Issue
Korean Journal of Chemical Engineering,
Vol.36, No.3, 439-449, 2019
Synthesis and performance evaluation of zeolitic imidazolate framework-8 membranes deposited onto alumina hollow fiber for desalination
This work describes the development of zeolitic imidazolate framework-8 (ZIF-8) membranes on modified alumina hollow fiber for desalination by forward osmosis. Effects of different seeds (ZnO, NiO and PDA) and sodium formate on in-situ deposition of ZIF-8 were studied in relation to the membrane…s morphology and performance. XRD result shows that ZIF-8 was successfully synthesized in the presence of sodium formate. FESEM images showed PDA modified support was unsuccessful in producing well defined and dense ZIF-8 membrane layer even after another ZIF-8 re-deposition due to its minimal amount. The NiO modified support was also found unsuccessful, as ZIF-8 crystals were formed in clusters. On the contrary, dense ZIF-8 membrane was successfully prepared on ZnO modified support with SF-1 synthesis solution producing bigger ZIF-8 crystal and thinner ZIF-8 membrane than as of SF-2. Water flux performance in forward osmosis showed that NiO/ZIF-8, PDA/ZIF-8 and PDA/ZIF-8 (re-deposition) membranes gave negative water fluxes of -50 kg/m2ㆍh, -5.2 kg/m2ㆍh and -1.7 kg/m2ㆍh with reverse solutes of 42.66 mol/m2ㆍh, 27.42mol/m2ㆍh and 3.22 mol/m2ㆍh, respectively, indicating the solute from draw solution diffused into the feed solution. However, ZIF-8 membrane prepared using SF with molar ratio of 1, on the ZnO modified support had a water flux of 13.3 kg/m2ㆍh, reverse solute of 0.95 kg/m2ㆍh and salt rejection of 52.1%. When the SF ratio was increased to 2, the ZIF-8 membranes showed a water flux of 12.5 kg/m2ㆍh, reverse solute of 1.64 kg/m2ㆍh and salt rejection of 54.9%. The moderate salt rejection could be associated with defects in the ZIF-8 membranes due to poor grain boundaries.
[References]
  1. Wang K, Abdalla AA, Khaleel MA, Hilal N, Khraisheh MK, Desalination, 401, 190, 2017
  2. Balfaqih H, Al-Nory MT, Nopiah ZM, Saibani N, Desalination, 406, 2, 2016
  3. Goh PS, Matsuura T, Ismail AF, Hilal N, Desalination, 391, 43, 2016
  4. Yang E, Kim CM, Song JH, Ki H, Ham MH, Kim IS, Carbon, 117, 293, 2017
  5. Shaffer DL, Werber JR, Jaramillo H, Lin SH, Elimelech M, Desalination, 356, 271, 2015
  6. Qiu S, Xue M, Zhu G, Chem. Soc. Rev., 43, 6116, 2014
  7. Lismont M, Dreesen L, Wuttke S, Adv. Funct. Mater., 27, 1, 2017
  8. Liu XL, Demir NK, Wu ZT, Li K, J. Am. Chem. Soc., 137(22), 6999, 2015
  9. Park KS, Ni Z, Cote AP, Choi JY, Huang R, Uribe-Romo FJ, Chae HK, O’Keeffe M, Yaghi OM, Proc. Natl. Acad Sci., 103, 10186, 2006
  10. Zhang C, Koros WJ, J. Phys. Chem. Lett., 6, 3841, 2015
  11. Lee YR, Jang MS, Cho BY, Kwon HJ, Kim S, Ahn WS, Chem. Eng. J., 271, 276, 2015
