Issue
Korean Journal of Chemical Engineering,
Vol.35, No.10, 1988-1993, 2018
Reduced graphene oxide supported V2O5-WO3-TiO2 catalysts for selective catalytic reduction of NOx
We present a reduced-graphene-oxide (rGO)-supported V2O5-WO3-TiO2 (VWTi) catalysts for the efficient selective catalytic reduction of NOx. The rGO support provides well-dispersed functional sites for the nucleation of nanoparticles, allowing the formation of VWTi catalysts with high specific surface areas. The dispersion of the nanoparticles, as observed by transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS), confirmed the uniform dispersion of the particles on the rGO surface. Detailed Fourier-transform infrared (FT-IR) and NH3 temperature-programmed desorption (NH3-TPD) analyses indicated that the high density of acidic sites provided by the rGO is key to the observed enhancement of NOx removal efficiency, and the rGO-supported catalysts exhibit improved NOx removal efficiencies with smaller amounts of V2O5 and WO3 compared with the commercially available V2O5-WO3-TiO2 catalysts.
[References]
  1. Andreoli S, Deorsola FA, Galletti C, Pirone R, Chem. Eng. J., 278, 174, 2015
  2. Hwang J, Ha HJ, Ryu J, Choi JJ, Ahn CW, Kim JW, Hahn BD, Yoon WH, Lee H, Choi JH, Catal. Commun., 94, 1, 2017
  3. Ko J, Jin D, Jang W, Myung CL, Kwon S, Park S, Appl. Energy, 187, 652, 2016
  4. Qi C, Bao W, Wang L, Li H, Wu W, Catalysts, 7, 110, 2017
  5. Chen JP, Yang RT, Appl. Catal. A: Gen., 80, 135, 1992
  6. Xiao X, Xiong SC, Li B, Geng Y, Yang SJ, Catal. Lett., 146(11), 2242, 2016
  7. Choi JH, Kim SK, Bak YC, Korean J. Chem. Eng., 18(5), 719, 2001
  8. Long RQ, Yang RT, J. Catal., 186, 254, 1991
  9. Li B, Wu C, Li Y, Zhang J, Environ. Sci. Technol., 45, 7394, 2011
  10. Wu X, Si Z, Li G, Weng D, Ma Z, J. Rare Earths., 29, 64, 2011
  11. Kamata H, Ueno S, Naito T, Yukimura A, Ind. Eng. Chem. Res., 47(21), 8136, 2008
  12. Madia G, Elsener M, Koebel M, Raimondi F, Wokaun A, Appl. Catal. A: Gen., 39, 181, 2002
  13. Djerad S, Tifouti L, Crocoll M, Weisweiler W, J. Mol. Catal. A-Chem., 208(1-2), 257, 2004
  14. Alemany LJ, Lietti L, Ferlazzo N, Forzatti P, Busca G, Giamello E, Bregani F, J. Catal., 155(1), 117, 1995
  15. Ehrlich VA, Nersesyan AK, Hoelzl C, Ferk F, et al., Environ. Health Perspect., 116, 1689, 2008
  16. Turkez H, Sonmez E, Turkez O, Mokhtar YI, Di Stefano A, Turgut G, Braz. Arch. Biol. Technol., 57, 532, 2014
  17. Cao M, Wang XX, Cao WQ, Yuna J, J. Mater. Chem. C, 3, 6589, 2015
  18. Zhu YW, Murali S, Cai WW, Li XS, Suk JW, Potts JR, Ruoff RS, Adv. Mater., 22(35), 3906, 2010
  19. Su W, Lu XN, Jia SH, Wang J, Ma HZ, Xing Y, Catal. Lett., 145(7), 1446, 2015
  20. Lee KK, Deng S, Fan HM, Mhaisalkar S, Tan HR, Tok ES, Loh KP, Chin WS, Sow CH, Nanoscale, 4, 2958, 2012
  21. Wang P, Zhai Y, Wang D, Dong S, Nanoscale, 3, 1640, 2010
  22. Mao S, Cui S, Lu G, Yu K, Wen Z, Chen J, J. Mater. Chem., 22, 11009, 2012
  23. Aguilar-Romero M, Camposeco R, Castillo S, Marin J, Rodriguez-Gonzalez V, Garcia-Serrano LA, Mejia-Centeno I, Fuel, 198, 123, 2017
  24. Nguyen VK, Park JH, Shin CH, Korean J. Chem. Eng., 31(4), 582, 2014
  25. Kwon DW, Nam KB, Hong SC, Appl. Catal. A: Gen., 497, 160, 2015
  26. VGB Technical Association of Large Power Plant Operators, Guideline for the testing of deNOx catalysts, VGB PowerTech, Essen (1998).
  27. Lu XN, Song CY, Chang CC, Teng YX, Tong ZS, Tang XL, Ind. Eng. Chem. Res., 53(29), 11601, 2014
  28. Shen S, Wang X, Chen T, Feng Z, Li C, J. Phys. Chem. C, 118, 12661, 2014
  29. Shen B, Liu T, Zhao N, Yang X, Deng L, J. Environ. Sci., 22, 1447, 2010
  30. Matralis HK, Papadopoulou C, Kordulis C, Elguezabal AA, Corberan VC, Appl. Catal. A: Gen., 126(2), 365, 1995
  31. Wang CZ, Yang SJ, Chang HZ, Peng Y, Li JH, Chem. Eng. J., 225, 520, 2013
  32. Nova I, Tronconi E, Urea-SCR Technology for deNOx After Treatment of Diesel Exhausts, Springer, New York (2014).
  33. Kongsong P, Sikong L, Niyomwas S, Rachpech V, Sci. World J., 2014, 869706, 2014
  34. Zheng H, Neo CY, Mei X, Qiu J, Ouyang J, J. Mater. Chem., 22, 14465, 2012
  35. Mjejri I, Etteyeb N, Sediri F, Mater. Res. Bull., 48(9), 3335, 2013
  36. Wang S, Guo T, Pan W, Li M, Sun P, Liu S, Liu S, Sun X, Liu J, Phys. Chem. Chem. Phys., 19, 5333, 2017
  37. Topsoe NY, Dumesic JA, Topsoe H, J. Catal., 151(1), 241, 1995
  38. Du X, Gao X, Qiu K, Luo Z, Cen K, J. Phys. Chem. C, 119, 1905, 2015
  39. Lin CH, Bai H, Appl. Catal. B: Environ., 42(3), 279, 2003
  40. Jo SH, Shin B, Shin MC, Van Tyne CJ, Lee H, Catal. Commun., 57, 134, 2014