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Issue
Korean Journal of Chemical Engineering,
Vol.35, No.7, 1389-1408, 2018
A review on metal nitrides/oxynitrides as an emerging supercapacitor electrode beyond oxide
Ghosh S, Jeong SM, Polaki SR
Electrode materials design is the most significant aspect in constructing a supercapacitor device. The evolution of metal nitrides/oxynitrides as supercapacitor electrode is strikingly noticeable today besides prevailing carbon or 2D materials, metal oxides/hydroxides and conducting polymers electrode materials. The theoretically estimated specific capacitance of a nitride-based supercapacitor is 1,560 F g-1. These nanostructures exhibit an excellent capacitive behavior with a specific capacitance of 15-951.3mF cm-2 or 82-990 F g-1, high energy density (16.5-162Wh Kg-1) and power density (7.3-54,000W Kg-1). On this account, supercapacitor performance of metal nitrides/oxynitrides is reviewed exclusively. The major focus of the present review is directed towards state-of-art progress in supercapacitor performance of nitrides/oxynitrides, underlying charge-storage mechanism, important outcomes and their limitations. Finally, we conclude with challenges and prospects of metal nitrides/oxynitrides for supercapacitor electrodes.
Keywords: Supercapacitor; Energy Storage Materials; Metal Nitrides; Metal Oxynitrides; Pseudocapacitance
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  2. Chu CH, Kwon BW, Lee WM, Kwon YC, Korean Journal of Chemical Engineering, 36(10), 1732, 2019
  3. Lim EH, Chun JY, Jo CS, Hwang JK, Korean Journal of Chemical Engineering, 38(2), 227, 2021
  4. Saroha R, Ahn JH, Cho JS, Korean Journal of Chemical Engineering, 38(3), 461, 2021
  5. Baasanjav E, Bandyopadhyay P, Saeed G, Lim SM, Jeong SM, Journal of Industrial and Engineering Chemistry, 99, 299, 2021
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