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Issue
Korean Journal of Chemical Engineering,
Vol.20, No.1, 71-76, 2003
Synthesis of Phenoxymethyl Ethylene Carbonate Using Quaternary Ammonium Salt Catalysts Grafted onto Styrene-Vinylbenzylchloride-Montmorillonite Support
Shin DH, Kim JJ, Yu BS, Lee MH, Park DW
The synthesis of phenoxymethyl ethylene carbonate (PMEC) from carbon dioxide and phenyl glycidyl ether (PGE) was investigated using styrene-vinylbenzylchloride-montmorillonite supported quaternary ammonium salt catalysts. The catalysts were prepared by grafting the copolymer of styrene (ST) and vinylbenzyl chloride (VBC) onto montmorillonite (MMT) interlayers, followed by the quaternization using trialkylamines. The influence of VBC concentration, the structure of trialkylamine, and the type of support on the catalytic activity was discussed. Quaternary ammonium salt grafted onto organophilic ST-VBC-MMT intercalates showed higher conversion of PGE than that grafted onto montmorillonite interlayers since the former exhibits greater affinity for organic solvents than the latter does.
Keywords: Phenylglycidyl Ether; Carbon Dioxide; Montmorillonite; Polystyrene; Supported Catalyst
[References]
  1. Akelah A, Moet A, "Functionalized Polymers and Their Applications," Chapmann & Hall, London, 1990
  2. Akelah A, Rehab A, Selim A, Agag T, J. Mol. Catal., 94, 311, 1994
  3. Awate SV, Waghmode SB, Patil KR, Agashe MS, Joshi PN, Korean J. Chem. Eng., 18(2), 257, 2001
  4. Clark JH, Tavener SJ, Barlow SJ, J. Mater. Chem., 5, 827, 1995
  5. Ford WT, Chem. Tech., 14, 436, 1984
  6. Kihara N, Hara N, Endo T, J. Org. Chem., 58, 6198, 1993
  7. Kim BS, Lee SH, Park YT, Ham SW, Chae HJ, Nam IS, Korean J. Chem. Eng., 18(5), 704, 2001
  8. Kim JJ, Shin DH, Park DW, Polym. Adv. Technol., submitted for publication, 2002
  9. Kuran GW, Marciniak BP, Monat. Chem., 115, 205, 1984
  10. Monsef-Mirzai P, McWhinnie W, Inorg. Chim. Acta, 52, 211, 1981
  11. Moon JY, Yang JG, Jung SM, Park DW, Lee JK, Korean J. Chem. Eng., 14(6), 507, 1997
  12. Moon JY, Jang HJ, Kim KH, Na SE, Park DW, Lee JK, Korean J. Chem. Eng., 16(6), 721, 1999
  13. Moronta A, Ferrer V, Quero J, Arteaga G, Choren E, Appl. Catal. A: Gen., 230(1-2), 127, 2002
  14. Nishikubo T, Kato T, Sugimoto S, Tomoi M, Ishigaki S, Macromolecules, 23, 3406, 1990
  15. Nishikubo T, kameyama A, yamashita I, Tomoi M, Fukuda W, J. Polym. Sci. A: Polym. Chem., 31, 939, 1993
  16. Nomura R, Ninagawa A, Matsuda H, J. Org. Chem., 45, 3735, 1980
  17. Park DW, Moon JY, Yang JG, Jung SM, Lee JK, Ha CS, Stud. Surf. Sci. Catal., 114, 403, 1998
  18. Pinnavaia TJ, Science, 220, 365, 1983
  19. Sasson Y, Neumann R, "Handbook of Phase Transfer Catalysis," Blackie Academic & Professional, New York, 1997
  20. Starks CM, Liotta CL, Halpem M, "Phase Transfer Catalysis," Chapman & Hall, New York, 1994
  21. Tomoi M, Kori N, Kakiuchi H, Makromol. Chem., 187, 2753, 1986
  22. Tundo P, Venturello P, J. Am. Chem. Soc., 101, 3920, 1979
  23. Tundo P, Venturello P, Angeletti E, Isr. J. Chem., 26, 283, 1985
  24. Varma RS, Naicker KP, Tetrahedron Lett., 39, 2915, 1998
  25. Venturello P, Tundo P, Angeletti E, J. Am. Chem. Soc., 104, 6547, 1982
  26. Wang ML, Peng CZ, Polym. Int., 34, 187, 1994
[Cited By]
  1. Mun NY, Kim KH, Park DW, Choe Y, Kim I, Korean Journal of Chemical Engineering, 22(4), 556, 2005
  2. Lee EH, Cha SW, Dharma MM, Choe Y, Ahn JY, Park DW, Korean Journal of Chemical Engineering, 24(3), 547, 2007
  3. Ju HY, Ahn JY, Manju MD, Kim KH, Park DW, Korean Journal of Chemical Engineering, 25(3), 471, 2008
  4. Yu JI, Ju HY, Kim KH, Park DW, Korean Journal of Chemical Engineering, 27(2), 446, 2010
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