Korean Journal of Chemical Engineering, Vol.35, No.3, 626-636, 2018
Kinetics of perovskite-like oxygen carriers for chemical looping air separation
Chemical looping air separation gives an energy-efficient choice for oxygen production. We performed kinetic analysis of YBaCo4O7+δ, Y0.95Ti0.05BaCo4O7+δ, Y0.2Ti0.05Dy0.75BaCo4O7+δ, and Y0.15Zr0.1Dy0.75BaCo4O7+δ oxygen carriers in a CLAS process. TG experiments were conducted with heating rates of 0.5, 1, and 2 oC/min in a thermogravimetric analyzer. Further exploration is required to develop an appropriate oxygen carrier. So, we used the model-free approach, Starink method, to evaluate the apparent activation energy. And, masterplots method was applied to determine the most probable mechanism function. The results show that the distributed activation energies of oxidation/ reduction process are 189.42/286.22 kJ/mol, 197.70/324.87 kJ/mol, 195.41/310.4 kJ/mol, and 192.20/293.53 kJ/mol for YBaCo4O7+δ, Y0.95Ti0.05BaCo4O7+δ, Y0.2Ti0.05Dy0.75BaCo4O7+δ, and Y0.15Zr0.1Dy0.75BaCo4O7+δ oxygen carriers, respectively. Random nucleation and nuclei growth A model is the most suitable for oxidation process. The A model and D are the most suitable for the reduction process. Regarding YBaCo4O7+δ, Y0.95Ti0.05BaCo4O7+δ, Y0.2Ti0.05Dy0.75BaCo4O7+δ, and Y0.15Zr0.1Dy0.75BaCo4O7+δ kinetic, oxygen transfer materials are rate-determined by nucleation and nuclei growth. For eduction kinetic, the gas diffusion stage could also become a dominant step.
[References]
Shah K, Moghtaderi B, Zanganeh J, Wall T, Fuel , 107 , 356, 2013
Smith AR, Klosek J, Fuel Process. Technol. , 70 (2), 115, 2001
Moghtaderi B, Energy Fuels , 24 (1), 190, 2010
Song H, Shah K, Doroodchi E, Wall T, Moghtaderi B, Energy Fuels , 28 , 173, 2013
Song H, Shah K, Doroodchi E, Moghtaderi B, Energy Fuels , 28 (1), 163, 2014
Shulman A, Cleverstam E, Mattisson T, Lyngfelt A, Energy Fuels , 23 , 5269, 2009
Wang K, Yu QB, Xie HQ, Qin Q, Funct. Mater. Lett. , 6 (2), 135002, 2013
Song H, Shah K, Doroodchi E, Wall T, Moghtaderi B, Energy Fuels , 28 (2), 1284, 2014
Wang K, Yu QB, Qin Q, Zuo ZL, J. Therm. Anal. Calorim. , 119 , 2221, 2014
Wang K, Yu QB, Qin Q, Energy Fuels , 27 (9), 5466, 2013
Ishida M, Yamamoto M, Ohba T, Energy Conv. Manag. , 43 (9-12), 1469, 2002
Mattisson T, Leion H, Lyngfelt A, Fuel , 88 (4), 683, 2009
Arjmand M, Azad AM, Leion H, Lyngfelt A, Mattisson T, Energy Fuels , 25 (11), 5493, 2011
Wang K, Yu QB, Qin Q, J. Therm. Anal. Calorim. , 112 (2), 747, 2013
Azimi G, Leion H, Ryden M, Mattisson T, Lyngfelt A, Energy Fuels , 27 (1), 367, 2013
Wang K, Yu QB, Qin Q, Zuo Z, J. Therm. Anal. Calorim. , 119 (3), 2221, 2015
Zhao K, He F, Huang Z, Wei G, Zheng A, Li H, Zhao Z, Korean J. Chem. Eng. , 34 (6), 1651, 2017
Kwak BS, Park NK, Baek JI, Ryu HJ, Kang MS, Korean J. Chem. Eng. , 34 (7), 1936, 2017
Motohashi T, Kadita S, Fjellvag H, Karppinen M, Yamauchi H, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol. , 148 (1), 196, 2008
Karppinen M, Yanauchi H, Otani S, Fujita T, Motohashi T, Huang YH, Valkeapaa M, Fjellvag H, Chem. Mater. , 18 (2), 490, 2006
Kadita S, Kappinen M, Motohashi T, Yamauchi H, Chem. Mater. , 20 , 6378, 2008
Wang S, Hao HS, Zhu BF, Jia JF, Hu X, J. Mater. Sci. , 43 (15), 5385, 2008
Hao HS, He QL, Cheng YG, Zhao LM, J. Phys. Chem. Solids , 75 (4), 495, 2014
Zhang SM, MA Dissertation, ZhengZhou University (2011).
