Limiting current densities equivalent to the transport-controlling step of lithium ions in organic electrolytes were measured by using a rotating disk electrode (RDE). The diffusion coefficients of lithium ion in the electrolyte of PC/LiClO4, EC : DEC/LiPF6 and EC : DMC/LiPF6 were determined by the limiting current density data according to the Levich equation. The diffusion coefficients increased in the order of PC/LiClO4

Keywords: Lithium Ion Batteries; RDE; Electrolyte; Limiting Current Density; Diffusion Coefficient

[References]

1. Aurbach D, Zaban A, Gofer Y, Ein-Eli Y, Weissman I, Chusid O, Abramson O, J. Power Sources, 54, 76, 1995
2. Aurbach D, Markovsky B, Shechter A, Eineli Y, Cohen H, J. Electrochem. Soc., 143(12), 3809, 1996
3. Blint RJ, J. Electrochem. Soc., 144(3), 787, 1997
4. Blomgren GE, "Lithium Batteries," (ed. by Gabano J.P.) Chap. 2, Academic Press Inc. (London) Ltd., 1993
5. Bockris J, Reddy A, "Modern Electrochemistry," Plenum Press, New York, 1973
6. Cazzanelli E, Croce F, Appetecchi GB, Benevelli F, Mustarelli P, J. Chem. Phys., 107(15), 5740, 1997
7. Cussler EL, "Diffusion, Mass Transfer in Fluid Systems," Cambridge Univ. Press, 118, 1984
8. Dominey LA, "Lithium Batteries, New Materials, Developments and Perspectives, Industrial Chemistry Liblary," (Edited by G. Pistoia) Vol. 5, Chap. 4, Elsevier Amsterdam, 1994
9. Eineli Y, Thomas SR, Koch VR, J. Electrochem. Soc., 143(9), L195, 1996
10. Eineli Y, Thomas SR, Chadha R, Blakley TJ, Koch VR, J. Electrochem. Soc., 144(3), 823, 1997
11. Horvath AL, "Handbook of Aqueous Electrolyte Solutions," Ellis Horwood Limited, New York, 1985
12. Ishikawa M, Morita M, Asao M, Matsuda Y, J. Electrochem. Soc., 141(5), 1105, 1994
13. Jung UH, Lee SI, Chun HS, Lee HH, Lee KY, Kim MH, "Electrochemical Characteristics of Electrolytes for Lithium Ion Battery," Proceeding of Korean Electrochemical Society, Seoul, Korea, Oct., 141, 1998
14. Kanamura K, Takezawa H, Shiraishi S, Takehara Z, J. Electrochem. Soc., 144(6), 1900, 1997
15. Langenhuizen NPW, J. Electrochem. Soc., 145(9), 3094, 1998
16. Lee SI, Lee JS, Park JH, Park GP, Lim JH, Lee JK, Chun HS, HWAHAK KONGHAK, 38(2), 129, 2000
17. Matsuda Y, Morita M, Tachihara F, Bull. Chem. Soc. Jpn., 59, 1967, 1986
18. Nam SC, Lim YC, Park HY, Jeon EJ, Yoon YS, Cho WI, Cho BW, Yun KS, Korean J. Chem. Eng., 18(5), 673, 2001
19. Naoi K, Mori M, Shinagawa Y, J. Electrochem. Soc., 143(8), 2517, 1996
20. Quickenden TI, Jiang X, Electrochim. Acta, 29, 639, 1984
21. Uceda DA, O'Keefe TJ, Cole ER, J. Electrochem. Soc., 137, 1397, 1990
22. Verbrugge MW, Koch BJ, J. Electrochem. Soc., 141(11), 3053, 1994
23. Wang X, Iyoda M, Nishida T, Uchida I, "Application of Microelectrode Technique to Kinetic Study of the Lithium Deposition/Dissolutionand Alloying in Organic Solution," Ext. Abstracts of 8th International Meeting on Lithium Batteries, Nagoya, Japan, 16-21, June, 385, 1996
24. Zhang SS, Angell CA, J. Electrochem. Soc., 143(12), 4047, 1996

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