Issue
Korean Journal of Chemical Engineering,
Vol.38, No.7, 1510-1521, 2021
The nano-magnetite-loaded 2-mercaptobenzoxazole as an adsorbent for the selective removal of the Pb2+, Ni2+ and Cd2+ ions from aqueous solutions
The present research focuses on the adsorption efficiency of nano-magnetite loaded 2-mercapto- benzoxazole as an adsorbent (Fe3O4@SiO2@CPTMS@MBOL) for Pb+2, Ni+2 and Cd+2 removal from the contaminated water by the technique of adsorption. The influence of pH, contact time, adsorbent dosage and temperature in 50 ppm concentration of each ion solutions on the sensitivity of the removal procedure was examined. By ICP test the adsorption data were fixed to linearize the adsorption isotherms of the Langmuir and Freundlich equations. This efficient adsorbent showed significant results for metal ion removal from water by formation of complex with adsorbent. From the Langmuir isotherm, the maximum adsorption capacities of nano magnetic adsorbent towards Pb2+, Ni2+ and Cd2+ ions were 238.4, 203.2 and 22.37mgg-1.
[References]
  1. Sun YJ, Shah KJ, Sun WQ, Zheng HL, Sep. Purif. Technol., 215, 208, 2019
  2. Muthusaravanan S, Sivarajasekar N, Vivek JS, Paramasivan T, Naushad M, Prakashmaran J, Gayathri V, Al-Duaij OK, Environ. Chem. Lett., 16, 1339, 2018
  3. Rambabu K, Thanigaivelan A, Bharath G, Sivarajasekar N, Banat F, Show PL, Chemosphere, 268, 128809, 2021
  4. Janani K, Sivarajasekar N, Muthusaravanan S, Ram K, Prakashmaran J, Sivamani S, Dhakal N, Shahnaz T, Selvaraju N, Bioresour. Technol., 7, 100265, 2019
  5. Sharavanan VJ, Sivaramakrishnan M, Sivarajasekar N, et al., Environ. Chem. Lett., 18, 325, 2020
  6. Muthusaravanan S, et al., Green Materials for Wastewater Treatment, 38, 191 (2020).
  7. Jun BM, Her N, Park CM, Yoo Y, Environ. Sci. Water Res. Technol., 6, 173, 2020
  8. Bobadilla MC, Lorza RL, Gomez FS, Garcia RE, Water, 12, 1320, 2020
  9. Devatha CP, Shivani S, J. Environ. Manage., 258, 110038, 2020
  10. Azimi A, Azari A, Rezakazemi M, Ansarpour M, ChemBio-Eng Rev., 4, 37, 2017
  11. Rahman MM, Asaduzzaman M, Naidu R, J. Hazard. Mater., 262, 1056, 2013
  12. Anjum M, Miandad R, Waqa M, Gehany F, Barakat MA, Arab. J. Chem, 12, 4897, 2019
  13. Lin LC, Li JK, Juang RS, Desalination, 225(1-3), 249, 2008
  14. Fan HL, Zhou SF, Jiao WZ, Qi GS, Liu YZ, Carbohydr. Polym., 174, 1192, 2017
  15. Bessbousse H, Rhlalou T, Verchere JF, Lebrun L, J. Membr. Sci., 307(2), 249, 2008
  16. Benito Y, Ruiz ML, Desalination, 142(3), 229, 2002
  17. Zhao F, Tang WZ, Zhao D, Meng Y, Yin D, Sillanpaa M, J. Water Process Eng., 4, 47, 2014
  18. Kobya M, Demirbas E, Senturk E, Ince M, Bioresour. Technol., 96(13), 1518, 2005
  19. Panneerselvam P, Bala V, Thinakaran N, Baskaralingam P, Palanichamy M, Sivanesan S, E- J. Chem., 6, 729, 2009
  20. Jiang MQ, Jin XY, Lu XQ, Chen ZL, Desalination, 252(1-3), 33, 2010
  21. Ambashta RD, Sillanpaa M, J. Hazard. Mater., 180(1-3), 38, 2010
  22. Sharma YC, Srivastava V, Singh CK, Kaul SN, Weng CH, Environ. Technol., 30, 583, 2009
  23. White BR, Stackhouse BT, Holcombe JA, J. Hazard. Mater., 161(2-3), 848, 2009
  24. Sharma YC, Srivastava V, J. Chem. Eng. Data, 55(3), 1441, 2010
  25. Karami H, Chem. Eng. J., 219, 209, 2013
  26. Badruddoza AZM, Shawon ZBZ, Tay WJD, Hidajat K, Uddin MS, Carbohydr. Polym., 91, 322, 2013
  27. Ariannezhad M, Habibi D, Heydari S, Russ. J. Org. Chem., 55, 1591, 2019
  28. Hawkes SJ, J. Chem. Educ., 73, 516, 1996
  29. Watanabe H, Seto JE, Bull. Chem. Soc. Jpn., 59, 2683, 1986
  30. Pirarath R, Shivashanmugam P, Syed A, Elgorban AM, AnandanAnandan S, Ashokkumar M, Front Environ. Sci. Eng., 15, 1, 2021
  31. Boparai HK, Joseph M, O'Carroll DM, J. Hazard. Mater., 186(1), 458, 2011
  32. Madrakian T, Afkhami A, Ahmadi M, Chemosphere, 90, 542, 2013
  33. Lian N, Chang X, Zheng H, Wang S, Cui Y, Zhai Y, Microchim. Acta, 151, 81, 2005
  34. Mohammadi S, Afzali D, Pourtalebi D, Open Chem., 8, 662, 2010
  35. Liu JY, Hu CW, Huang QG, Bioresour. Technol., 271, 487, 2019
  36. Cui Y, Chang X, Zhai Y, Zhu ZH, Lian N, Microchem. J., 83, 35, 2006
  37. Ozer A, J. Hazard. Mater., 141(3), 753, 2007
  38. Heidari A, Younesi H, Mehraban Z, Chem. Eng. J., 153(1-3), 70, 2009
  39. Huang C, Hu B, Spectroc. Acta Pt. B-Atom. Spectr., 63, 437, 2008