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Issue
Korean Journal of Chemical Engineering,
Vol.34, No.11, 3009-3016, 2017
A correlation of results measured by cyclic voltammogram and impedance spectroscopy in glucose oxidase based biocatalysts
Christwardana M, Chung YJ, Kwon YC
A new biocatalyst consisting of glucose oxidase (GOx) and polyethylenimine (PEI) immobilized on carbon nanotube (CNT) (CNT/PEI/GOx) was developed, while cyclic voltammogram (CV) behaviors of several related catalysts including the CNT/PEI/GOx were analyzed in terms of charge transfer resistances (Rcts) obtained by measuring Nyquist plots using electrochemical impedance spectroscopy (EIS). A qualitative correlation between the flavin adenine dinucleotide (FAD) redox reactivity measured by the CV and Rct was established. As factors affecting both the FAD reactivity and Rct, concentrations of GOx, glucose, and phosphate buffer solution, electrolyte pH and ambient condition were considered and evaluations of the catalysts using the CV curves and Nyquist plots confirmed that a pattern in the FAD reactivity was closely linked to that in the Rct, implying that FAD reactivities of the catalysts are predicted by the measurements of their Rcts. Even regarding performance of the enzymatic biofeul cells(EBCs) using the reacted catalysts, a pattern of the Rcts is compatible with that in the maximum power densities (MPDs) of the EBCs.
Keywords: Glucose Oxidase; Charge Transfer Resistance; Flavin Adenine Dinucleotide Redox Reactivity; Enzymatic Biofuel Cell; Cyclic Voltammogram
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[Cited By]
  1. Kang SH, Yoo KS, Chung YJ, Kwon YC, Journal of Industrial and Engineering Chemistry, 62, 329, 2018
  2. Christwardana M, Chung YJ, Tannia DC, Kwon YC, Korean Journal of Chemical Engineering, 35(12), 2421, 2018
  3. Lee WM, Kwon YJ, Korean Chemical Engineering Research, 56(6), 890, 2018
  4. Christwardana M, Chung YJ, Kim DH, Kwon YC, Journal of Industrial and Engineering Chemistry, 71, 435, 2019
  5. Lee WM, Chung KY, Kwon YC, Korean Chemical Engineering Research, 57(2), 239, 2019
  6. Chu CH, Kwon BW, Lee WM, Kwon YC, Korean Journal of Chemical Engineering, 36(10), 1732, 2019
  7. Lee WM, Kwon YC, Korean Chemical Engineering Research, 57(5), 695, 2019
  8. Yang JW, Yang SW, Chung YJ, Kwon YC, Korean Journal of Chemical Engineering, 37(1), 176, 2020
  9. Ji JY, Chung YJ, Hyun KH, Chung KY, Kwon YC, Journal of Industrial and Engineering Chemistry, 88, 366, 2020
  10. Yang SW, Chung YJ, Lee KS, Kwon YC, Journal of Industrial and Engineering Chemistry, 90, 351, 2020
  11. Lee JY, Hyun KH, Kwon YC, Journal of Industrial and Engineering Chemistry, 93, 383, 2021
  12. Lee WM, Park GH, Schroder D, Kwon YC, Korean Journal of Chemical Engineering, 39(6), 1624, 2022
  13. Ji JY, Kim SJ, Chung YJ, Kwon YC, Journal of Industrial and Engineering Chemistry, 111, 263, 2022
  14. Lim HS, Shin MG, Noh CH, Koo EM, Kwon YC, Chung KY, Korean Journal of Chemical Engineering, 39(11), 3146, 2022
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