About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
  Guidelines for Publication
  Ethics
Articles & Issues
  Search
  Issue
  Online First
  KJChE on
For Authors
  Instructions to Authors
  Ethical Responsibilities of
  Authors in KJChE
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
Issue
Korean Journal of Chemical Engineering,
Vol.34, No.12, 3185-3194, 2017
Preparation and characterization of a porous silicate material from silica fume
Zhang Y, Qi H, Li Y, Zhang Y, Sun J
A porous silicate material derived from silica fume was successfully prepared and characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Fourier-transform infrared (FT-IR) spectroscopy, Thermogravimetry and Differential thermal gravity (TG-DTG), N2 adsorption and desorption isotherms, and scanning electron microscopy (SEM). Raw silica fume was analyzed by XRD, FT-IR and SEM. The analysis results of silica fume indicated that SiO2 in silica fume is mainly determined as amorphous state, and that the particles of raw silica fume exhibited characteristic spherical structure with a diameter of from 50 nm to 200 nm. The preparation of the porous silicate material involved two steps. The first step was the extraction of the SiO3 2- leachate from raw silica fume. The maximum value of SiO3 2- extraction yield was obtained under the following conditions: reaction temperature of 120 °C, reaction time of 120 min, NaOH concentration of 15%, and alkali to SiO2 molar ratio of 2. The second step was the preparation of the porous silicate material though the reaction of SiO3 2- leachate and Ca(OH)2 suspension liquid. The optimum preparation conditions were as follows: preparation temperature of 90 °C, preparation time of 1.5 h, Si/Ca molar ratio of 1 : 1, and stirring rate of 100 r/min. The BET surface area and pore size of the porous silicate material were 220.7m2·g-1 and 8.55 cm3/g, respectively. The porous silicate material presented an amorphous and unordered structure. The spectroscopic results indicated that the porous silicate material was mainly composed of Si, Ca, O, C, and Na, in the form of Ca2+, SiO3 2-, CO3 2- and Na+ ions, respectively, which agreed with the XRD, TG-DSC, and FT-IR data. The N2 adsorption-desorption isotherm mode indicates that the porous silicate material belonged to a typical mesoporous material. The porous silicate material presented efficiency for the removal of formaldehyde: it showed a formaldehyde adsorption capacity of 8.01mg/g for 140 min at 25 °C.
Keywords: Silica Fume; Porous Silicate Material; Preparation; Mesoporous Material
[References]
  1. Li X, Korayem AH, Li C, Liu Y, He H, Sanjayan JG, Duan WH, Constr Build Mater., 123 (2016).
  2. Jinliang Z, Zhancheng G, Xin Z, Huiqing T, Chin. J. Pro. Eng., 12 (2012).
  3. Zhou C, Yan C, Zhao J, Wang H, Zhou Q, Luo W, J. Taiwan. Inst. Chem. E, 62 (2016).
  4. Ji H, Huang Z, Chen K, Li W, Gao Y, Fang M, Liu Y, Wu X, Powder. Technol., 252 (2014).
  5. Mastali M, Dalvand A, Constr. Build. Mater., 125 (2016).
  6. Fakhri M, Saberi F. K, J. Clean. Prod., 129 (2016).
  7. Ramezanianpour AA, Springer Berlin Heidelberg, 193 (2014).
  8. Lijuan L, Tielong L, Zhaohui J, Chin. J. Enviro. Eng., 4 (2010).
  9. Lilkov V, Petrov O, Kovacheva D, Rostovsky I, Tzvetanova Y, Petkova V, Petrova N, Constr. Build. Mater., 124 (2016).
  10. Okoye FN, Durgaprasad J, Singh NB, Ceram. Int., 42 (2016).
  11. Gaoping H, Weidong X, Henan. Chem. Ind., 07 (2006).
  12. Deyi Z, Huixia F, Heming L, Yi W, Xuefu C, Yanjun W, Chin. Non-Metallic. Miner. Ind., 5 (2009).
  13. Li W, Ping X, Xu Y, Li H, Yi Z, Tang Y, Concrete., 6 (2011).
  14. Zhu H, Shandong University of Science and Technology Doctor Degree (2009).
  15. Hai H, Zhang Y, Zhang Y, Sun J, Hao Z, Chin. J. Enviro. Eng., 11 (2017).
  16. Zhang J, Guo Z, XZ, HT, Chinese J. Environ. Eng., 12, 2, 2012
  17. Azouaoua N, Sadaou Z, Djaafri A, et al., J. Hazar. Mater., 184 (2010).
  18. Anirudhan T S, RadhakrishLnan P G, Thermodynamics., 40 (2008).
  19. Langmuir I, J. Am. Chem. Soc., 40, 1361, 1918
  20. Onisei S, Pontikes Y, Gerven TV, Angelopoulos GN, Velea T, Predica V, Moldovan P, J. Hazard. Mater., 101 (2012).
  21. Gao Y, Huang H, Tang W, Liu X, Yang X, Zhang J, Micropor, Mesopor. Mater., 217 (2015).
  22. Maximo GJ, Meirelles AJA, Batista EAC, Fluid Phase Equilibr., 299 (2010).
  23. Wang R, Zhai Y, Ning Z, Ma P, T Nonferr Metal Soc., 24 (2014).
  24. Yadav RR, Mudliar SN, Shekh AY, Fulke AB, Devi SS, Krishnamurthi K, Juwarkar A, Chakrabarti T, Process Biochem., 47 (2012).
  25. Sun J, Wu Z, Cheng H, Zhang Z, Frost RL, Spectro. Act. Part A: Mole. and Biomo. Spec., 117 (2014).
  26. Yang X, Liu X, Tang W, Gao Y, Ni H, Zhang J, Korean J. Chem. Eng., 34, 3, 2017
  27. Li L, Zhang Y, Zhang Y, Sun J, Hao Z, J. Therm. Anal. Calorim. (2016), DOI:10.1007/s10973-016-5711-4.
  28. Zaitan H, Bianchi D, Achak O, Chafik T, J. Hazard. Mater., 153 (2008).
  29. Meiszterics A, Rosta L, Peterlik H, Rohonczy J, Kubuki S, Henits P, Sinko K, J. Phys. Chem. A, 114 (2010).
  30. Zhang Y, Liu Q, Wu Z, Zheng Q, Cheng H, J. Therm. Anal. Calorim. (2012), DOI:10.1007/s10973-011-2038-z.
  31. Zhang Y, Liu Q, Wu Z, Zhang Y, J. Therm. Anal. Calorim. (2015), DOI:10.1007/s10973-015-4652-7.
  32. Xiaoqin P, Huixing Z, Xiaohua J, Guowei X, J. Chin. Cer. Soc., 36 (2008).
  33. Xiaoqin P, Fang H, Le Z, Xuejun Q, Yuanyan T, J. Southwest Jiaotong Univ., 44 (2009).
  34. Jilin H, Xin L, Hanning X, Zhishu Y, Yangxi P, Inorgan Chem. Ind., 41 (2009).
  35. Jingnan H, Junmin S, Xuebin X, Huibin Y, Yungai L, Bulle. Chin. Cer. Soc., 35 (2016).
  36. Tang W, Huang H, Gao Y, Liu X, Yang X, Ni H, Zhang J, Mater. Des., 88 (2015).
  37. Ozkaya B, J. Hazard. Mater., B129, 158, 2006
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.