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Issue
Korean Journal of Chemical Engineering,
Vol.36, No.5, 669-677, 2019
Flocculation kinetics and dewatering studies of quaternized cellulose derived from oil palm empty fruit bunches
Mohtar SS, Saman N, Noor AMM, Busu TNZTM, Yusoff NA, Mat H
Flocculation kinetics and sludge dewatering of kaolin suspension as influenced by various q-EFBC flocculant dosing were studied. In this study, 62.5mg L-1 q-EFBC exhibited the highest turbidity removal efficiency of 99.53∂ 0.08%. The adsorption rate of kaolin towards 12.5mg L-1 to 112.5mg L-1 q-EFBC dosing increased rapidly for t<60 s and became gradual before completion. The mass transfer coefficient was independent of dosage. The experimental data best-fitted the non-linear pseudo-first order due to the R2>0.99 and the lowest standard deviation. The highest rate constant of particle aggregation and breakage was consistent with the highest rate constant of particle collision, which led to the highest turbidity removal at the optimal dosage. The rate-limiting steps in the flocculation process were particle collision and aggregation since their rate constant was lower than the other kinetic constants. The lower values of SRF and TTF of treated sludge as compared to the untreated one confirmed the improvement in the dewaterability characteristic. The lowest TTF (37.44 ± 1.44 s) and SRF (1.49 x 010 m kg-1) was observed for 62.5mg L-1 q EFBC. The high turbidity removal nd improved sludge dewaterability indicate the potential application of q-EFBC for water treatment.
Keywords: Adsorption; Flocculation; Kinetics; Cellulose; Turbidity Removal
[References]
  1. Hogg R, Int. J. Miner. Process., 58, 223, 2000
  2. Pal G, Sen S, Ghosh S, Singh RP, Carbohydr. Polym., 87, 336, 2012
  3. Khiari R, Dridi-Dhaouadi S, Aguir C, Mhenni MF, J. Environ. Sci., 22, 1539, 2010
  4. Beltran-Heredia J, Sanchez-Martin J, J. Hazard. Mater., 164(2-3), 713, 2009
  5. Tripathy J, Mishra DK, Srivastava A, Mishra MM, Behari K, Carbohydr. Polym., 72, 462, 2008
  6. Liimatainen H, Sirvio J, Sundman O, Visanko M, Hormi O, Niinimaki J, Bioresour. Technol., 102(20), 9626, 2011
  7. Song YB, Zhang J, Gan WP, Zhou JP, Zhang LN, Ind. Eng. Chem. Res., 49(3), 1242, 2010
  8. Mohtar SS, Busu TNZTM, Noor AMM, Shaari N, Yusoff NA, Yunus MAC, Mat H, Clean Technol. Environ., 19, 191, 2017
  9. Kono H, Resour. Eff. Technol., 3, 55, 2017
  10. Yang Z, Ren K, Guibal E, Jia S, Shen J, Zhang X, Yang W, Chemosphere, 161, 482, 2016
  11. Rasteiro MG, Pinheiro I, Ahmadloo H, Hunkeler D, Garcia FAP, Ferreira P, Wandrey C, Chem. Eng. Res. Des., 95, 298, 2015
  12. Chen YX, Liu SY, Wang GY, Chem. Eng. J., 133(1-3), 325, 2007
  13. Gregory J, in: Encyclopedia of colloid and interface science, Ed.), Springer, Berlin, Heidelberg (2013).
  14. Ding C, Li Y, Wang Y, Li J, Sun Y, Lin Y, Sun W, Luo C, Int. J. Biol. Macromol., 107, 957, 2018
  15. Kacprzak M, Neczaj E, Fijałkowski K, Grobelak A, Grosser A, Worwag M, Rorat A, Brattebo H, Almas A, Singh BR, Environ. Res., 156, 39, 2017
  16. Wei H, Gao B, Ren J, Li A, Yang H, Water Res., 143, 608, 2018
  17. Christensen ML, Keiding K, Nielsen PH, Jørgensen MK, Water Res., 82, 14, 2015
  18. Qi Y, Thapa KB, Hoadley AFA, Chem. Eng. J., 171(2), 373, 2011
  19. Tuan PA, Mika S, Pirjo I, Dry. Technol., 30, 691, 2012
  20. To VHP, Nguyen TV, Vigneswaran S, Ngo HH, Water Sci. Technol., 74, 1, 2016
  21. Liu BT, Song HY, Li YX, Adv. Mater. Res., 383, 3134, 2012
  22. Kuutti L, Haavisto S, Hyvarinen S, Mikkonen H, Koski R, Peltonen S, Suortti T, Kyllonen H, Bioresources, 6, 2836, 2011
  23. Wang JP, Yuan SJ, Wang Y, Yu HQ, Water Res., 47, 2643, 2013
  24. Suopajarvi T, Sirvio JA, Liimatainen H, J. Environ. Chem. Eng., 5, 86, 2017
  25. Zhou K, Stuber J, Schubert RL, Kabbe C, Barjenbruch M, Water Sci. Technol., 77, 7, 2017
  26. Mohtar SS, Busu TNZTM, Noor AMM, Shaari N, Mat H, Carbohydr. Polym., 166, 291, 2017
  27. Gregory J, Barany S, Adv. Colloid Interface Sci., 169, 1, 2011
  28. Hema M, Arivoli S, J. Appl. Sci. Environ. Manage., 12, 43, 2008
  29. Saman N, Johari K, Song ST, Kong H, Cheu SC, Mat H, J. Environ. Chem. Eng., 4, 2487, 2016
  30. Ocampo-Perez R, Leyva-Ramos R, Alonso-Davila P, Rivera-Utrilla J, Sanchez-Polo M, Chem. Eng. J., 165(1), 133, 2010
  31. Tran HN, You SJ, Hosseini-Bandegharaei A, Chao HP, Water Res., 120, 88, 2017
  32. Bergmann CP, Machado F, Carbon nanomaterials as adsorbents for environmental and biological applications, Springer International Publishing, Switzerland (2015).
  33. Kumar KV, J. Hazard. Mater., 137(3), 1538, 2006
  34. Lick W, Sediment and contaminant transport in surface waters, CRC Press, Boca Raton (2009).
  35. Gregory J, Particles in water: Properties and processes, CRC Press, Boca Raton (2006).
  36. Das KK, Somasundaran P, J. Colloid Interface Sci., 271(1), 102, 2004
  37. Jarvis P, Jefferson B, Parsons SA, Rev. Environ. Sci. Biotechnol., 4, 1, 2005
  38. Besra L, Sengupta DK, Roy SK, Int. J. Miner. Process., 59(2), 89, 2000
  39. Wang HF, Hu H, Wang HJ, Zeng RJ, Sci. Total Environ., 643, 1065, 2018
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