Issue
Korean Journal of Chemical Engineering,
Vol.20, No.3, 482-486, 2003
Process Development for the Removal of Copper from Wastewater using Ferric/Limestone Treatment
The removal of copper from wastewater by ferric/limestone coagulation followed by screen filtration was carried out at a laboratory scale. The optimum coagulant (FeCl3) dose and working pH were 50 mg/l of Fe(III) and pH 7.5, respectively, through jar tests. For the efficient removal of copper from wastewater, we developed a novel process including the co-precipitation of copper with FeCl3, alkalization in a limestone aeration bed, and separation of precipitates in a sedimentation tank coupled with internal stainless steel screen filter. The performance results showed that removal of copper from the solution was over 99.5%. The pH was effectively maintained over 7.5 in limestone bed during the whole process. Ferric hydroxide/copper aggregates were removed over 99% by stainless steel screen filter of 1,450 mesh. Periodic air backwashing alleviated fouling of the filter surface.
[References]
  1. Agelidis T, Fytianos K, Vasilikiotis G, Jannakoudakis D, Environ. Pollut., 50, 243, 1988
  2. Al-Malack MH, Abuzaid NS, Elmubarak AH, Water Res., 33, 521, 1999
  3. Blanchard G, Maunaye M, Martin G, Water Res., 18, 1501, 1984
  4. Gloaguen V, Morvan H, J. Environ. Sci. Health Part A-Toxic/Hazard. Subst. Environ. Eng., 32, 901, 1997
  5. Gupta VK, Ali I, Sep. Purif. Technol., 18, 131, 2000
  6. Higgins TE, Sater VE, Environ. Prog., 3, 12, 1984
  7. Homburger F, Hayes JA, Pelikan EW, "A Guide to General Toxicology," KARGER, New York, 1983
  8. Jeon C, Park JY, Yoo YJ, Korean J. Chem. Eng., 18(6), 955, 2001
  9. Jiang JQ, Graham NJD, Water Res., 32, 930, 1998
  10. Kim SJ, Jeung SY, Moon H, Korean J. Chem. Eng., 15(6), 637, 1998
  11. Lee SH, Jung CH, Chung H, Lee MY, Yang JW, Process Biochem., 33(2), 205, 1998
  12. Martinez CE, Mcbride MB, Environ. Sci. Technol., 32, 743, 1998
  13. Plessis P, Maree JP, Water Sci. Technol., 29, 93, 1994
  14. Rao PR, Sitharamayya S, "Comparative Study of Different Techniques in the Removal of Heavy Metal Ions from Wastewaters," Proceedings of the Asia-Pacific Biochemical Engineering Conference, Dec. 1996, MasseyUniversity, New Zealand, 768, 1996
  15. Reed BE, Nonavinakere SK, Sep. Sci. Technol., 27, 1985, 1992
  16. Roques H, "Chemical Water Treatment," VCH Publishers, Inc., New York, 1996
  17. Rubio J, Tessele F, Miner. Eng., 7, 671, 1997
  18. Sim SJ, Kang CD, Lee JW, Kim WS, J. Environ. Sci. Health Part A-Toxic/Hazard. Subst. Environ. Eng., 36, 25, 2001
  19. Terashima Y, Ozaki H, Sekine M, Water Res., 20, 537, 1986
  20. The Korean Ministry of Environment, "Regulatory Limits for Drinking Water and Wastewater," J. Environmental Hi-technology, 4, 148, 1996