Korean Journal of Chemical Engineering, Vol.35, No.10, 1988-1993, 2018
Reduced graphene oxide supported V2O5-WO3-TiO2 catalysts for selective catalytic reduction of NOx
We present a reduced-graphene-oxide (rGO)-supported V2O5-WO3-TiO2 (VWTi) catalysts for the efficient selective catalytic reduction of NOx. The rGO support provides well-dispersed functional sites for the nucleation of nanoparticles, allowing the formation of VWTi catalysts with high specific surface areas. The dispersion of the nanoparticles, as observed by transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS), confirmed the uniform dispersion of the particles on the rGO surface. Detailed Fourier-transform infrared (FT-IR) and NH3 temperature-programmed desorption (NH3-TPD) analyses indicated that the high density of acidic sites provided by the rGO is key to the observed enhancement of NOx removal efficiency, and the rGO-supported catalysts exhibit improved NOx removal efficiencies with smaller amounts of V2O5 and WO3 compared with the commercially available V2O5-WO3-TiO2 catalysts.
[References]
Andreoli S, Deorsola FA, Galletti C, Pirone R, Chem. Eng. J. , 278 , 174, 2015
Hwang J, Ha HJ, Ryu J, Choi JJ, Ahn CW, Kim JW, Hahn BD, Yoon WH, Lee H, Choi JH, Catal. Commun. , 94 , 1, 2017
Ko J, Jin D, Jang W, Myung CL, Kwon S, Park S, Appl. Energy , 187 , 652, 2016
Qi C, Bao W, Wang L, Li H, Wu W, Catalysts , 7 , 110, 2017
Chen JP, Yang RT, Appl. Catal. A: Gen. , 80 , 135, 1992
Xiao X, Xiong SC, Li B, Geng Y, Yang SJ, Catal. Lett. , 146 (11), 2242, 2016
Choi JH, Kim SK, Bak YC, Korean J. Chem. Eng. , 18 (5), 719, 2001
Long RQ, Yang RT, J. Catal. , 186 , 254, 1991
Li B, Wu C, Li Y, Zhang J, Environ. Sci. Technol. , 45 , 7394, 2011
Wu X, Si Z, Li G, Weng D, Ma Z, J. Rare Earths. , 29 , 64, 2011
Kamata H, Ueno S, Naito T, Yukimura A, Ind. Eng. Chem. Res. , 47 (21), 8136, 2008
Madia G, Elsener M, Koebel M, Raimondi F, Wokaun A, Appl. Catal. A: Gen. , 39 , 181, 2002
Djerad S, Tifouti L, Crocoll M, Weisweiler W, J. Mol. Catal. A-Chem. , 208 (1-2), 257, 2004
Alemany LJ, Lietti L, Ferlazzo N, Forzatti P, Busca G, Giamello E, Bregani F, J. Catal. , 155 (1), 117, 1995
Ehrlich VA, Nersesyan AK, Hoelzl C, Ferk F, et al., Environ. Health Perspect. , 116 , 1689, 2008
Turkez H, Sonmez E, Turkez O, Mokhtar YI, Di Stefano A, Turgut G, Braz. Arch. Biol. Technol. , 57 , 532, 2014
Cao M, Wang XX, Cao WQ, Yuna J, J. Mater. Chem. C , 3 , 6589, 2015
Zhu YW, Murali S, Cai WW, Li XS, Suk JW, Potts JR, Ruoff RS, Adv. Mater. , 22 (35), 3906, 2010
Su W, Lu XN, Jia SH, Wang J, Ma HZ, Xing Y, Catal. Lett. , 145 (7), 1446, 2015
Lee KK, Deng S, Fan HM, Mhaisalkar S, Tan HR, Tok ES, Loh KP, Chin WS, Sow CH, Nanoscale , 4 , 2958, 2012
Wang P, Zhai Y, Wang D, Dong S, Nanoscale , 3 , 1640, 2010
Mao S, Cui S, Lu G, Yu K, Wen Z, Chen J, J. Mater. Chem. , 22 , 11009, 2012
Aguilar-Romero M, Camposeco R, Castillo S, Marin J, Rodriguez-Gonzalez V, Garcia-Serrano LA, Mejia-Centeno I, Fuel , 198 , 123, 2017
Nguyen VK, Park JH, Shin CH, Korean J. Chem. Eng. , 31 (4), 582, 2014
Kwon DW, Nam KB, Hong SC, Appl. Catal. A: Gen. , 497 , 160, 2015
VGB Technical Association of Large Power Plant Operators, Guideline for the testing of deNOx catalysts, VGB PowerTech, Essen (1998).
Lu XN, Song CY, Chang CC, Teng YX, Tong ZS, Tang XL, Ind. Eng. Chem. Res. , 53 (29), 11601, 2014
Shen S, Wang X, Chen T, Feng Z, Li C, J. Phys. Chem. C , 118 , 12661, 2014
Shen B, Liu T, Zhao N, Yang X, Deng L, J. Environ. Sci. , 22 , 1447, 2010
Matralis HK, Papadopoulou C, Kordulis C, Elguezabal AA, Corberan VC, Appl. Catal. A: Gen. , 126 (2), 365, 1995
Wang CZ, Yang SJ, Chang HZ, Peng Y, Li JH, Chem. Eng. J. , 225 , 520, 2013
Nova I, Tronconi E, Urea-SCR Technology for deNOx After Treatment of Diesel Exhausts, Springer, New York (2014).
Kongsong P, Sikong L, Niyomwas S, Rachpech V, Sci. World J. , 2014 , 869706, 2014
Zheng H, Neo CY, Mei X, Qiu J, Ouyang J, J. Mater. Chem. , 22 , 14465, 2012
Mjejri I, Etteyeb N, Sediri F, Mater. Res. Bull. , 48 (9), 3335, 2013
Wang S, Guo T, Pan W, Li M, Sun P, Liu S, Liu S, Sun X, Liu J, Phys. Chem. Chem. Phys. , 19 , 5333, 2017
Topsoe NY, Dumesic JA, Topsoe H, J. Catal. , 151 (1), 241, 1995
Du X, Gao X, Qiu K, Luo Z, Cen K, J. Phys. Chem. C , 119 , 1905, 2015
Lin CH, Bai H, Appl. Catal. B: Environ. , 42 (3), 279, 2003
Jo SH, Shin B, Shin MC, Van Tyne CJ, Lee H, Catal. Commun. , 57 , 134, 2014
[Cited By]
Lu Q, Ali Z, Tang H, Iqbal T, Arain Z, Cui MS, Liu DJ, Li WY, Yang YP, Korean Journal of Chemical Engineering , 36 (3), 377, 2019
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