Issue
Korean Journal of Chemical Engineering,
Vol.24, No.4, 618-623, 2007
Application of hybrid photocatalysis systems coupled with flocculation and adsorption to biologically treated sewage effluent for organic removal
The application of a photocatalysis hybrid system coupled with flocculation and adsorption in treating biologically treated sewage effluent (BTSE) was investigated. The removal of organic matter was studied in terms of dissolved organic matter (DOC), removal of hydrophobic (HP), transphilic (TP) and hydrophilic (HL) fractions, and molecular weight (MW) distribution. The photooxidation removed the majority of MW (263, 580, 865, and 43109 daltons) within the first 30 minutes of operation. The removal of MW range of organic matter of 330 daltons was low. DOC removal of HP and TP was high (80%). DOC removal from HL fraction was, however, minimum. The photocatalytic system with simultaneous PAC adsorption and FeCl3 flocculation removed the effluent organic matter (EfOM) up to 90%. Therefore, photocatalysis with the ferric chloride (FeCl3) flocculation and PAC adsorption hybrid system can be a possible option in the removal of DOC from BTSE for water reuse.
[References]
  1. Shon HK, Vigneswaran S, Kim IS, Cho J, Ngo HH, Water Res., 38, 1933, 2004
  2. Sagawe G, Brandi RJ, Bahnemann D, Cassano AE, Chem. Eng. Sci., 58(12), 2587, 2003
  3. Molinari R, Borgese M, Drioli E, Palmisano L, Schiavello M, Catal. Today, 75(1-4), 77, 2002
  4. Arana J, Melian JAH, Rodriguez JMD, Diaz OG, Viera A, Pena JP, Sosa PMM, Jimenez VE, Catal. Today, 76(2-4), 279, 2002
  5. Blount MC, Kim DH, Falconer JL, Environ. Sci. Technol., 35, 2988, 2001
  6. Xiaoli Y, Huixiang S, Dahui W, Korean J. Chem. Eng., 20(4), 679, 2003
  7. Lee HJ, Kang DW, Chi J, Lee DH, Korean J. Chem. Eng., 20(3), 503, 2003
  8. Thiruvenkatachari R, Kwon TO, Moon IS, Korean J. Chem. Eng., 22(6), 938, 2005
  9. Lu MC, Roam GD, Chen JN, Huang CP, Water Sci. Technol., 30, 29, 1994
  10. Doong RA, Maithreepala RA, Chang SM, Water Sci. Technol., 42, 253, 2000
  11. Shon HK, Vigneswaran S, Ngo HH, Kim JH, Water Res., 39, 2549, 2005
  12. Kleine J, Peinemann KV, Schuster C, Warnecke HJ, Chem. Eng. Sci., 57(9), 1661, 2002
  13. Molinari R, Grande C, Drioli E, Palmisano L, Schiavello M, Catal. Today, 67(1-3), 273, 2001
  14. Al-Rasheed R, Cardin DJ, Chemosphere, 51, 925, 2003
  15. Cho JW, Amy G, Pellegrino J, Yoon YM, Desalination, 118(1-3), 101, 1998
  16. Yoon YM, Amy G, Cho JW, Her N, Desalination, 173(3), 209, 2005
  17. Imai A, Fukushima T, Matsushige K, Kim YH, Choi K, Water Res., 36, 859, 2002
  18. Her NG, Amy G, Foss D, Cho J, Yoon Y, Kosenka P, Environ. Sci. Technol., 36, 1069, 2002
  19. Shon HK, Vigneswaran S, Snyder SA, Crit. Rev. Environ. Sci. Technol., 36, 327, 2006