About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
  Guidelines for Publication
  Ethics
Articles & Issues
  Search
  Issue
  Online First
  KJChE on
For Authors
  Instructions to Authors
  Ethical Responsibilities of
  Authors in KJChE
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
Issue
Korean Journal of Chemical Engineering,
Vol.34, No.9, 2488-2497, 2017
Surface modification of silica-graphene nanohybrid as a novel stabilizer for oil-water emulsion
Tajik S, Nasernejad B, Rashidi A
The surface modification of silica-graphene nanohybrid through treatment with a mixture of nitric and sulfuric acid vapors to prepare a novel stabilizer for decalin-water emulsion was investigated. The nanohybrid was prepared through chemical vapor deposition using silica aerogel and acetylene as catalyst and carbon precursor at atmospheric pressure and 600 °C. The physicochemical properties of the modified nanohybrid were characterized by FT-IR, XPS, Raman spectroscopy, and TEM. The surface modification of nanohybrid was at various duration times (24, 48, and 72 hours) to optimize the surface modification conditions. Zeta potential of -39.9 mV revealed that the surface modification of nanohybrid after 72 hours had an excellent stability in aqueous phase due to the presence of exceptional functional groups. The emulsion average droplet size decreased by increasing the nanohybrid concentration. The negative value of the zeta potential showed the proposed nanohybrid can be applied as an appropriate stabilizer for emulsion.
Keywords: Chemical Vapor Deposition; Nanostructures; Functional Groups; Silica-graphene; Stabilizer
[References]
  1. Crossley S, Faria J, Shen M, Resasco DE, Science, 327(5961), 68, 2010
  2. Ma S, Wang Y, Jiang K, Han X, Nano Res., 8, 2603, 2015
  3. Dickinson E, Curr. Opin. Colloid Interface Sci., 15, 40, 2010
  4. Rayner M, Timgren A, Sjoo M, Dejmek P, J. Sci. Food Agric., 92, 1841, 2012
  5. Marku D, Wahlgren M, Rayner M, Sjoo M, Timgren A, Int. J. Pharm., 428, 1, 2012
  6. Leal-Calderon F, Schmitt V, Curr. Opin. Colloid Interface Sci., 13, 217, 2008
  7. Melle S, Lask M, Fuller GG, Langmuir, 21(6), 2158, 2005
  8. Torres L, Iturbe R, Snowden M, Chowdhry B, Leharne S, Colloids Surf. A: Physicochem. Eng. Asp., 302, 439, 2007
  9. Binks BP, Lumsdon SO, Langmuir, 16(23), 8622, 2000
  10. Schrade A, Landfester K, Ziener U, Chem. Soc. Rev., 42, 6823, 2013
  11. Shi JF, Wang XL, Zhang WY, Jiang ZY, Liang YP, Zhu YY, Zhang CH, Adv. Funct. Mater., 23(11), 1450, 2013
  12. Wu CZ, Bai S, Ansorge-Schumacher MB, Wang DY, Adv. Mater., 23(47), 5694, 2011
  13. Zhou J, Qiao XY, Binks BP, Sun K, Bai MW, Li YL, Liu Y, Langmuir, 27(7), 3308, 2011
  14. Chen T, Colver PJ, Bon SAF, Adv. Mater., 19(17), 2286, 2007
  15. Luu XC, Yu J, Striolo A, Langmuir, 29(24), 7221, 2013
  16. Shen M, Resasco DE, Langmuir, 25(18), 10843, 2009
  17. Binks BP, Rodrigues JA, Angew. Chem.-Int. Edit., 117, 445, 2005
  18. Cui YN, Threlfall M, van Duijneveldt JS, J. Colloid Interface Sci., 356(2), 665, 2011
  19. Berton-Carabin CC, Schroen K, Annu. Rev. Food Sci. Technol., 6, 263, 2015
  20. Chen D, Zhang H, Liu Y, Li J, Energy Environ. Sci., 6, 1362, 2013
  21. Yadegari A, Omidi M, Choolaei M, Haghiralsadat F, Yazdian F, Procedia Eng., 87, 967, 2014
  22. Yadegari A, Omidi M, Yazdian F, Zali H, Tayebi L, RSC Adv., 7, 2365, 2017
  23. Omidi M, Fathinia A, Farahani M, Niknam Z, Yadegari A, Hashemi M, Jazayeri H, Zali H, Zahedinik M, Tayebi L, Advanced 2D Materials, 433 (2016).