  12. Duke MC, Zhu B, Doherty CM, Hill MR, Hill AJ, Carreon MA, Desalination, 377, 128, 2016
  13. Zhu YQ, Gupta KM, Liu Q, Jiang JW, Caro J, Huang AS, Desalination, 385, 75, 2016
  14. Pan Y, Wang B, Lai Z, J. Membr. Sci., 421-422, 292, 2012
  15. Bux H, Feldho A, Cravillon J, Wiebcke M, Li Y, Caro J, Chem. Mater., 23, 2262, 2011
  16. Zhang X, Liu Y, Kong L, Liu H, Qiu J, Han W, Weng LT, J. Mater. Chem. A, 1, 10635, 2013
  17. Kong LY, Zhang XF, Liu HO, Qiu JS, J. Membr. Sci., 490, 354, 2015
  18. Kong L, Zhang G, Liu H, Zhang X, Mater. Lett., 141, 344, 2015
  19. Huang A, Liu Q, Wang N, Caro J, J. Mater. Chem. A, 2, 8246, 2014
  20. Drobek M, Bechelany M, Vallicari C, Abou Chaaya A, Charmette C, Salvador-Levehang C, Miele P, Julbe A, J. Membr. Sci., 475, 39, 2015
  21. Wang X, Sun M, Meng B, Tan X, Liu J, Wang S, Liu S, Chem. Commun., 52, 13448, 2016
  22. Neelakanda P, Barankova E, Peinemann KV, Microporous Mesoporous Mater., 220, 215, 2016
  23. Wu M, Ye H, Zhao F, Zeng B, Sci. Rep., 7, 1, 2017
  24. Stassen I, Styles M, Grenci G, Van Gorp H, Vanderlinden W, De Feyter S, Falcaro P, De Vos D, Vereecken P, Ameloot R, Nat. Mater., 15(3), 304, 2016
  25. Yang J, Xie Z, Yin H, Wang J, Xu J, Wang J, Lu J, Yin D, Zhang Y, Microporous Mesoporous Mater., 198, 263, 2014
  26. Lee H, Dellatore SM, Miller WM, Messersmith PB, Science, 318, 426, 2007
  27. Liu Q, Wang NY, Caro J, Huang AS, J. Am. Chem. Soc., 135(47), 17679, 2013
  28. Huang AS, Liu Q, Wang NY, Zhu YQ, Caro J, J. Am. Chem. Soc., 136(42), 14686, 2014
  29. Cravillon J, Schroder CA, Bux H, Rothkirch AA, Caro J, Wiebcke M, CrystEngComm, 14, 492, 2012
  30. Shah M, Kwon HT, Tran V, Sachdeva S, Jeong HK, Microporous Mesoporous Mater., 165, 63, 2013
  31. Abdullah N, Rahman MA, Othman MHD, Ismail AF, Jaafar J, Aziz AA, Ceram. Int., 42, 12312, 2016
  32. Zhou C, Yuan CF, Zhu YQ, Caro J, Huang AS, J. Membr. Sci., 494, 174, 2015
  33. Li K, Ceramic Membranes for Separation and Reaction, Wiley (2007).
  34. Garcia-Garcia FR, Rahman MA, Kingsbury BFK, Li K, Appl. Catal. A: Gen., 393(1-2), 71, 2011
  35. Wei Q, Zhang F, Li J, Li B, Zhao C, Polym. Chem., 1, 1430, 2010
  36. Barras A, Lyskawa J, Szunerits S, Woisel P, Boulcherroub R, Langmuir, 27(20), 12451, 2011
  37. Mcguire CV, Forgan RS, Chem. Commun., 51, 5199, 2014
  38. Cravillon J, Nayuk R, Springer S, Feldhoff A, Huber K, Wiebcke M, Chem. Mater., 23, 2130, 2011
  39. Zhang HF, James J, Zhao M, Yao Y, Zhang YS, Zhang BQ, Lin YS, J. Membr. Sci., 532, 1, 2017
  40. Gray GT, McCutcheon JR, Elimelech M, Desalination, 197(1-3), 1, 2006
  41. Gupta KM, Zhang K, Jiang JW, Langmuir, 31(48), 13230, 2015
  42. Hu Z, Chen Y, Jiang J, J. Chem. Phys., 134, 134705, 2011
  43. Fairen-Jimenez D, Moggach SA, Wharmby MT, Wright PA, Parsons S, Duren T, J. Am. Chem. Soc., 133(23), 8900, 2011