Issue
Korean Journal of Chemical Engineering,
Vol.37, No.8, 1340-1345, 2020
Hydrogen evolving electrode with low Pt loading fabricated by repeated pulse electrodeposition
Reducing the Pt loading amount in an electrode is essential for the commercialization of water electrolyzers. We report a simple method for the fabrication of a low Pt loading electrode, using an electrochemical method named selfterminated electrodeposition, at room temperature and under ambient pressure. Controlling the deposition conditions enables the quenching deposition of Pt on a C-coated gas diffusion layer by H passivation at a highly negative potential. Repeating deposition pulses facilitate the facile control of the Pt surface composition and electrochemical surface area, which significantly affects their catalytic performance for the hydrogen evolution reaction. The results presented show that the aforementioned Pt electrode can be a promising cathode for use in membrane-based water electrolyzers.
[References]
  1. Turner JA, Science, 305, 972, 2004
  2. Hosseini SE, Wahid MAJR, Renew. Sust. Energ. Rev., 57, 850, 2016
  3. Acar C, Dincer I, Int. J. Hydrog. Energy, 39(1), 1, 2014
  4. Lee B, Chae H, Choi NH, Moon C, Moon S, Lim H, Int. J. Hydrog. Energy, 42(10), 6462, 2017
  5. Voldsund M, Jordal K, Anantharaman R, Int. J. Hydrog. Energy, 41(9), 4969, 2016
  6. Holladay JD, Hu J, King DL, Wang Y, Catal. Today, 139, 244, 2009
  7. Park JE, Kim S. Kim OH, Ahn CH, Kim MJ, Kang SY, et al., Nano Energy, 58, 158, 2019
  8. Kim H, Choe S, Park H, Jang JH, Ahn SH, Kim SK, Nanoscale, 9, 190545, 2017
  9. Lee BS, Ahn SH, Park HY, Choi I, Yoo SJ, Kim HJ, Henkensmeier D, Kim JY, Park S, Nam SW, Lee KY, Jang JH, Appl. Catal. B: Environ., 179, 285, 2015
  10. Choe S, Lee BS, Cho MK, Kim HJ, Henkensmeier D, Yoo SJ, Kim JY, Lee SY, Park HS, Jang JH, Appl. Catal. B: Environ., 226, 289, 2018
  11. Kim J, Kim J, Kim H, Ahn SH, ACS Appl. Mater. Interfaces, 11, 330774, 2019
  12. Buhler M, Holzapfel P, McLaughlin D, Thiele S, J. Electrochem. Soc., 166(14), F1070, 2019
  13. Chen Q, Cao Z, Du G, Kuang Q, Huang J, Xie Z, Zheng L, Nano Energy, 39, 582, 2017
  14. Cao X, Han Y, Gao C, Xu Y, Huang X, Willander M, Wang N, Nano Energy, 9, 301, 2014
  15. Shi Y, Zhang B, Chem. Soc. Rev., 45, 1529, 2016
  16. Guo Y, Park T, Yi JW, Henzie J, Kim J, Wang Z, Jiang B, et al., Adv. Mater., 31, 180713, 2019
  17. Esposito DV, Hunt ST, Stottlemyer AL, Dobson KD, McCandless BE, Birkmire RW, Chen JG, Angew. Chem.-Int. Edit., 49, 9859, 2010
  18. Esposito DV, Hunt ST, Kimmel YC, Chen JGG, J. Am. Chem. Soc., 134(6), 3025, 2012
  19. Pi Y, Shao Q, Zhu X, Huang X, ACS Nano, 12, 7371, 2018
  20. Wang Y, Yu X, Liu G, Zhu X, Xu R, Ji M, Ma Y, Ma L, Adv. Sustainable Syst., 3, 190002, 2019
  21. Buhler M, Hegge F, Holzapfel P, Bierling M, Suermann M, Vierrath S, Thiele S, J. Mater. Chem. A, 7, 26984, 2019
  22. Mo J, Kang Z, Retterer ST, Cullen DA, Toops TJ, Green JB, Mench MM, Zhang FY, Sci. Adv., 2, e16006, 2016
  23. Kang Z, Yang G, Mo J, Li Y, Yu S, Cullen DA, Retterer ST, et al., Nano Energy, 47, 434, 2018
  24. Zeng YC, Guo XQ, Shao ZG, Yu HM, Song W, Wang ZQ, Zhang HJ, Yi BL, J. Power Sources, 342, 947, 2017
  25. Cheng J, Yang J, Kitano S, Juhasz G, Higashi M, Sadakiyo M, et al., ACS Catal., 9, 6974, 2019
  26. Claudel F, Dubau L, Berthome G, Sola-Hernandez L, Beauger C, Piccolo L, Maillard F, ACS Catal., 9, 4688, 2019
  27. Fedotov AA, Grigoriev SA, Millet P, Fateev VN, Int. J. Hydrog. Energy, 39, 8568, 2013
  28. Kim J, Kim H, Kim J, Kim JH, Ahn SH, J. Alloy. Compd., 807, 144881, 2019
  29. Kim H, Park H, Kim DK, Oh S, Choi I, Kim SK, ACS Sust. Chem. Eng., 7, 8265, 2019
  30. Hussain S, Erikson H, Kongi N, Tarre A, Ritslaid P, Rahn M, Matisen L, Merisalu M, Sammelselg V, Tammeveski K, Int. J. Hydrog. Energy, 43(10), 4967, 2018
  31. Wang H, Zhang M, Cheng F, Xu C, Int. J. Electrochem. Sci., 3, 946, 2008
  32. Li J, Liu W, Wang J, Rozen I, He S, Chen C, Kim HG, et al., Adv. Funct. Mater., 27, 170059, 2017
  33. Hsu IJ, Kimmel YC, Jiang X, Willis BG, Chen JG, Chem. Commun., 48, 1063, 2012
  34. Liu Y, Gokcen D, Bertocci U, Moffat TP, Science, 388, 1327, 2012
  35. Ahn SH, Liu Y, Moffat TP, ACS Catal., 5, 2124, 2015