Korean Journal of Chemical Engineering, Vol.25, No.3, 419-422, 2008
Adiabatic runaway studies for methyl ethyl ketone peroxide with inorganic acids by vent sizing package 2
Methyl ethyl ketone peroxide (MEKPO) is an unstable material that is classified as an explosive substance. We evaluated MEKPO 10 mass% under mixing with three inorganic acids (6 N HNO3, 6 N H3PO4, and 6 N H2SO4) by adiabatic system of vent sizing package 2 (VSP2). Results from evaluation and testing indicated that these three inorganic acids could increase the degree of hazard while combined with pure MEKPO. Therefore, information on the hazards and phenomena of runaway reaction should be provided in order to lessen the degree of hazard.
[References]
Duh YS, Kao CS, Hwang HH, Lee WL, Trans. Inst. Chem. Eng. , 76B , 271, 1998
Chuang GS, Chao AC, Li HY, Korean J. Chem. Eng. , 21 (5), 963, 2004
Kim KS, Ko JW, Korean J. Chem. Eng. , 22 (1), 26, 2005
Nam YW, Park KS, Korean J. Chem. Eng. , 21 (2), 370, 2004
Arpornwichanop A, Kittisupakorn P, Hussain MA, Korean J. Chem. Eng. , 19 (2), 221, 2002
Chung TJ, Kim MC, Choi CK, Korean J. Chem. Eng. , 21 (1), 41, 2004
Kim EH, Kwon SW, Lee EH, Yoo JH, Korean J. Chem. Eng. , 19 (2), 305, 2002
Leila BD, Fierz HJ, Hazard. Mater. , 93 , 137, 2002
Parulekar SJ, Chem. Eng. Sci. , 53 (13), 2379, 1998
El-Sayed SA, J. Loss Prev. Process Ind. , 16 , 249, 2003
Kumar J, Nath S, Chem. Eng. Sci. , 52 (20), 3455, 1997
Kotoyori T, J. Hazard. Mater. , A64 , 1, 1999
Chervin S, Bodman GT, Thermochim. Acta , 392-393 , 371, 2002
Wang YW, Shu CM, Duh YS, Kao CS, Ind. Eng. Chem. Res. , 40 (4), 1125, 2001
Kossoy AA, Hofelich T, Pro. Saf. Prog. , 22 , 235, 2003
Kossoy AA, Akhmetshin Y, Pro. Saf. Prog. , DOI: 10.1002/prs.10189, 2007
Milas NA, Golubovic A, J. Am. Chem. Soc. , 82 , 5824, 1959
OSHA, Methyl Ethyl Ketone Peroxide Organic Method # 77, Occupational Safety and Health Administration, USA, 1989
Ingold KU, Chem. Rev. , 61 , 563, 1961
Farkaas, Passaqlied, J. Am. Chem. Soc. , 72 , 3333, 1950
Knorred G, Maizusz K, Emanueln M, Doklady Akad. Nauk S.S.S.R. , 123 , 123, 1958
Tiwari G, Bose P, Ind. Eng. Chem. Res. , 45 (1), 109, 2006
Kwon BG, Lee JH, Anal. Chem. , 76 , 6359, 2004
Black ED, Hayon E, J. Phys. Chem. , 74 , 3199, 1970
Maruthamuthu P, Neta P, J. Phys. Chem. , 82 , 710, 1978
Jiang PY, Katsumura Y, Domae M, Ishikawa K, Nagaishi R, Ishigure K, Yoshida Y, J. Chem. Soc.-Faraday Trans. , 88 , 3319, 1992
이전 논문 다음 논문
Result Search