guo X, Huang C, Chen B
One-step synthesis of methylmethacrylate (MMA) using heteropoly compounds (HPCs) as catalysts was demonstrated by feeding a mixture of methacrolein (MAL), air, water, nitrogen and MeOH (methanol). The HPCs with different counter-ions, such as H1.7Cs1.5Cu0.25As0.1PMo11VO40 (CsPMo11VO40), H1.7La0.7Cu0.25As0.1PMo11VO40 (LaPMo11VO40) and H1.7K1.5Cu0.25As0.1PMo11VO40 (KPMo11VO40), were studied in oxidation of MAL, esterification of methacrylic acid (MAA) and one-step synthesis of MMA from MAL, respectively. The selectivity of MAA was up to 45.7% and MMA was 44.6% with 93.3% MAL conversion over CsPMo11VO40.
Keywords: Methylmethacrylate; Methacrolein; HPCs; Counter Ions
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[Cited By]
  1. Xue J, Yin H, Li H, Zhang D, Jiang T, Yu L, Shen Y, Korean Journal of Chemical Engineering, 26(3), 654, 2009
  2. Sun P, Yu DH, Hu Y, Tang ZC, Xia JJ, Li H, Huang H, Korean Journal of Chemical Engineering, 28(1), 99, 2011
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