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Issue
Korean Journal of Chemical Engineering,
Vol.38, No.8, 1676-1685, 2021
Construction of OH sites within MIL-101(Cr)-NH2 framework for enhanced CO2 adsorption and CO2/N2 selectivity
Vo TK, Vu PV, Nguyen VC, Kim JS
The MIL-101(Cr)-NH2 framework was effectively modified by 2,5-dihydroxyterephthalic acid ((HO)2BDC) guest molecules to obtain (HO)2BDC-incorporated MIL-101(Cr)-NH2 adsorbent, namely (HO)2BDC@CrN. The CO2- temperature programmed-desorption (TPD) analysis indicated that the incorporation of (HO)2BDC into the MIL- 101(Cr)-NH2 framework generated new OH sites besides unsaturated Cr- metal sites and NH2 sites. The formed OH sites improved CO2 adsorption and separation on the prepared adsorbent. The highest CO2 uptake capacity of ~3.58mmol g-1 obtained over the novel (HO)2BDC@CrN adsorbent was higher 40% than that of the parent MOF, and also surpasses that of other previously reported adsorbents, including activated carbon, nitrogen-doped hollow carbon, zeolite, ZIF-68, MOF-5, ZIF-8, UiO-66(Zr), and MIL-100(Cr). The highest ideal adsorbed solution theory (IAST) CO2/ N2 selectivity of ~67 was obtained over the (HO)2BDC@CrN adsorbent at 100 kPa. The achieved selectivity was six times greater than that of pure MIL-101(Cr)-NH2. In addition, the synthesized (HO)2BDC@CrN adsorbent displayed good regenerability after six consecutive adsorption-desorption cycles.
Keywords: CO2 Adsorption; MIL-101(Cr)-NH2; Dihydroxyterephthalic Acid; (HO)2BDC@CrN; CO2/N2 Separation; CO2-TPD
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[Cited By]
  1. Ravi S, Choi YJ, Park WJ, Han HH, Wu S, Xiao R, Bae YS, Journal of Industrial and Engineering Chemistry, 108, 188, 2022
  2. Behaien S, Aghel B, Shadloo MS, Korean Journal of Chemical Engineering, 40(1), 145, 2023
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