Korean Journal of Chemical Engineering, Vol.35, No.11, 2232-2240, 2018
Valorization of galactose into levulinic acid via acid catalysis
We applied methanesulfonic acid (MSA) as a green catalyst to produce levulinic acid (LA) from monomeric sugars. To optimize reaction factors and assess the effect of reciprocal interactions, a statistical experimental design was applied. Optimized result of 40.7% LA yield was obtained under the following conditions: 60 g/L galactose, 0.4M MSA at 188 °C for 26.7 min. On the other hand, 66.1% LA yield was achieved under 60 g/L fructose and 0.4M MSA at 188 °C for 36 min conditions. For the effect of combined severity factor on the LA yield from galactose, the LA yield showed a peaked pattern, which was linearly increased until a CSF 3.2 and then diminished with a high CSF. Moreover, it was closely fitted to a non-linear Gaussian peak pattern with a high regression value of 0.989. These results suggest that MSA and galactose, derived from marine red macro-algae, can potentially be applied for the conversion into platform chemicals.
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[Cited By]
Gong C, Wei J, Tang X, Zeng X, Sun Y, Lin L, Korean Journal of Chemical Engineering , 36 (5), 740, 2019
Jeong GT, Kim SK, Korean Chemical Engineering Research , 58 (2), 293, 2020
Jeong GT, Kim SK, Korean Journal of Chemical Engineering , 38 (5), 997, 2021
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