Korean Journal of Chemical Engineering, Vol.36, No.12, 2085-2094, 2019
A preferential CO2 separation using binary phases membrane consisting of Pebax®1657 and [Omim][PF6] ionic liquid
Pebax®1657 and [Omim][PF6] ionic liquid (IL) were used to fabricate a blend membrane and applied for CO2 separation. The changes upon adding ionic liquid into the polymer matrix as well as the membrane characteristics were studied through SEM, FTIR, DSC and TGA analysis. The obtained gas permeation results indicated that the CO2 permeability in all membranes was much higher than the other studied gases. CO2 permeability of Pebax containing 8 wt% IL increased from 82.3 Barrer up to 125.6 Barrer at a pressure of 2 bar, which showed a 53% increment compared to the neat Pebax membrane. Furthermore, as the [Omim][PF6] loading within the polymer matrix was increased, the CO2/CH4 and CO2/N2 selectivities improved. In addition, the permeability and selectivity of gases was enhanced as the feed pressure increased. Upon increasing feed pressure to 10 bar, the CO2 permeability of Pebax containing 8 wt% IL reached 185.3 Barrer, which was approximately 48% higher than the permeability at a pressure of 2 bar. Moreover, the selectivity of CO2/CH4 and CO2/N2 for the Pebax/8 wt% IL membrane at pressure of 2 bar was 15.3 and 46.5, respectively, which improved to 19.7 and 59.8 as the pressure increased to 10 bar.
[References]
Lee RJ, Jawad ZA, Ahmad AL, Chua HB, Process Saf. Environ. Protect. , 117 , 159, 2018
Nematollahi MH, Babaei S, Abedini R, Korean J. Chem. Eng. , 36 (5), 763, 2019
Shakeel I, Hussain A, Farrukh S, J. Polym. Environ. , 27 , 1449, 2019
Heck R, Qahtani MS, Yahaya GO, Tanis I, Brown D, Bahamdan AA, Ameen AW, Vaidya MM, Ballaguet JPR, Alhajry RH, Espuche E, Mercier R, Sep. Purif. Technol. , 173 , 183, 2017
Abedini R, Omidkhah M, Dorosti F, RSC Adv. , 4 , 36522, 2014
Kiadehi AD, Rahimpour A, Jahanshahi M, Ghoreyshi AA, J. Ind. Eng. Chem. , 22 , 199, 2015
Nezhadmoghadam E, Chenar MP, Omidkhah M, Nezhadmoghadam A, Abedini R, Korean J. Chem. Eng. , 35 , 526, 2019
Mahdavi HR, Azizi N, Arzani M, Mohammadi T, J. Nat. Gas. Sci. Eng. , 46 , 275, 2017
Raza A, Farrukh S, Hussain A, J. Polym. Environ. , 25 , 46, 2017
Hao L, Li P, Yang TX, Chung TS, J. Membr. Sci. , 436 , 221, 2013
Dorosti F, Omidkhah M, Abedini R, Chem. Eng. Res. Des. , 92 (11), 2439, 2014
Rabiee H, Ghadimi A, Mohammadi T, J. Membr. Sci. , 476 , 286, 2015
Vatani M, Raisi A, Pazuki G, J. Mol. Liq. , 277 , 471, 2019
Bernardo P, Jansen JC, Bazzarelli F, Tasselli F, Fuoco A, Friess K, Izak P, Jarmarova V, Kacirkova M, Clarizia G, Sep. Purif. Technol. , 97 , 73, 2012
Estahbanati EG, Omidkhah M, Amooghin AE, ACS. Appl. Mater. Inter. , 9 , 10094, 2017
Mozafari M, Abedini R, Rahimpour A, J. Mater. Chem. A , 6 , 12380, 2018
Beiragh HH, Omidkhah M, Abedini R, Khosravi T, Pakseresht S, Asia.Pac. J. Chem. Eng. , 11 , 522, 2016
Pazirofteh M, Dehghani M, Niazi S, Mohammadi AH, Asghari M, J. Mol. Liq. , 241 , 646, 2017
Chung TS, Jiang LY, Li Y, Kulprathipanja S, Prog. Polym. Sci , 32 , 483, 2007
Sasikumar B, Arthanareeswaran G, Ismail A, J. Mol. Liq. , 266 , 330, 2018
Zhao YS, Pan MG, Kang XJ, Tu WH, Gao HS, Zhang XP, Chem. Eng. Sci. , 189 , 43, 2018
Li M, Zhang X, Zeng S, Gao H, Deng J, Yang Q, Zhang S, RSC Adv. , 7 , 6422, 2017
Car A, Stropnik C, Yave W, Peinemann KV, Sep. Purif. Technol. , 62 (1), 110, 2008
Bhattacharya M, Mandal MK, J. Clean Prod. , 156 , 174, 2017
Fam W, Mansouri J, Li HY, Chen V, J. Membr. Sci. , 537 , 54, 2017
Estahbanati EG, Omidkhah M, Amooghin AE, J. Ind. Eng. Chem. , 51 , 77, 2010
Bhattacharya M, Mandal MK, J. Clean Prod. , 156 , 174, 2017
Lin R, Ge L, Diao H, Rudolph V, Zhu Z, ACS Appl. Mater. Interfaces , 46 , 32041, 2016
Otvagina KV, Mochalova AE, Sazanova TS, Petukhov AN, Moskvichev AA, Vorotyntsev AV, Afonso CAM, Vorotyntsev IV, Membranes , 6 , 31, 2016
Azizi N, Mohammadi T, Behbahani RM, J. Energy Chem. , 26 , 454, 2017
Abedini R, Omidkhah M, Dorosti F, Int. J. Hydrog. Energy , 39 (15), 7897, 2014
Jamshidi M, Pirouzfar V, Abedini R, Pedram MZ, Korean J. Chem. Eng. , 34 (3), 829, 2017
Huang GJ, Isfahani AP, Muchtar A, Sakurai K, Shrestha BB, Qin DT, Yamaguch D, Sivaniah E, Ghalei B, J. Membr. Sci. , 565 , 370, 2018
Fu YJ, Hu CC, Qui HZ, Lee KR, Lai JY, Sep. Purif. Technol. , 62 (1), 175, 2008
Joly C, Le Cerf D, Chappey C, Langevin D, Muller G, Sep. Purif. Technol. , 16 (1), 47, 1999
Jomekian A, Bazooyar B, Behbahani RM, Mohammadi T, Kargari A, J. Membr. Sci. , 524 , 652, 2017
Nasir R, Ahmad NNR, Mukhtar H, Mohshim DF, J. Environ. Chem. Eng. , 6 , 2363, 2018
Parodi E, Govaert LE, Peters GWM, Thermochim. Acta , 657 , 110, 2017
Ghadimi A, Amirilargani M, Mohammadi T, Kasiri N, Sadatnia B, J. Membr. Sci. , 458 , 14, 2014
Sanaeepur H, Ahmadi R, Amooghin AE, Ghanbari D, J. Membr. Sci. , 573 , 234, 2019
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