Composition Group Vector Space (CGVS) method for estimating melting and boiling point Tm, Tb of organic compound has been proposed, and the principle of this method has been elucidated. The models for estimating Tm, Tb have been established and the numerical values of relative parameters have been presented. The average percentage deviations of Tm, Tb estimation are 7.53 and 1.58, respectively, which show that the present method demonstrates significant improvement in applicability to predict the above properties, compared to conventional group methods.
Hall KR, Beach LB, selected values of properties of hydrocarbons and related compounds, Thermodynamics Research Center, Texas A & M university, Texas, 1981
Poling BE, Prausnitz JM, O’Connell JP, The properties of gases and liquids, 5th ed. McGraw-Hill Book Co., New York, 2001
West RC, Astle MJ, CRC handbook of data on organic compounds, CRC Press Inc., Boca Raton, FL, 1985
Majer V, Svoboda V, Enthalpies of vaporization of organic compounds, Blackwell Scientific Publication, Oxford, 1985