Guo LJ, MA Dissertation, ZhengZhou University (2005).
Kozeeva LP, Kameneva MY, Lavrov AN, Podberezskaya NV, Inorg Mater. , 49 (6), 626, 2013
Parkkima O, Yamauchi H, Karppinen M, Chem. Mater. , 25 (4), 599, 2013
Martin V, Solid State Sci. , 7 (10), 1163, 2005
Rasanen S, Motohashi T, Yamauchi H, Kappinen M, J. Solid State Chem. , 183 , 692, 2010
Komiyama T, Motohashi T, Masubuchi Y, Kikkawa S, Mater. Res. Bull. , 45 (10), 1527, 2010
Rasanen S, Parkkima O, Rautama EL, Yamauchi H, Karppinen M, Solid State Ion. , 208 , 31, 2012
Jankovic B, Adnadevic B, Jovanovic J, Thermochim. Acta , 452 (2), 106, 2007
Vyazovkin S, Thermochim. Acta , 355 , 145, 2000
Brown ME, Dollimore D, Galwey AK, Elsevier, Amsterdam., 22, 41 (1980).
Vyazovkin S, Wight CA, Thermachim. Acta , 341 , 53, 1999
Vyazovkin S, Wight CA, J. Phys. Chem. A , 101 (39), 7217, 1997
Coats AW, Redfern JP, Nature , 201 , 68, 1964
Coats AW, Redfern JP, J. Polym. Sci. Part B: Polym. Lett. , 3 , 917, 1965
Ozawa T, Bull. Chem. Soc. Jpn. , 38 , 1881, 1965
Doyle CD, Anal. Chem. , 33 , 77, 1961
Doyle CD, J. Appl. Polym. Sci. , 5 , 285, 1961
Doyle CD, Nature , 207 , 290, 1965
Kissinger HE, Anal. Chem. , 29 , 1702, 1957
Akahira T, Sunose T, Res. Rep. Chiba. Inst. Technol. , 16 , 22, 1971
Vyazovkin SV, Lesnikovich AI, Thermochim. Acta , 34 (3), 609, 1988
Agrawal PK, Thermochim. Acta , 203 , 93, 1992
Starink MJ, Thermochim. Acta , 288 (1-2), 97, 1996
Vyazovkin S, Burnham AK, Criado JM, Perez-Maqueda LA, Popescu C, Sbirrazzuoli N, Thermochim. Acta , 520 (1-2), 1, 2011
Wanjun T, Yuwen L, Hen Z, Cunxin W, Thermochim. Acta , 74 , 309, 2003
Gotor FJ, Criado JM, Malek J, Koga N, J. Phys. Chem. A , 104 (46), 10777, 2000
Wanjun T, Yuwen L, Hen Z, Cunxin W, Thermochim. Acta , 74 , 309, 2003
Jin H, Okamoto T, Ishida M, Energy Fuels , 12 (6), 1272, 1998
Halikia I, Neou-Syngouna P, Kolitsa D, Thermochim. Acta , 320 (1-2), 75, 1998
Perkins C, Lichty P, Weimer AW, Chem. Eng. Sci. , 62 (21), 5952, 2007
Pineau A, Kanari N, Gaballah I, Thermochim. Acta , 447 (1), 89, 2006
Hossain MM, de Lasa HI, Chem. Eng. Sci. , 65 (1), 98, 2010
Hossain MM, de Lasa HI, Chem. Eng. Sci. , 63 (18), 4433, 2008
Sun YQ, Sridhar S, Seetharaman S, Wang H, Liu LL, Wang XD, Zhang ZT, Sci. Rep. , 6 , 1, 2016
Hossain MM, de Lasa HI, Chem. Eng. Sci. , 65 (1), 98, 2010
Hossain MM, de Lasa HI, Chem. Eng. Sci. , 63 (18), 4433, 2008
Hancock JD, Sharp JH, J. Am. Ceram. Soc. , 55 (2), 74, 1972
이전 논문 다음 논문
Result Search