Issue
Korean Journal of Chemical Engineering,
Vol.34, No.9, 2480-2487, 2017
Effect of functionalized multiwalled carbon nanotubes on weather degradation and corrosion of waterborne polyurethane coatings
A series of waterborne polyurethane/functionalized multiwalled carbon nanotube (WBPU/f-MWCNT) nanocomposite dispersions was prepared using three defined concentrations of 0.5, 1.0 and 2.0 wt% carboxyl functionalized multiwalled carbon nanotubes (f-MWCNTs). All dispersions were coated on mild steel and exposed under natural weather condition for a maximum of 365 days. Both exposed and unexposed coatings were characterized by potentiodynamic polarization (PDP) and X-ray photoelectron spectroscopy (XPS) analyses. The pristine WBPU coating showed slight degradation and corrosion protection. Inclusion of a higher content of f-MWCNTs significantly improved both the degradation and corrosion protection efficiencies of the coatings. Maximal degradation and corrosion protection was observed when 2.0 wt% f-MWCNT was mixed with WBPU for all of the coatings.
[References]
  1. Chattopadhyay DK, Raju KVSN, Prog. Polym. Sci, 32, 352, 2007
  2. Rahman MM, Hasneen A, Lee YK, Lim KT, J. Sol-Gel Sci. Technol., 67, 473, 2013
  3. Chen GN, Chen KN, J. Appl. Polym. Sci., 63(12), 1609, 1997
  4. Coutinho FMB, Delpech MC, Polym. Degrad. Stabil., 70, 49, 2000
  5. Rahman MM, Kim HD, Lee WK, Fib. Pol., 10, 6, 2009
  6. de. Meijer M, Prog. Org. Coat., 43, 217, 2001
  7. Podgorski L, Roux JM, Surf. Coat. Int., 82, 590, 1999
  8. Cristea MV, Riedl B, Blanchet P, Prog. Org. Coat., 72, 755, 2011
  9. Lowry MS, Hubble DR, Wressell AL, Vratsanos MS, Pepe FR, Hegedus CR, J. Coat. Technol., 5, 233, 2008
  10. Rashvand M, Ranjbar Z, Rastegar S, Prog. Org. Coat., 71, 362, 2011
  11. Gugumus F, Polym. Degrad. Stabil., 39, 117, 1993
  12. Yaneff PV, Adamsons K, Cliff N, Kanouni M, J. Coat. Technol., 3, 201, 2004
  13. Rahman MM, Kim EY, Lim KT, Lee WK, J. Adhes. Sci. Technol., 23(6), 839, 2009
  14. Rahman MM, Kim HD, J. Adhes. Sci. Technol., 21(1), 81, 2007
  15. Zheludkevich ML, Salvado IM, Ferreira MGS, J. Mater. Chem., 15, 5099, 2005
  16. Cook A, Gabriel A, Laycock L, J. Electrochem. Soc., 151, 529, 2004
  17. Suleiman R, Rahman MM, Alfaifi N, Ali BE, Akid R, Corrosion Engin. Sci. Technol., 48, 525, 2013
  18. Shi X, Nguyen TA, Liu ZY, Avci R, Surf. Coat. Technol., 204, 237, 2009
  19. Metroke TL, Kachurina O, Knobbe ET, Prog. Org. Coat., 44, 295, 2002
  20. Metroke TL, Kachurina O, Knobbe ET, Prog. Org. Coat., 44, 185, 2002
  21. Metroke TL, Gandhi JS, Apblett A, Prog. Org. Coat., 50, 231, 2004
  22. Metroke TL, Apblett A, Prog. Org. Coat., 51, 36, 2004
  23. Behzadnasab M, Mirabedini SM, Kabiri K, Jamali S, Corrosion Sci., 53, 89, 2011
  24. Kinlen PJ, Ding Y, Silverman DC, Corrosion, 58, 490, 2002
  25. Markevicius G, Chaudhuri S, Bajracharya C, Rastogi R, Xiao J, Burnett C, Chastek TQ, Prog. Org. Coat., 75, 319, 2012
  26. Shen JF, Huang WS, Wu LP, Hu YZ, Ye MX, Compos. Sci. Technol., 67, 3041, 2007
  27. Liu L, Grunlan JC, Adv. Funct. Mater., 17(14), 2343, 2007
  28. Boger L, Wichmann MHG, Meyer LO, Schulte K, Compos. Sci. Technol., 68, 1886, 2008
  29. Kim BK, Seo JW, Jeong HM, Europ. Polym. J., 39, 85, 2003
  30. Kwon JY, Kim HD, J. Appl. Polym. Sci., 96(2), 595, 2005
  31. Robati D, Bagheriyan S, Rajabi M, Int. Nano Lett., 5, 179, 2015
  32. Batmanghelich F, Ghorbani M, Ceram. Int., 39, 5393, 2013
  33. Rahman MM, Chun HH, Park HJ, Coat. Tech. Res., 8, 389, 2011
  34. Chun LF, Sheng HY, Yu WZ, Wei SH, Hou HE, Wei KE, Chin. Sci. Bull., 55, 650, 2010
  35. Asmatulu R, Claus RO, Mecham JB, Corcoran SG, Mater. Sci., 43, 415, 2007