About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
  Guidelines for Publication
  Ethics
Articles & Issues
  Search
  Issue
  Online First
  KJChE on
For Authors
  Instructions to Authors
  Ethical Responsibilities of
  Authors in KJChE
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
Issue
Korean Journal of Chemical Engineering,
Vol.35, No.2, 511-517, 2018
Characteristics and kinetics analyses of different genus biomass pyrolysis
Yao C, Tian H, Hu Z, Yin Y, Chen D, Yan X
Four kinds of biomass (Chinese silvergrass, corn stalk, rice husk and pine) in China were selected as experimental samples for this study. Pyrolysis process of these biomass was researched by thermogravimetric Fourier transform infrared spectroscopy at 10 K/min. The results show that the pyrolysis process of all samples can be divided into three stages, and the comprehensive characteristics of volatile release degree of Chinese silvergrass is the highest, followed by corn stalk and rice husk, the lowest is pine. FTIR spectra results indicate that the pyrolysis gaseous products are mainly CO2, CO, CH4 and H2O. Kinetic parameters of the biomass were analyzed and determined by Coats-Redfern method, and the results show that corn stalk is the most susceptible to pyrolysis because the activation energy of Chinese silvergrass, corn stalk, rice husk and pine are 46.7, 29.3, 54.3 and 58.1 kJ/mol respectively.
Keywords: TG-FTIR; Biomass; Coats-redfern Method; Kinetic Analysis
[References]
  1. Yan JD, Chem. Ind. Forest Products, 34, 151, 2014
  2. Xiao J, Duan JC, Wang H, Zhuang XG, Safety Environmental Engineering, 10, 11, 2003
  3. Wang JM, Cai FP, Jin FQ, Wang B, Jiang B, Adv. Mater. Res., 512, 468, 2012
  4. Yu XW, Ji HB, Chen SZ, Liu XG, Zeng QZ, Adv. Mater. Res., 806, 260, 2013
  5. Fu DZ, Tang Y, Fu ZH, Li W, Adv. Mater. Res., 884, 148, 2014
  6. Fu XF, Zhong ZP, Xiao G, Li R, Boiler Technol., 25, 199, 2009
  7. Chen ZH, Hu M, Zhu XL, Guo DB, Liu SM, Hu ZQ, Xiao B, Wang JB, Laghari M, Bioresour. Technol., 192, 441, 2015
  8. Wang J, Wang G, Zhang MX, Chen MQ, Li DM, Min FF, Chen MG, Zhang SP, Ren ZW, Yan YJ, Process Biochem., 41(8), 1883, 2006
  9. Wang J, Zhang MQ, Chen MQ, Min FF, Zhang SP, Ren ZW, Yan YJ, Thermochim. Acta, 444(1), 110, 2006
  10. Zhao H, Yan HX, Liu M, Zhang CW, Qin S, Chinese J. Oceanology Limnology, 29, 996, 2011
  11. Zhao H, Yan HX, Liu M, Zhang CW, Qin S, Adv. Mater. Res., 113, 170, 2010
  12. Abdelouaned L, Leveneur S, Hassimi LV, Balland L,Taouk B, J. Therm. Anal. Calorim., 129, 1201, 2017
  13. Bach QV, Chen WH, Energy Conv. Manag., 131, 109, 2017
  14. Kim YM, Han TU, Wang BH, Lee B, Lee HW, Park YK, Kim S, Korean J. Chem. Eng., 33, 1, 2016
  15. Long Y, Zhou H, Meng A, Li Q, Zhang Y, Korean J. Chem. Eng., 33(9), 2638, 2016
  16. Haykiri-Acma H, Yaman S, Fuel, 86(3), 373, 2007
  17. Transplantation, Wang TP, Ye XN, Lu Q, Zhang ZB, Dong CQ, Transactions of the Chinese Society of Agricultural Engineering, 430, 223 (201).
  18. Huang YQ, Wei ZG, Yin XL, Wu CZ, Transactions of the Chinese Society for Agricultural Machinery, 43, 86 (2012).
  19. Hu S, Sun LS, Xiang J, Qiu JR, Xu MH, CIESC J., 58, 2889, 2007
  20. Sevim F, Demir F, Bilen M, Okur H, Korean J. Chem. Eng., 23(5), 736, 2006
  21. Wang SR, Luo ZY, Pyrloysis of Biomass Components, Science Press, Beijing (2013).
  22. Raveendran K, Ganesh A, Khilar KC, Fuel, 75, 987, 1996
  23. Vamvuka D, Kakaras E, Kastanaki E, Grammelis P, Fuel, 82(15-17), 1949, 2003
  24. Gu LF, Chen XP, Zhao CS, J. of Engineering for Thermal Energy and Power, 18, 561 (2003).
  25. Xiao J, Shen LH, Zheng M, Acta Energiae Solaris Sinica, 28, 972, 2007
  26. Yang HP, Yan R, Chen HP, Lee DH, Zheng CG, Fuel, 86(12-13), 1781, 2007
  27. Che DY, Jiang WQ, J. Chinese Agricultural Mechanization, 37, 241, 2016
  28. Gu XL, Ma X, Li LX, Acta Petrolei Sinica, 29, 174, 2013
  29. Liu C, Zhang YY, Huang XL, Fuel Process. Technol., 123, 159, 2014
  30. Fu P, Hu S, Sun LS, Xiang J, Chen QQ, Yang T, Proceedings of The Chinese Society for Electrical Engineering, 29, 113 (2009).
  31. Brebu M, Vasile C, Cell Chem. Technol., 44, 353, 2010
  32. Yao DL, Jin BL, Tao H, Energy Research Utilization, 20, 11, 2008
  33. Xiang Y, Xiang Y, Wang L, J. Environ. Chem. Eng., 4, 3303, 2016
  34. Lim A, Chin B, Jawad Z, Procedia Eng., 148, 1247, 2016
  35. Cai JM, He F, Yi WM, Yao FS, Chem. Eng. J., 124(1-3), 15, 2006
  36. Liu JL, Chinese Academy of Forestry (2012).
  37. Marini A, Berbenni V, Flor G, Zeitschrift Fur Naturforschung A, 34, 661, 1979
[Cited By]
  1. Bak YC, Choi JH, Korean Chemical Engineering Research, 56(5), 725, 2018
  2. Yao X, Yu Q, Xu G, Han Z, Qin Q, Korean Journal of Chemical Engineering, 36(5), 722, 2019
  3. Ozsin G, Kilic M, Apaydin-Varol E, Putun AE, Putun E, Korean Journal of Chemical Engineering, 37(11), 1888, 2020
  4. Park HJ, Oh SS, Olanrewaju ON, Ling JLJ, Jeong CS, Park HS, Lee SH, Korean Chemical Engineering Research, 61(1), 8, 2023
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.