  24. Hashemi M, Yadegari A, Yazdanpanah G, Jabbehdari S, Omidi M, Tayebi L, RSC Adv., 6, 74072, 2016
  25. Kim J, Cote LJ, Kim F, Yuan W, Shull KR, Huang J, J. Am. Ceram. Soc., 132, 8180, 2010
  26. Song X, Yang Y, Liu J, Zhao H, Langmuir, 27, 1186, 2010
  27. Hoffmann F, Cornelius M, Morell J, Froba M, Angew. Chem.-Int. Edit., 45, 3216, 2006
  28. Ikem VO, Menner A, Bismarck A, Angew. Chem.-Int. Edit., 47, 8277, 2008
  29. Choolaei M, Rashidi AM, Ardjmand M, Yadegari A, Soltanian H, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 538, 288, 2012
  30. Dreyer DR, Park S, Bielawski CW, Ruoff RS, Chem. Soc. Rev., 39, 228, 2010
  31. Wen Y, Ding H, Shan Y, Nanoscale, 3, 4411, 2011
  32. Simmons JM, Nichols BM, Baker SE, Marcus MS, Castellini OM, Lee CS, Hamers RJ, Eriksson MA, J. Phys. Chem. B, 110(14), 7113, 2006
  33. Zhao J, Buldum A, Han J, Lu JP, Nanotechnology, 13, 195, 2002
  34. Ovejero G, Sotelo JL, Romero MD, Rodriguez A, Ocana MA, Rodriguez G, Garcia J, Ind. Eng. Chem. Res., 45(7), 2206, 2006
  35. Santangelo S, Messina G, Faggio G, Rahim SA, Milone C, J. Raman Spectrosc., 43, 1432, 2012
  36. Niu X, Yang W, Guo H, Ren J, Gao J, Biosens. Bioelectron., 41, 225, 2013
  37. Xia W, Jin C, Kundu S, Muhler M, Carbon, 47, 919, 2009
  38. Bangi UKH, Dhere SL, Rao AV, J. Mater. Sci., 45(11), 2944, 2010
  39. Chen T, Deng F, Zhu J, Chen C, Sun G, Ma S, Yang X, J. Mater. Chem., 22, 15190, 2012
  40. Luo Y, Kong D, Jia Y, Luo J, Lu Y, Zhang D, Qiu K, Li CM, Yu T, RSC Adv., 3, 5851, 2013
  41. Krishnamoorthy K, Veerapandian M, Yun K, Kim SJ, Carbon, 53, 38, 2013
  42. Park OK, Lee S, Joh HI, Kim JK, Kang PH, Lee JH, Ku BC, Polymer, 53(11), 2168, 2012
  43. Ferrari A, Meyer J, Scardaci V, Casiraghi C, Lazzeri M, Mauri F, Piscanec S, Jiang D, Novoselov K, Roth S, Phys. Rev. Lett., 97, 187401, 2006
  44. Jiang LQ, Gao L, Sun J, J. Colloid Interface Sci., 260(1), 89, 2003
  45. Cui ZG, Cui CF, Zhu Y, Binks B, Langmuir, 28, 314, 2011
  46. Binks BP, Lumsdon SO, Langmuir, 17(15), 4540, 2001
  47. Chevalier Y, Bolzinger MA, Colloids Surf. A: Physicochem. Eng. Asp., 439, 23, 2013
  48. Nikfarjam N, Qazvini NT, Deng Y, Colloid Polym. Sci., 292, 599, 2014
  49. Bon SAF, Colver PJ, Langmuir, 23(16), 8316, 2007
  50. Yang HJ, Cho WG, Park SN, Ind. Eng. Chem., 15, 331, 2009
  51. Gudarzi MM, Sharif F, Soft Matter, 7, 3432, 2011
  52. Cunha AG, Mougel JB, Cathala B, Berglund LA, Capron I, Langmuir, 30(31), 9327, 2014
  53. Yan H, Zhao B, Long Y, Zheng L, Tung CH, Song K, Colloids Surf. A: Physicochem. Eng. Asp., 482, 639, 2015
  54. Ridel L, Bolzinger MA, Gilon-Delepine N, Dugas PY, Chevalier Y, Soft Matter, 12, 7564, 2016
  55. Kim F, Cote LJ, Huang JX, Adv. Mater., 22(17), 1954, 2010
  56. Guo P, Song H, Chen X, J. Mater. Chem., 20, 4868, 2010
  57. Wege HA, Kim S, Paunov VN, Zhong QX, Velev OD, Langmuir, 24(17), 9245, 2008
  58. Ashby N, Binks B, Phys. Chem. Chem. Phys., 2, 5640, 2000
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.