Issue
Korean Journal of Chemical Engineering,
Vol.18, No.2, 184-189, 2001
Heat Transfer Effect of Inert Gas on Multi-Tubular Reactor for Partial Oxidation Reaction
The heat transfer effect of an inert gas on a multi-tubular reactor for a partial oxidation reaction has been determined. The model reaction system in the study was partial oxidation of propylene to acrolein. Both theoretical modeling and experimental studies have been performed to determine the heat transfer effect of inert gas on the system. Among many inert gases, CO2 was selected and tested as a diluent gas for the partial oxidation of propylene to acrolein system instead of conventionally used N2. The productivity increase through changing the inert gas from N2 to CO2 was possible due to the heat transfer capability of CO2. In this study, by replacing the inert gas from N2 to CO2, productivity increased up to 14%.
[References]
  1. Byun YC, Lee WH, "Process for Manufacturing Catalysts for the Acrolein and Methacrolein Production," KR Patent, 99-21570, 1999
  2. Calderbank JJ, Pogorski LA, Trans. Inst. Chem. Eng., 35, 195, 1957
  3. Carberry JJ, "Chemical and Catalytic Reaction Engineering," McGraw-Hill, New York, 1976
  4. Choi J, Eigenberger G, Chem. Ing. Tech., 61(8), 641, 1989
  5. Doraiswamy LK, Sharma MM, "Heterogeneous Reactions: Analysis, Examples, and Reactor Design," Wiley, New York, 1984
  6. Franzen EP, Maycock RL, Nelson LE, Smith WC, "Tubular Catalytic Reactor with Cooler," US Patent 3147084, 1964
  7. Froment GF, Bischoff KB, "Chemical Reactor Analysis and Design," Wiley, New York, 1979
  8. Jung KY, So JH, Park SB, Yang SM, Korean J. Chem. Eng., 16(2), 193, 1999
  9. Ko D, Lee WH, Paek KH, "The Preparation Method for Partial Oxidation Catalyst," KR Patent, 177326, 1998
  10. Petrovic LJ, Thodos G, Ind. Eng. Chem. Fundam., 7, 274, 1968
  11. Roach PJ, "Computational Fluid Dynamics," Hermosa, Albuquerque N.M., 1972
  12. Rowe PN, Claxton KT, Lewis JB, Trans. Inst. Chem. Eng., 43(T), 14, 1965
  13. Satterfield CN, Massachusetts Institute Technology, 78, 1970
  14. Song KH, Park KH, "Process Development of Acrylates," LG Chem research report, 1998
  15. Szekely J, Evans JW, Sohn HY, "Gas-Solid Reactions," Academic Press, New York, 1976
  16. Tan HS, Downie J, Bacon DW, Can. J. Chem. Eng., 67, 412, 1989