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Issue
Korean Journal of Chemical Engineering,
Vol.25, No.1, 164-170, 2008
Liquid-liquid equilibrium for the quaternary system of o-xylene(1)+water(2) +butyric acid(3)+ethyl acetate(4) at 25 ℃ and atmospheric pressure
Ok DS, Kim YK, Park DW
The liquid-liquid equilibrium for the quaternary system of o-xylene(1)+water(2)+butyric acid(3)+ethyl acetate(4) was measured at 25 ℃ and atmospheric pressure. Binodal curves, tie-lines, distribution, and selectivity for the quaternary system have been determined in order to investigate the effect of binary solvents, o-xylene and ethyl acetate, on extracting butyric acid from aqueous solution. In addition, these experimental tie line data were also compared with the values predicted by the UNIFAC model. It is found that UNIFAC group interaction parameters used for LLE could not provide a good prediction.
Keywords: Liquid-Liquid Equilibrium; Quaternary System; Ternary System; UNIFAC; Butyric Acid
[References]
  1. Bilgin M, Kirbasular SI, Ozcan O, Dramur U, J. Chem. Eng. Data, 51(5), 1546, 2006
  2. Roychoudhury PK, Srivastava A, Sahai V, in: Fiechter (Ed.), A., Downstream processing biosurfactants/carotenoids, Springer, Berlin, 61, 1995
  3. Hartl J, Marr R, Sep. Sci. Technol., 28, 805, 1993
  4. Dramur U, Tatli B, J. Chem. Eng. Data, 38, 23, 1993
  5. Briones JA, Mullins JC, Thies MC, Ind. Eng. Chem. Res., 33(1), 151, 1994
  6. Arce A, Blanco A, Souza P, Vidal I, J. Chem. Eng. Data, 40(1), 225, 1995
  7. Fahim MA, Almuhtaseb SA, J. Chem. Eng. Data, 41(6), 1311, 1996
  8. Fahim MA, Almuhtaseb SA, Alnashef IM, J. Chem. Eng. Data, 42(1), 183, 1997
  9. Hano T, Matsumoto M, Ohtake T, Sasaki K, Hori F, Kawano Y, J. Chem. Eng. Jpn., 23(6), 734, 1990
  10. Dziedzak JD, Food Technol., 40, 8, 1986
  11. Sharpell FHJ, In Comprehensive biotechnology, Pergamon Press, Moo-Young M. editor, Microbial flavors and fragrances, New York, 965, 1985
  12. Vandak D, Zigova J, Sturdik E, Schlosser S, Proc. Biochem., 32, 245, 1997
  13. Zigova J, Sturdik E, Vandak D, Schlosser S, Proc. Biochem., 34, 835, 1999
  14. Fredenslund A, Vapor-liquid equilibria using, UNIFAC, Elsevier, Amsterdam, 1977
  15. Gupte PA, Danner RP, Ind. Eng. Chem. Res., 26, 2036, 1987
  16. Larsen BL, Rasmussen P, Fredenslund A, Ind. Eng. Chem. Res., 26, 2274, 1987
  17. Jang YS, Park DW, J. Korean Ind. Eng. Chem., 11(3), 254, 2000
  18. Prausnitz JM, Anderson TF, Grens EA, Eckert CA, Hsieh R, O’Connell JP, Computer calculations for multicomponent vapor-liquid and liquid-liquid equilibria, Prentice Hall, Englewood Cliffs, NJ, 145, 1980
  19. Sørensen JM, Arlt W, Liquid-liquid equilibrium data collection, DECHEMA, Frankfurt am Main, Vol. V, parts 1-3, 1980
  20. Othmer DF, White RE, Trueger E, Ind. Eng. Chem., 33, 1240, 1941
  21. Othmer DF, Tobias PE, Ind. Eng. Chem., 34(6), 690, 1942
  22. Hand DB, J. Phys. Chem., 34, 9, 1930
  23. Magnussen T, Rasmussen P, Fredenslund A, Ind. Eng. Process Des. Dev., 20, 331, 1981
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